天山乌苏段火山泥元素组成及含量分析

采用能量色散型X射线荧光光谱分析（EDXRF）对新疆乌苏天山泥火山土壤样品的元素含量进行了测定。采用单指标评价指数法和内梅罗综合指数法,对新疆天山乌苏段火山泥中的重金属的种类和含量进行了研究,结果显示：Cd、As、Cu元素的含量达到土壤环境质量评价的二级标准,Hg、Pb、Cr、Zn、Ni元素的含量达到土壤环境质量评价的一级标准,乌苏天山火山泥综合评价达到二级标准。将火山泥的元素含量与新疆地区不同土质的土壤元素含量进行比较,与干旱区不同省份的土壤元素含量进行比较,分析了火山泥元素组成及含量的成因。     

1730年夏季黄淮地区暴雨极端事件研究

1730年（清雍正八年）7—8月,我国黄淮地区连续暴雨17 d,引起黄河、大运河和淮河暴涨、决堤的大范围洪涝灾害。这是小冰期中相对温暖时段气候背景下的极端气候事件。本文依据历史文献记载复原了1730年夏季暴雨时段的天气实况,绘制了暴雨区域图显示强降雨中心移动动态和水灾地域分布图,概述当年气候特点,指出暴雨事件与台风活动的关联。1730年是太阳活动周极小年的前3年、有重大火山活动,是极强的厄尔尼诺事件后的第2年。这些天气特点和背景条件与现代罕见的1975年河南“75?8暴雨”相似。     

土壤重金属连续提取方法的优化

重金属在污染土壤中的形态分布决定着重金属的迁移性和危害的程度。土壤重金属形态分析应用最多的是Tessier和BCR连续提取法。Tessier和BCR连续提取法没有考虑土壤样品的特征。美国环保署危险废物浸出毒性鉴别标准法虽然考虑土壤pH值,但没有划分形态。采集不同pH土样,结合Tessier、BCR和毒性浸出鉴别方法的特征,优化出针对不同pH值土壤的连续提取方法,将土壤中重金属划分为活性态、次生碳酸盐结合态、次稳定态和稳定态。用优化的连续提取方法对土样进行连续提取,重金属回收率为85%~115%。优化连续提取方法的结果与Tessier和BCR结果对比显示优化连续提取方法克服了Tessier连续提取法对非石灰质土壤提取过量BCR连续提取法对石灰质土壤提取不足的缺点。优化后的连续提取方法数据稳定可靠,可作为重金属形态分析方法使用。     

江西省冻雨垂直温度层结分析及预报

利用1960-2013年江西省89个气象观测站常规观测资料,采用统计分析和插值处理方法,对江西106次冻雨过程垂直温度层结进行分析,并建立冻雨预报思路。结果表明：江西省冻雨发生通常伴随1000-850 hPa剧烈降温和700 hPa增温,925-700 hPa存在明显逆温。融化层是冻雨发生的必要条件,87.7 %样本融化层位于700 hPa,9.4 %样本融化层位于850 hPa;一般以1000 hPa温度<1.0 ℃、925 hPa和850 hPa温度<-2.0 ℃和700 hPa温度≥0.0 ℃作为江西冻雨预报的温度阈值标准,同时也应注意融化层位于850 hPa的情况。地面气温越低,越有利于冻雨形成,冻雨发生时最低气温为0.0 ℃以下,平均气温为1.0 ℃以下。冷暖空气持续在27°-28 °N交汇,且鄱阳湖以南至抚河流域平均气温＜1.0 ℃和最低气温＜0.0 ℃出现比其他地区多,造成该区域冻雨发生频次比其他地区明显偏多。另外,通过大气逆温层结、地面气温与冻雨的对应关系,建立基于模式资料和常规观测资料的自动诊断方法。     

Crude-oil hydrocarbon composition characteristics and oil viscosity prediction in the northern Songliao Basin

Crude oil hydrocarbon composition characteristics and oil viscosity prediction are important bases in petroleum exploration.A total of 54 oil/heavy-oil samples and 17 oil sands were analyzed and quantified using both comprehensive 2D gas chromatography(GC×GC)and comprehensive 2D gas chromatography/time-of-flight mass spectrometry(GC×GC/TOFMS).The results show that crude oil in the West slope is mainly heavy oil and its hydrocarbon composition is characterized overall by paraffinsmono-aromaticsnaphthenesnon-hydrocarbonsdi-aromaticstri-aromaticstetra-aromatics.Aromatics are most abundant and non-hydrocarbons are least abundant,whilst content differences among paraffins,naphthenes,aromatics,and non-hydrocarbons are less than 15%.There are two types of heavy oil,secondary type and mixing type.Biodegradation is the main formation mechanism of heavy oil.Biodegradation levels cover light biodegradation,moderate biodegradation,and severe biodegradation.With increasing biodegradation,paraffin content decreases while contents of aromatics and nonhydrocarbons increase.In contrast,naphthene content increases first and then decreases with increasing biodegradation.In severe biodegradation stage,naphthenes decrease more quickly than aromatics and non-hydrocarbons.This provides a new method for studying oil/heavy-oil biodegradation mechanism and biodegradation resistance of different hydrocarbons at different biodegradation stages.In the Longhupao-Daan terrace and Qijia-Gulong depression,most crude oil is conventional oil.Its composition is dominated by paraffins with the lowest content of aromatics.In some casual oil wells from the Longhupao-Daan terrace,crude oil from Saertu oil reservoirs is moderately biodegraded whereas crude oil from Putaohua oil reservoir is lightly biodegraded.Chemical parameters using saturate hydrocarbons and aromatics are usually not suitable for determining organic type and thermal maturity of biodegraded oil,especially of moderately or severely biodegraded oil,whilst Ts/(Ts+Tm)ratio can be used to determine thermal maturity of both conventional crude oil and heavy oil.     

