Physicochemistry and Mineralogy of Storm Dust and Dust Sediment in Northern China

Dust sediments collected from 1995 to 1998 in Beijing, Dunhuang, Inner Mongolia, Kashi, the Kunlun Mountains, Lanzhou, Ningxia, the Taklimakan Desert, and Xi‘an, China, were characterized in terms of their physical, chemical, and mineralogical properties. Most aerosols and dust analysed ranged in texture from silty clay to clay loam. Their median particle diameters (Mds) generally ranged between 5 to 63μm,coinciding with those of loess from central China and the finest sand from northwestern China. The dust sediments were characterized by a predominance of SiO2 and Al2O3, followed by K2O. Their SiO2/Al2O3and K2O/SiO2 molar ratios ranged from 5.17 to 8.43 and from 0.009 to 0.0368, respectively. The mass concentration spectrum during a dust storm showed a single peak, rather than the triple peak generally observed under clear sky conditions. The dominant minerals were chlorite, illite, calcite, and dolomite.These physical, chemical, and mineralogical properties were consistent with those of aeolian soils and loess in western and central China. The results suggest that aerosols and fine-gained fractions of dust sediments collected in northern China are mainly composed of soil material transported from the arid and semiarid regions of China and Mongolia by prevailing winds. The rate of deposition and properties of dust falling on eastern China were strongly influenced by meteorological conditions, season, latitude, longitude, and altitude of the sampling sites.     

北京地区两次沙尘(暴)天气过程对比分析

通过对 2 0 0 0年 4月 6日和 4月 9日北京地区两次沙尘 (暴 )天气过程的对比分析认为 :蒙古气旋型和不伴有气旋的西北槽型所造成的北京沙尘天气的严重程度不同 ;沙源地区中低层较强上升运动的主要作用是将当地沙尘垂直输送到空中 ,然后在70 0hPa较强西北气流的引导下将卷起的沙尘水平输送到下游地区 ;不稳定层结又加强了沙尘天气 ;沙尘暴区上空z 螺旋度分布的特征是高层为负值 ,低层为正值 ,对流层中低层螺旋度正的大值区与卫星云图显示的沙尘暴区具有较好的一致性 ,对沙尘暴的预报有一定的指示意义     

重金属迁移转化模型研究

大量重金属污染物迁移转化的现象和研究成果都表明重金属以泥沙颗粒为载体迁移转化,描述重金属在天然水体中的迁移转化必须紧紧抓住泥沙颗粒运动及重金属与泥沙之间的转化关系进行.为此在对现有的重金属迁移转化数学模型进行概括分类的基础上,根据水沙运动与污染物相互作用关系,分析了泥沙颗粒运动及重金属吸附解吸不平衡过程,并结合水沙数学模型,建立了重金属迁移转化的耦合模型.同时在模型合理性分析的基础上,对模型进行了计算分析,分析表明模型能够合理地反映重金属污染物在水体中的迁移转化过程.     

Hydro-thermal performance of multilayer capillary barriers in arid lands

In this study, a capillary barrier system was designed and tested for an arid land environment. To simulate arid land conditions of high temperature and sub-irrigation systems, the barrier was subjected to thermal and hydraulic gradients in opposite directions; to test the barrier system under these severe conditions, an experimental apparatus was designed and fabricated. The multilayer capillary barrier consisted of three layers made of silica sand, a mixture of sand and bentonite in equal portions, and a mixture of clay (25%) and aggregate (75%). Several one dimensional coupled heat and moisture tests were performed. Temperature variations along the thickness of the barrier were recorded as a function of time, and at the end of each test, the barrier was sliced into small sections, for the determination of volumetric water content as a function of distance from the heat source. The experimental results were discussed in view of the barrier's intended purpose of its ability to store moisture for long time durations. Coupled heat and moisture flow equations were developed and solved numerically via a finite difference method. Diffusivity parameters were calculated by using experimental results, a numerical model, and Powell's conjugate directions method of nonlinear optimization. The model was calibrated and the results were discussed. Good agreement between calculated and experimental results was obtained. This revised version was published online in July 2006 with corrections to the Cover Date.     

Transport of dissolved methoxy-nonafluorobutane through a saturated column

Solute transport experiments were conducted in a one-dimensional saturated column using dissolved methoxy-nonafluorobutane (HFE-7100), a Novec engineered fluid developed by the 3M Corporation, as the solute. Novec engineered fluids are considered dense non-aqueous phase liquids (DNAPLs) because they are immiscible with water and have a specific gravity greater than one. The HFE-7100 fluid is safer and environmentally friendlier than common DNAPL contaminants such as tetrachloroethylene (PCE) or trichloroethylene (TCE); thus, it is an ideal substitute DNAPL for laboratory groundwater contamination research. Three sets of solute transport experiments were conducted. The first set of experiments was conducted in a glass-bead-packed column using dissolved HFE-7100 as the solute. The second set of experiments was conducted in a sand-packed column using dissolved HFE-7100 as the solute. The third set of experiments was conducted in a sand-packed column using dissolved PCE as the solute. The dissolved HFE-7100 column breakthrough concentrations were compared with dissolved PCE breakthrough concentrations. Results show that the one-dimensional solute transport equation was successful in describing the transport behavior of dissolved HFE-7100. This study demonstrates that the HFE-7100 fluid can be used as a safer substitute DNAPL for groundwater contaminant dissolution and transport research.     

