不同环境条件下堆石料变形特性的试验研究

探讨了对处于受压状态的堆石料进行干湿、冷热变化等环境因素作用下力学性质研究的试验方法。使用新研制的堆石料风化试验仪,对某种泥质粉砂岩堆石料进行了干湿循环、冷热循环以及湿冷-干热耦合变化三种环境条件下的长期变形特性试验研究,探讨了堆石料长期劣化变形的机制。试验结果表明,干湿循环试验和湿冷-干热耦合循环均可导致堆石体产生较大幅度的附加变形,其变形机制包括湿化变形、堆石体颗粒湿胀和干缩循环变形以及堆石料的劣化变形等。环境因素的循环变化可导致堆石体颗粒的劣化,堆石体劣化变形是高土石坝后期变形的重要组成部分。     

高钙粉煤灰固化重金属污染土的工程性质试验研究

高钙粉煤灰是燃煤电厂排出的固体废物,其堆放不仅需占用大量土地,而且对周围环境存在严重威胁。通过系统的室内试验,着重研究了高钙粉煤灰固化铅与锌污染土的工程性质,揭示了其作用机制,探讨了利用高钙粉煤灰固化重金属污染土的可行性。试验结果表明,土体受到重金属离子污染后其无侧限抗压强度降低,掺入高钙粉煤灰可提高土体强度,并能抑制重金属离子的滤出;污染物浓度较低时,固化污染土中的Pb2+和Zn2+均能得到有效固化,污染物浓度较高时,Zn2+的固化效果优于Pb2+。干湿循环试验结果表明,高钙粉煤灰固化污染土的强度随干湿循环次数的增加,先增大后减小;固化土体中重金属离子浓度较低时,滤出液中金属离子浓度随干湿循环次数增加而增大;重金属离子浓度较高时,滤出液中金属离子浓度基本保持不变。     

干湿循环作用下压实黄土湿陷特性试验研究

压实黄土作为重要的填筑材料,广泛应用于我国西北、华北公路、铁路、机场等基础设施建设中.由于降雨及蒸发的周期性变化,黄土路基及基础经历着强烈的干湿交替作用.基于此,开展压实黄土风干干燥-滴水增湿条件下的干湿循环试验,利用双线法测试最佳含水量条件下不同初始压实度的黄土土样干湿循环前后的湿陷系数.结果表明：没有经历干湿交替作用的土样,湿陷系数随着压实度的增大而快速减小,当压实度达到90%,提高压实度对于黄土湿陷变形特征的影响较小;5次干湿循环作用后,不同压实度下的试样的湿陷系数均明显增大,且压实度越大,干湿作用对其湿陷变形的影响越显著;压实度K=95%试样在经历5次干湿循环作用后土样上部出现肉眼可见的细微孔隙,体积膨胀,有可溶盐析出,湿陷系数达到0.017,土样出现二次湿陷.     

水泥基渗透结晶型防水材料对硫铝酸盐水泥固化土性能影响及机制分析

水泥土固化过程中Ca2+浓度会随水化反应的进行而逐步降低,导致水泥颗粒未完全水化,固化土强度增长受限,而水泥基渗透结晶型防水材料（CCCW）中活性物质能催化未水化水泥颗粒反应。选择硫铝酸盐水泥（SAC）为胶凝材料、CCCW为添加剂,通过单掺与复掺的方式,结合X射线衍射（XRD）、电镜扫描（SEM）表征,分析了固化土的无侧限抗压强度、水稳定性、耐干湿循环性能及微观结构。结果表明,复掺16%混合料（4%CCCW+12%SAC）的固化土强度是同掺量下单掺SAC固化土强度的1.5倍,且比单掺20%SAC的固化土强度高1.41 MPa;复掺16%混合料（4%CCCW+12%SAC）的固化土泡水2～8 d软化系数平均达0.97,而同掺量下SAC固化土平均仅为0.73;单掺的固化土强度随干湿循环次数增加逐级降低,而复掺混合料的固化土强度呈波浪式发展;CCCW中活性物质能增加固化土中钙矾石生成量并修复微裂缝,钙矾石长径比显著增大,可直接连接两个甚至多个土颗粒,形成三维网状结构,显著提高结晶体的微观加筋、骨架及填充作用,改善SAC固化土强度、水稳定性及耐干湿循环性能。     

浸泡-风干循环作用下砂岩动力特性劣化规律研究

在库水的长期浸泡-风干循环作用下,库岸边坡岩体的动力特性变化规律直接影响其长期稳定性能,其中,消落带是库岸边坡稳定的敏感地带。因此,特选取三峡库区库岸边坡消落带典型砂岩为研究对象,设计了考虑水压力反复升降变化和浸泡-风干循环耦合作用的试验方案,对不同浸泡-风干循环作用周期的岩样进行单轴循环加、卸载动力响应试验。研究结果表明：随着浸泡-风干循环作用次数的增加,相同次数加、卸载循环作用时对应岩样的轴向应变、动应力-应变曲线的滞回圈面积逐渐增大,计算得到砂岩的阻尼系数、阻尼比逐渐变大,动弹性模量逐渐减小,说明浸泡-风干循环作用对砂岩动力特性的损伤是一种累积性发展的过程。最后,基于岩样的微观结构变化,对浸泡-风干水岩循环作用下砂岩动力特性劣化机制进行探讨。研究成果对库区大量存在的库岸边坡在考虑地震作用下的长期稳定性评价具有较高的参考价值。     

