硅酸盐样品微波加热碱熔分解方法

本文研究了硅酸盐样品在常压下，用微波炉进行碱熔分解的熔样时间，试剂用量和滴加水量等情况对分解的影响，确定了最佳实验条件，将此法用于地球化学标准参考样品ＳｉＯ２的测定，取得了满意的结果。     

Comparison of Aircraft and Ground-Based FluxMeasurements during OASIS95

Aircraft and ground-based measurements made during the1995 Australian OASIS field campaign are compared. The aircraft data were recorded during low-level flightsat 6 m above ground level and grid flights at altitudes of between 15 and 65 m, allin unstable atmospheric conditions. The low-level flights revealed an inadequate temperaturesensor response time, a correction for which was determined from subsequent work ina wind tunnel. Aircraft and ground-based measurements of mean wind speed, wind directionand air temperature agree to within 0.2 m s^-1, 4° and 0.9 °C respectively.Comparisons between aircraft and ground-based observations of the standarddeviations of vertical velocity, horizontal wind speed, air temperature and specifichumidity have slopes of 0.96, 0.97, 0.92 and 0.99 respectively but the observed scatter isroughly twice the random error expected due to the averaging length of the aircraft data andthe averaging period of the ground-based data. For the low-level flights, the ground-basedand aircraft measurements of sensible and latent heat flux show mean differences of 27 and-25 W m^-2 respectively, which reduce to 11 and -4 W m^-2 respectivelywhen analysis of aircraft data is limited to areas immediately adjacent to the fluxtowers. For the flights at 15 to 65 m above ground level, the mean differences between theground-based and aircraft measurements of sensible and latent heat flux are -22 and-1 W m^-2 respectively and these change to -1 and -7 W m^-2 respectively oncethe effect of surface heterogeneity is included. Aircraft and ground-based measurementsof net radiation agree to within 6% at one ground-based site but differ by 20% at a second.Aircraft measurements of friction velocity at 6 m above the ground agree well withground-based data, but those from flights between 15 and 65 m above ground level do not.This is because at these heights the aircraft measurements provide the local shear stress,not the surface shear stress. Overall, the level of agreement allows confidence in the aircraftdata provided due care is taken of instrument response times and differences in thesurfaces sampled by aircraft and ground-based systems.     

多尺度分解在地震信号处理中的应用

利用小波分析中的多尺度分解及信号消噪技术，对记录不清、信噪比小、震相无法辨认的地震信号进行处理。结果表明：多尺度分解在弱震信号提取和弱震相的识别等方面有很好的效果。     

金矿样品的几种溶样方法

通过王水、封闭和烧杯敞口及聚乙烯溶样瓶封闭溶样等方法，对含Au矿样的试样分解、溶样体系及各种溶样方法的对比表明，利用聚乙烯溶样瓶，采用HNO3 NaCl KMnO4 NH4HF2溶样体系，在水浴锅中封闭溶样40min，矿样中的Au即可完全分解。经国家标准物质分析验证，结果与标准值相符。封闭溶样可以避免样品外溢、进溅，使分析结果更准确可靠，降低成本，减少环境污染，适用于大批量样品分析。     

地—空界面天然中子辐射场的扰动及其环境意义

介绍了地—空界面天然中子流的来源和轻便型天然中子流测量仪器。论述了地—空界面天然中子辐射场的扰动。理论与长期观测表明,在地—空界面上天然中子流注量率随高程的增加而呈指数规律增加,而在近地表(20m内)却随距地面高度的增加而呈指数规律减少;天然中子流注量率与大气压力呈负相关关系,气压系数为(-0.060～-0.064)中子计数/30min/kPa;地—空界面天然中子流的纬度效应与高空中更显著;天然中子流注量率异常与气象的变化密切相关;地表介质的含水率增高,则地—空界面上升快中子流明显降低。通过对地一空界面天然中子流测量,可以揭示气象的瞬态变化、确定地表介质的含水率的关系,以及在地震预报与环境电离辐射评价方面具有重要的科学意义与实用价值。     