Effects of temperature and humidity upon the transport of sedimentary particles by wind

Wind tunnel simulations of aeolian transport carried out over a range in mean temperature between 32 °C and ?9 °C suggest that cold airflows support higher mass transport rates (Q) than very warm air. The magnitude of this increase is larger than expected, so that analytical and semi‐empirical models underestimate Q. Extrapolation of the results suggests that, at ?40 °C, as for example in the dry valleys of Antarctica in winter, Q may be as much as 70% higher than for the equivalent wind speed in hot deserts at air temperatures of 40 °C. Temperature‐dependent changes in air density and turbulence contribute to this result. The decreased tension of water adsorbed onto particle surfaces at low temperatures is postulated to reduce interparticle cohesion and, thus, to increase the elasticity of particle impacts on cold beds. Definition of the roles that temperature and humidity play in aeolian transport is relevant to studies of palaeoenvironmental reconstruction and extraterrestrial (or planetary) geology. Investigation of present‐day, cold climate features and of climate change effects also requires knowledge of these fundamental relations.     

Nuclear Waste Disposal Simulations: Couplex Test Cases

We give some results obtained for the Couplex test cases proposed by the ANDRA. In this paper our aim is twofold. Firstly, to compute the release of nuclides out of the repository by concentrating on the 3D near field (Couplex 2). The simulation of the transport phenomena takes into account the dissolution of the glass containers and congruent emissions of the radio-nuclides including filiation chains and some simplified chemistry. Secondly, it is to use the near field computations in order to simulate the nuclide migrations in a 2D far field (Couplex 3). Coupling in between the two simulations takes into consideration the periodicity of the disposal modules and the geometry of the repository described in Couplex 1. The mixed finite element and discontinuous Galerkin methods are used to solve the convection–diffusion equations. In order to handle the nonlinear precipitation/dissolution term, we developed a new iterative technique that combines Picard and Newton–Raphson methods.     

Modélisation du transport réactif en milieux poreux non saturés avec une méthode ELLAM en maillage variable

Modelling contaminant transfer with biological/chemical/radioactive processes needs appropriate numerical methods able to reproduce sharp concentration fronts. In this work, we develop a new Eulerian–Lagrangian Localized Adjoint Method (ELLAM) for solving the reactive transport equation with non-constant coefficients. To avoid interpolation (leading to errors), we use a moving grid to define the solution and test functions. The method is used to simulate first the infiltration of solute into a column of unsaturated porous medium and second the multispecies transport. The developed ELLAM gives accurate results without non-physical oscillations or numerical diffusion, even when using large time steps. To cite this article: A. Younes, C. R. Geoscience 336 (2004).     

利用遥感综合分析西风引导气流与地形对沙尘运移路径的影响

沙尘暴的发生受大气环流、地表状况、降雨的影响，还受到局部地区地形的影响。一次规模较大的沙尘暴过程，沙尘可以从蒙古国和我国西部沙源地输送到我国东部、韩国、日本乃至夏威夷、美国西海岸。中日亚洲沙尘暴ADEC项目对亚洲沙尘暴的起沙、传输和降落的运行机制已经作了深入的研究，并建立了亚洲沙尘暴的数值模拟系统。本文以影响北京地区的沙尘暴事件为例，利用遥感技术，综合DEM地形数据和地面实测数据分析西风引导气流和地形对沙尘运移路径影响，将MODIs影像数据和DEM地形数据以及地面观测站点实测数据相结合，进行综合分析，结果表明在一次沙尘暴过程中，沙尘在运移过程中的运移路径明显地受到西风引导气流、沙尘粒子自然沉降规律以及局部地形的影响，要预防(减少)北京地区的沙尘暴仅仅作好北京地区的生态环境建设是不够的，加强北京周边地区，尤其是张家口地区、官厅水库库区及库区周围地区的生态环境建设尤为重要。     

沙尘天气等对西安市空气污染影响的研究

通过对西安市1981—2000年TSP、SO2和NOx年平均浓度资料,1998—2000年周报和日报环境监测资料以及相应的地面、高空常规气象观测资料的统计分析,研究了该市空气污染的时间变化特点以及沙尘天气等几种气象条件对其浓度变化的影响。结果表明:(1)颗粒污染物(TSP和PM10)是西安市的首要污染物,其次是SO2。1981—2000年期间,TSP年平均浓度降低了75%,SO2年平均浓度降低了77%,NOx年平均浓度总体上变化不大;这三种污染物月平均浓度的年变化都呈单周期型,冬季1月份最高,夏季最低(TSP是7月份最低,SO2和NOx是8月份最低)。(2)2001年春季3～4月份沙尘天气的频繁发生,使西安市空气污染日出现全年的第二个多发期(23d·月-1),这有别于正常年份仅在冬季1月份出现一个浓度峰值的特点;强沙尘暴天气过程会使西安市PM10浓度在非常短的时间内提高3倍左右,造成严重的颗粒物污染。(3)西安市冬半年出现轻度污染以上级别的几率明显大于夏半年。影响西安市的地面天气系统可归纳为12类,当受不同天气系统控制时,其污染状况会有较大差异。(4)西安市一年四季都有逆温存在,100m平均逆温强度为0.90℃;全年以低层逆温出现日数最多,但冬季贴地逆温出现日数最多,厚度最厚,强度最大,是造成西安市冬季空气污染严重的最重要气象因素之一。(5)西安