微波炉法测定遗址土含水率的可靠性研究

古代土遗址病害发展与土的含水率变化密切相关,但土遗址保护现场快速准确测定土的含水率不是一件容易的事。选择遗址土、含盐土、黄土等进行对比试验,研究分析微波炉烘干法（简称微波炉法）测遗址土含水率结果的可靠性。在测定试验土样界限含水率和易溶盐含量的基础上,对比分析微波炉法、烘箱法两种方法测定土含水率的误差来源。试验结果表明,土的塑性对微波炉法的测定有一定影响,但测定误差均在2%以内;土的含盐量影响水分的蒸发速度,不影响微波炉法的测定结果;微波法测定遗址土含水率准确,且具有快速、便捷等优势,值得在土遗址保护工程中推广使用。     

西北地区气候变化新动态及对干旱环境的影响——总体暖干化,局部出现暖湿迹象

近50 a来,西北地区气温呈显著的上升趋势,降水变化空间差异突出,西北地区整体暖干化趋势明显,局部出现暖湿现象。气候变暖使冰川退缩,雪线上升,冻土消融,湿地退化,湖泊萎缩,河流流量减少,水资源越来越短缺,出现生态环境恶化问题。根据IPCC预测结果分析,未来西北地区气候变暖趋势会更加明显。从保护西北地区生态环境、完善气候变化综合监测系统以及开展重点区域气候变化过程专项研究等方面提出了对策建议。     

Relative contribution of various climatic processes in disintegration of clay-bearing rocks

The climatic processes of heating and cooling, wetting and drying, and freezing and thawing affect the disintegration characteristics of clay-bearing rocks (shales, claystones, mudstones, and siltstones) to varying degrees. Although heating and cooling, wetting and drying, and freezing and thawing are known to be the main processes responsible for physical disintegration of rocks under natural conditions, most of the previous investigators have used methods based only on water content variations (e.g., jar slake, slake index, and slake durability index tests) to assess the disintegration of clay-bearing rocks. Such assessments may not be adequate to explain the field behaviour of clay-bearing rocks subjected to a full range of climatic processes. In order to evaluate the combined effects as well as relative contributions of various climatic processes on the disintegration behaviour, samples of selected clay-bearing rocks, consisting of 5–6 particles, each weighing 85–150 g, were subjected to multiple cycles of heating and cooling, wetting and drying, and freezing and thawing. These treatments resulted in fragmentation of samples with fragments ranging from 50 to 2 mm and finer in dimensions. A new approach, referred to as the disintegration ratio, and defined as the area under the grain size distribution curve of the disintegrated material to the total area encompassing all grain size distribution curves of the samples, was used to account for fragmentation into varying sizes. Statistical analyses were performed to investigate the relationship between fragmentation, mineralogical composition, and physical properties.     

Determination of Abundances of Fifty‐Two Elements in Natural Waters by ICP‐MS with Freeze‐Drying Pre‐concentration

To precisely determine the abundances of fifty‐two elements found within natural water samples, with mass fractions down to fg g^?1 level, we have developed a method which combines freeze‐drying pre‐concentration (FDC) and isotope dilution internal standardisation (ID‐IS). By sublimation of H₂O, the sample solution was reduced to < 1/50 of the original volume. To determine element abundance with accuracy better than 10%, we found that for solutions being analysed by mass spectrometry the HNO₃ concentration should be > 0.3 mol l^?1 to avoid hydrolysis. Matrix‐affected signal suppression was not significant for the solutions with NaCl concentrations lower than 0.2 and 0.1 cg g^?1 for quadrupole ICP‐MS and sector field ICP‐MS, respectively. The recovery yields of elements after FDC were 97–105%. The detection limits for the sample solutions prepared by FDC were ≤ 10 pg g^?1, except for Na, K and Ca. Blanks prepared using FDC were at pg‐levels, except for eleven elements (Na, Mg, Al, P, Ca, Mn, Fe, Co, Ni, Cu and Zn). The abundances of fifty‐two elements in bottled drinking water were determined from five different geological sources with mass fractions ranging from the fg g^?1 to μg g^?1 level with high accuracy.     

冻结岩石钻进空气洗井时压缩空气的冷却和干燥问题

在冻结岩石中钻进时,使用压缩空气作为冲洗介质较之使用钻井液有很多优点。给出了冷却空气洗井钻进时井内温度的简化计算公式,按照这些计算公式可以确定空气洗井时井内任何时间、任何深度的温度和代表性关系曲线。井内温度的分布与进入钻杆柱内空气的初始温度有直接的关系,从空气压缩机中出来的压缩空气的温度很高,因此必须对其进行冷却和干燥,给出了冷却和干燥的方法和手段,提出了相应的建议。