贵州百花湖分层晚期有机质降解过程与溶解N2O循环

百花湖是一个具有季节性分层的富营养小型湖泊,在秋季湖水倒转期经常发生水质恶化事件,碳氮循环出现异常。文章研究特选择在秋初,湖泊分层开始消失时,测定了湖水中不同深度的N₂O,CH₄,CO₂,有机和无机碳同位素以及其他化学参数变化。结果发现:采样时百花湖在约6m和16m深度附近出现了两个温度不连续层(SDL和PDL),并影响到有机颗粒的沉降和分解。相对而言,有较多的有机质在这两个层内发生降解,但降解的途径有所不同,上部主要是有氧降解,下部则主要是无氧降解过程。N₂O的产生和消耗与有机质的降解过程完全对应:PDL层以上,ΔN₂O与AOU的线性关系反映了N₂O主要形成于硝化作用;PDL层以下反硝化作用导致N₂O严重不饱和;PDL内位于硝化作用和反硝化作用过渡带的N₂O峰,显然是硝化与反硝化联合作用的结果。PDL层内较大的CH₄浓度变化梯度,说明嗜甲烷细菌可能通过氧化NH+4贡献了部分N₂O。百花湖秋、冬季表层湖水N₂O都是过饱和的,都是大气N₂O的源,依据分子扩散模型计算湖泊N₂O的释放通量在12～14μmol/m·day之间,秋、冬季没有明显的差别。秋季底层湖水的反硝化作用是湖泊N₂O的汇,其消耗通量与表层的释放通量基本相当。     

Transport over a narrow shelf: Exuma Cays, Bahamas

Current meter and temperature data were collected over a 402-day period from an outer shelf and a tidal channel study site in the Exuma Cays, Bahamas. The shelf width is less than 2 km, and floods and ebbs through a nearby tidal channel extend across the entire shelf and reduce coherence of wind forcing and along-shelf flow. The data are used in perturbation analyses to investigate the across-shelf turbulent transport of heat and momentum over seasonal time scales. Data show a net landward transport of both heat and momentum over the course of the study, but the perturbation products contain distinct seasonal cycles. In fall and winter months, across-shelf heat and momentum fluxes are landward, while during spring and summer months fluxes are seaward. Comparison of shelf-water temperature with the temperature of bank water leaving on the ebb suggests that seasonal cycles of across-shelf heat and momentum in shelf waters are influenced by the seasonal export of relatively warm and cool water from Great Bahama Bank.Responsible Editor: Iris Grabemann     

Approximate modal decomposition of inelastic dynamic responses of wall buildings

Two approximate methods for decomposing complicated inelastic dynamic responses of wall buildings into simple modal responses are presented. Both methods are based on the equivalent linear concept, where a non‐linear structure is represented by a set of equivalent linear models. One linear model is used for representing only one vibration mode of the non‐linear structure, and its equivalent linear parameters are identified from the inelastic response time histories by using a numerical optimizer. Several theoretical relations essential for the modal decomposition are derived under the framework of complex modal analysis. Various numerical examinations have been carried out to check the validity of the proposed modal decomposition methods, and the results are quite satisfactory in all cases. Fluctuating bending moment and shear at any location along the wall height contributed by each individual vibration mode can be obtained. Modal contributions to shear and flexural strength demands, as well as the corresponding modal properties, under various seismic loading conditions can also be identified and examined in detail. Furthermore, the effects of higher vibration modes on seismic demands of wall buildings are investigated by using the modal decomposition methods. Several new insights into the complicated inelastic dynamics of multi‐story wall buildings are presented. Copyright © 2004 John Wiley & Sons, Ltd.     

基于小波分解的西太平洋副热带高压模糊推理预测

基于NCEP/NCAR再分析资料,讨论了西太平洋副高脊线与其前期位置的相互关系,并在此基础上用小波分解和自适应模糊推理方法,对副高脊线进行集成建模和预测.基于小波分解重构的副高脊线短期活动集成预测结果表明,该方法可有效降低预报难度,明显改进和提高了副高脊线短期活动的预报准确率.     

洪山泉流量动态系统分析

为查明洪山泉域的开采程度,在前人研究基础上,建立了现阶段泉流量-降雨量的线性模拟模型。通过对模型的系统辨识,对系统的"慢时变"现象作出了合理解释,并发现系统在1994年以后发生了"快时变",说明开采量从1995年开始迅猛增加。同时,由多年来泉流量序列的自相关分析,发现其宏观周期到2000年基本保持不变,说明虽然第二输入(即人为开采量)对该系统的作用已不可忽略,但尚未达到足以改变其宏观频率的程度。