Predicting quantiles of water quality from catchment characteristics

Water quality is often highly variable both in space and time, which poses challenges for modelling the more extreme concentrations. This study developed an alternative approach to predicting water quality quantiles at individual locations. We focused on river water quality data that were collected over 25 years, at 102 catchments across the State of Victoria, Australia. We analysed and modelled spatial patterns of the 10th, 25th, 50th, 75th and 90th percentiles of the concentrations of sediments, nutrients and salt, with six common constituents: total suspended solids (TSS), total phosphorus (TP), filterable reactive phosphorus (FRP), total Kjeldahl nitrogen (TKN), nitrate-nitrite (NO_x), and electrical conductivity (EC). To predict the spatial variation of each quantile for each constituent, we developed statistical regression models and exhaustively searched through 50 catchment characteristics to identify the best set of predictors for that quantile. The models predict the spatial variation in individual quantiles of TSS, TKN and EC well (66%–96% spatial variation explained), while those for TP, FRP and NO_x have lower performance (37%–73% spatial variation explained). The most common factors that influence the spatial variations of the different constituents and quantiles are: annual temperature, percentage of cropping land area in catchment and channel slope. The statistical models developed can be used to predict how low- and high-concentration quantiles change with landscape characteristics, and thus provide a useful tool for catchment managers to inform planning and policy making with changing climate and land use conditions.     

Solution for a plane strain rough‐walled hydraulic fracture driven by turbulent fluid through impermeable rock

The impact of turbulent flow on plane strain fluid‐driven crack propagation is an important but still poorly understood consideration in hydraulic fracture modeling. The changes that hydraulic fracturing has experienced over the past decade, especially in the area of fracturing fluids, have played a major role in the transition of the typical fluid regime from laminar to turbulent flow. Motivated by the increasing preponderance of high‐rate, water‐driven hydraulic fractures with high Reynolds number, we present a semianalytical solution for the propagation of a plane strain hydraulic fracture driven by a turbulent fluid in an impermeable formation. The formulation uses a power law relationship between the Darcy‐Weisbach friction factor and the scale of the fracture roughness, where one specific manifestation of this generalized friction factor is the classical Gauckler‐Manning‐Strickler approximation for turbulent flow in a rough‐walled channel. Conservation of mass, elasticity, and crack propagation are also solved simultaneously. We obtain a semianalytical solution using an orthogonal polynomial series. An approximate closed‐form solution is enabled by a choice of orthogonal polynomials embedding the near‐tip asymptotic behavior and thus giving very rapid convergence; a precise solution is obtained with 2 terms of the series. By comparison with numerical simulations, we show that the transition region between the laminar and turbulent regimes can be relatively small so that full solutions can often be well approximated by either a fully laminar or fully turbulent solution.     

Modelling the poroelastoplastic behaviour of soils subjected to internal erosion by suffusion

Granular soils subjected to seepage flow may suffer suffusion, ie, a selective internal erosion. Extending the classical approach of poromechanics, we deduce a new form of the Clausius-Duhem inequality accounting for dissipation due to suffusion, and we deduce restrictions on the constitutive laws of the soil. We suggest (a) a possible coupling between the seepage forces and the suffusion kinetics and (b) an extension of an existing elastoplastic model for the skeleton mechanical behaviour. Numerical integrations of the elastoplastic model are carried out under drained axisymmetric triaxial and oedometric conditions. As a result, we prove that the extended model is able to qualitatively reproduce the suffusion induced strains and the strength reduction experimentally observed. Predictions on the oedometric behaviour of suffusive soils are also provided.     

A modified numerical model for moisture-salt transport in unsaturated sandy soil under evaporation

Soil salinization, caused by salt migration and accumulation underneath the soil surface, will corrode structures. To analyze the moisture-salt migration and salt precipitation in soil under evaporation conditions, a mathematical model consisting of a series of theoretical equations is briefly presented. The filling effect of precipitated salts on tortuosity factor and evaporation rate are taken into account in relevant equations. Besides, a transition equation to link the solute transport equation before and after salt precipitation is proposed. Meanwhile, a new relative humidity equation deduced from Pitzer ions model is used to modify the vapor transport flux equation. The results show that the calculated values are in good agreement with the published experimental data, especially for the simulation of volume water content and evaporation rate of Toyoura sand, which confirm the reliability and applicability of the proposed model.     

Overview of In - Situ Biodegradation and Enhancement

Microbial degradation technologies have been developed to restore ground water quality in aquifers polluted by organic contaminants effectively in recent years. However, in course of the degradation, the formation of biofilms in ground water remediation technology can be detrimental to the effectiveness of a ground water remediation project. Several alternatives are available to a remedial design engineer, such as Permeable Reactive Barriers (PRBs) and in -situ bioremediation, Hydrogen Releasing Compounds (HRCs) barrier, Oxygen Releasing Compounds (ORCs) barrier etc. which are efficient and cost- effective technologies. Excessive biomass formation renders a barrier ineffective in degrading the contaminants, Efforts are made to develop kinetics models which accurately determine bio - fouling and bio - filn formation and to control excessive biomass formation.     

一种有发展前景的隧道及井巷超前预报技术——电磁导弹探测技术

对于隧道和煤矿井巷的安全掘进 ,超前预报显得特别重要。但由于掌子面前的特殊环境限制及多种干扰的严重影响 ,给隧道及井巷超前预报技术的研究带来许多困难。在瞬变电磁理论的基础上 ,引入新的电磁传播理论———电磁导弹技术 ,作为对该技术的初步探索 ,文章论证了该技术在隧道超前预报中应用的可能性 ,并提出了研究的主要内容和发展方向以及可能取得的新的技术突破和技术支撑     

Activity and kinematics of members of the TW Hydrae association

We present high-resolution echelle spectroscopy of 20 stars in 16 systems catalogued as members of the TW Hydrae association, and 16 stars identified as possible new members. We have calibrated the range of coronal and chromospheric activity expected for such young stars as a function of spectral type by combining our observations with literature data for field and open cluster stars. We also compute space motions for TWA members and candidate members with proper motion measurements, using two techniques to estimate distances to stars lacking direct trigonometric parallax measurements. The mean space motion of the four TWA members with known parallaxes is  ( U , V , W : −10.0, −17.8, −4.6) km s⁻¹  . 14 of the candidates have properties inconsistent with cluster membership; the remaining two are potential new members, although further observations are required to confirm this possibility.     

First evidence of IMF control of Jovian magnetospheric boundary locations: Cassini and Galileo magnetic field measurements compared

The Cassini spacecraft, en route to Saturn, passed close to Jupiter while the Galileo spacecraft was completing its 28th and 29th orbits of Jupiter, thus offering a unique opportunity for direct study of the solar wind-Jovian interaction. Here evidence is given of response of the Jovian magnetopause and bow shock positions to changes of the north-south component of the solar wind magnetic field, a phenomenon long known to occur in equivalent circumstances at Earth. The period analyzed starts with the passage over Cassini of an interplanetary shock far upstream of Jupiter. The shock's arrival at Galileo on the dusk-flank of the magnetosphere caused Galileo to exit into the solar wind. Using inter-spacecraft timing based on the time delay established from the shock arrival at each spacecraft, we point out that Galileo's position with respect to the Jovian bow shock appears to correlate with changes in the disturbed north-south reversing field seen behind the shock. We specifically rule out the alternative of changes in the shape of the bow shock with rotations of the interplanetary magnetic field as the cause.