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101.
A 2-D global chemistry-transport model is set up in this paper.The model simulates the atmospheric ozone distributions well with specified dynamical conditions.The analysis of ozone variation mechanism shows that ozone is chemically in quasi-equilibrium except for the polar night region where the variation of ozone concentration is under the control of dynamical processes,that the oxygen atoms which produce ozone are mainly provided by the photolysis of O2 in the upper stratosphere and by the photolysis of NO2 in the lower stratosphere and the troposphere.and that the ozone is destroyed mainly by NOx:the reactions between NOx and O3 and the odd oxygen cycle contribute 80% to more than 90% of the ozone destruction. 相似文献
102.
TH. Blumenstock H. Fisher A. Friedle F. Hase P. Thomas 《Journal of Atmospheric Chemistry》1997,26(3):311-321
During SESAME phase I ground-based FTIR measurements were performed atEsrange near Kiruna, Sweden, from 28 January to 26 March 1994. Zenith columnamounts of ClONO2, HCl, HF, HNO3,O3, N2O, CH4, and CFC-12 werederived from solar absorption spectra. Time series of ClONO2and HCl indicate a chlorine activation at the end of January and around 1March. On 1 March a very low amount of HCl of 2.09times; 1015molec. cm-2 was detected, probably caused by a second chlorineactivation phase starting from an already decreased amount of HCl. The ratioof column amounts of HCl to ClONO2 decreased inside the vortexfrom about 1 in January to 0.4 in late March compared to values of about 2outside the vortex. Although the Arctic stratosphere was rather warm in winter1993/94 and PSCs occurred seldom, chlorine partitioning into its reservoirspecies HCl and ClONO2 changed during that winter andClONO2 is the major chlorine reservoir at the end of thewinter as in cold winters like 1991/92 and 1994/95. 相似文献
103.
L. Kristensen C. E. Andersen H. E. Jørgensen P. Kirkegaard K. Pilegaard 《Journal of Atmospheric Chemistry》1997,27(3):249-269
We have discussed the behavior of a non-conserved scalar in the stationary, horizontally homogeneous, neutral surface-flux layer and, on the basis of conventional second-order closure, derived analytic expressions for flux and for mean concentration of a gas, subjected to a first-order removal process. The analytic flux solution showed a clear deviation from the constant flux, characterizing a conserved scalar in the surface-flux layer. It decreases with height and is reduced by an order of magnitude of the surface flux at a height equal to about the typical mean distance a molecule can travel before destruction. The predicted mean concentration profile, however, shows only a small deviation from the logarithmic behavior of a conserved scalar. The solution is consistent with assuming a flux-gradient relationship with a turbulent diffusivity corrected by the Damköhler ratio, the ratio of a characteristic turbulent time scale and the scalar mean lifetime. We show that if we use only first-order closure and neglect the effect of the Damköhler ratio on the turbulent diffusivity we obtain another analytic solution for the profiles of the flux and the mean concentration which, from an experimental point of view, is indistinguishable from the first analytic solution. We have discussed two cases where the model should apply, namely NO which, by night, is irreversibly destroyed by interaction with mainly O3 and the radioactive 220Rn. Only in the last case was it possible to find data to shed light on the validity of our predictions. The agreement seemed such that a falsification of our model was impossible. It is shown how the model can be used to predict the surface flux of 220Rn from measured concentration profiles. 相似文献
104.
辽东湾北部浅海区泥沙输送及其沉积特征 总被引:16,自引:1,他引:16
根据实测资料,本文定量分析了辽东湾北部泥沙输送及其分布,并对辽河三角洲沉积区划作了初步讨论。研究表明本区泥沙以纵向搬运为特征。双台子河以西来沙和辽河西水道入海泥沙是区域东部拦门沙体和浅滩发育的主导因素。汛季大潮期,泥沙自西向东运移落淤在河口及毗邻浅水域;小潮期,泥沙除向东扩散外,大部泥沙向海方搬运。调查区可划分六个现代沉积作用区,即潮坪沉积区、辽河水下三角洲细粒沉积区、河口沙洲沉积区、波浪潮流冲蚀沉积区、河口冲积沉积区以及潮汐水道沉积区。 相似文献
105.
Frédérick Delay Hélène Housset-Resche Gilles Porel Ghislain de Marsily 《Mathematical Geology》1996,28(1):45-71
A new method for solving the transport equation based on the management of a large numbe of particles in a discretized 2-D domain is presented. The method uses numerical variables to represent the number of particles in a given mesh and is more complex than the 1-D problem. The first part of the paper focuses on the specific management of particles in a 2-D problem. The method also would be valid for three dimensions as long as the medium can be modeled similar to a layered system. As the particles are no longer tracked individually, the algorithm is fast and does not depend on the number of particles present. The numerical tests show that the method is nearly numerical dispersion free and permits accurate calculations even for simulations of low-concentration transport. Because each mesh is considered as a closed system between two successive time steps, it is easy to add adsorption phenomenon without any problem of numerical stability. The model is tested under conditions that are extremely demanding for its operating mode and gives a good fit to analytical solutions. The conditions in which it can be used to best advantage are discussed. 相似文献
106.
流体地质作用的构造效应 总被引:2,自引:1,他引:2
许多事实证明,在地壳及地球深部存在着大量的流体,它们以气体、液体、熔融体等形式存在于地球内部不同深度处。这些流体的活动在地壳及岩石圈运动演化过程中扮演着十分重要的角色,其作用贯穿于地壳与岩石圈运动演化的全过程,地球表面形成的各种构造与流体作用的参与有着密切的联系。 相似文献
107.
姚磊华 《吉林大学学报(地球科学版)》1997,(4)
对对流占优的三维溶质运移问题提出了分步广义迎风解法,首先利用N.N.Ya-nenko对水动力弥散方程分步求解的思想,将原来的一个定解问题分解为两个定解问题即对流定解问题和扩散定解问题,对对流定解问题采用广义迎风对偶单元均衡法求解,对扩散定解问题采用一般的Galerkin有限元法求解,不仅避免了用一般有限元法和有限差分法求解对流占优的地下水水质数学模型时常出现数值弥散和过量问题,而且避免了求节点速度这一步,节省运算步骤,对井点的浓度变化给出了更合适的求解方法。 相似文献
108.
Zhang Sheng Li Tongjin Wang LiankuiGuangzhou Institute of Geochemistry Chinese Academy of SciencesWushan Guangzhou 《《地质学报》英文版》1997,71(4):433-445
The Changkeng gold-silver deposits consist of a sediment-hosted, disseminated gold deposit and a replacement-type silver deposit. The mineralizations of gold and silver are zoned and closely related to the silicification of carbonate and clastic rocks, so that siliceous ores dominate in the deposit. The mineralizing temperature ranges mainly from 300 to 170℃, and K+, Na+, Ca2+, Mg2+, and Cl- are the major ions in the ore-forming fluid. Calculations of distribution of metal complexes show that gold is mainly transported by hydrosulphide complexes, but chloride complexes of silver, iron, lead, and zinc, which are transformed into hydroxyl and hydrosulphide complexes under neutral to weak-alkaline circumstances in the late stage, predominate in the ore-forming solutions. Water-rock interaction is confirmed to be the effective mechanism for the formation of silver ores by computer modelling of reaction of hydrothermal solution with carbonate rocks. The solubility analyses demonstrate that the precipitation 相似文献
109.
Rate constants for the gas-phase reactions of OH radicals, NO3 radicals and O3 with the C7-carbonyl compounds 4-methylenehex-5-enal [CH2=CHC(=CH2)CH2CH2CHO], (3Z)- and (3E)-4-methylhexa-3,5-dienal [CH2=CHC(CH3)=CHCH2CHO] and 4-methylcyclohex-3-en-1-one, which are products of the atmospheric degradations of myrcene, Z- and E-ocimene and terpinolene, respectively, have been measured at 296 ± 2 K and atmospheric pressure of air using relative rate methods. The rate constants obtained (in cm3 molecule–1 s–1 units) were: for 4-methylenehex-5-enal, (1.55 ± 0.15) × 10–10, (4.75 ± 0.35) × 10–13 and (1.46 ± 0.12) × 10–17 for the OH radical, NO3 radical and O3 reactions, respectively; for (3Z)-4-methylhexa-3,5-dienal: (1.61 ± 0.35) × 10–10, (2.17 ± 0.30) × 10–12, and (4.13 ± 0.81) × 10–17 for the OH radical, NO3 radical and O3 reactions, respectively; for (3E)-4-methylhexa-3,5-dienal: (2.52 ± 0.65) × 10–10, (1.75 ± 0.27) × 10–12, and (5.36 ± 0.28) × 10–17 for the OH radical, NO3 radical and O3 reactions, respectively; and for 4-methylcyclohex-3-en-1-one: (1.10 ± 0.19) × 10–10, (1.81 ± 0.35) × 10–12, and (6.98 ± 0.40) × 10–17 for the OH radical, NO3 radical and O3 reactions, respectively. These carbonyl compounds are all reactive in the troposphere, with daytime reaction with the OH radical and nighttime reaction with the NO3 radical being predicted to dominate as loss processes and with estimated lifetimes of about an hour or less. 相似文献
110.
Ralph Lehmann 《Journal of Atmospheric Chemistry》2004,47(1):45-78
When the output of a complex chemical model is analysed, a typical topic isthe determination of pathways, i.e., reaction sequences, that produce ordestroy a chemical species of interest.A representative example is the investigation of catalytic ozone destruction cycles in the stratosphere.An algorithm for the automatic determination of pathways in any given reactionsystem is presented. Under the assumption that reaction rates are known, it finds all significant pathways, i.e., all pathways with a rate above a prescribed threshold.The algorithm forms pathways step by step, starting from single reactions.The chemical species in the system are consecutively considered as `branching points'.For every branching-point species, each pathway producing it is connected witheach pathway consuming it.Rates proportional to `branching probabilities' are calculated.Pathways with a rate that is smaller than a prescribed threshold arediscarded.If a newly formed pathway contains sub-pathways, e.g., null cycles, it is split into these simpler pathways.In order to demonstrate the performance of the algorithm, it has been applied to the determination of catalytic ozone destruction cycles and methaneoxidation pathways in the stratosphere. 相似文献