1965-2012年甘肃平凉地区大雪天气气候特征

利用甘肃平凉地区7个气象自动站1965-2012年的逐日气象整编资料, 统计出近48 a来大雪天气出现次数, 分析了平凉大雪天气的统计特征和气候变化规律, 然后用近14 a历史天气图资料对31次大雪过程进行对比分型, 总结出三类天气形势的特征. 结果表明: 1965-2012年48 a来, 平凉大雪天气出现次数总体变化趋势不显著; 大雪天气多集中出现在秋冬、冬春冷暖季节交替的时期, 冬春交替期间出现次数多于秋冬交替期间, 隆冬季节出现次数相对较少. 平凉产生大雪天气的主要天气形势有三类: 高原低槽型、西风带小槽型和阻高-横槽型, 三类形势中最多的是高原低槽型, 其他两类出现概率相差不到10个百分点.     

淋洗剂乙二胺四乙酸对重金属污染土工程特性的影响

以重金属铅（Pb2+）污染土和淋洗剂乙二胺四乙酸（EDTA）为研究对象,通过批次试验研究了不同浓度EDTA的淋洗对Pb2+污染土的渗透特性、持水特性、压缩特性、抗剪强度等工程特性的影响,为淋洗修复后土壤的二次利用提供参数支持。基于矿物成分、孔隙结构等微观试验,揭示了土壤工程特性变化的内在机制。研究结果表明,当淋洗剂EDTA浓度从0增加到0.15 mol/L,经淋洗修复后的污染土壤pH值从7.94下降到5.12,渗透系数降低超过一个数量级,黏聚力降低50%以上,而内摩擦角增大,持水性能提高,孔隙比从0.81下降到了0.76。微观试验的结果表明,随着淋洗剂浓度的增大,土壤中的蒙脱石、钠长石和伊利石矿物含量减少,石英矿物含量增加,其中蒙脱石含量从7.87%下降到了0.07%,而石英矿物含量增加了11.09%;淋洗后土壤单位质量进汞量由0.22 ml/g降低到0.15 ml/g,土壤总孔隙体积减少。重金属污染土淋洗修复工程在考虑重金属去除率及经济性指标的同时,还应考虑淋洗剂对土壤工程特性的弱化。     

城市道路尘埃的磁性特征及其环境意义

城市环境磁性研究表明,道路尘埃中的粗颗粒磁性载体(频率磁化率系数χ′FD＜5%)多为人为源,磁性矿物以单畴和多畴状态的磁铁矿为主,同时含有少量的赤铁矿和其他磁性矿物;细颗粒磁性载体(χ′FD为7%～11%)多为自然源,磁化率较低(小于100×10-8 m3/kg).磁性物质在迁移时往往与粗一级粒径的尘埃颗粒相伴生,磁性参数(如磁化率)和重金属元素(如铅、锌)质量分数之间呈相关关系,它们之间的关系可以用回归分析方法确定.利用电镜分析、因子分析和聚类分析方法可以识别道路尘埃物质的污染源.因此,道路尘埃的磁性特征研究在城市环境评价中具有潜在的重要意义.     

降雨入渗时土坡中水土化学作用浅析

提出了土坡在降雨入渗过程中水土化学作用理论,简要分析其作用类型,阐述其作用主控因素,系统研究其溶解与沉淀作用、交换与吸附作用、氧化还原作用、以及水解与络合作用等水土化学作用机理,同时分析水土化学作用对土的强度与变形特性起到强化或弱化作用。     

Characterization of an Area Polluted by Copper and Zinc:the Relation between Soil Texture,Mineralogy and Pollutant Concentration

Abstract: Twenty-four soil samples were collected at three depths from an approximately 2.5 acre contaminated site in southern Piedmont (Italy) and then analyzed. The main soil parameters determined were: pH, Cation Exchange Capacity (CEC), particle size distribution, total organic carbon (TOC) content and retained metal concentration. The mineral phases were identified by X-Ray Powder Diffraction (XRPD). All of the samples contained Zn and Cu resulting from industrial contamination during the last century, and those obtained at depths of 20-40 cm consistently showed the highest levels. To determine which size fraction was most active in the retention process, the samples were separated into four fractions (≤2 mm, ≤63 μm, ≤30 μm and ≤2 μm) and the amount of pollutant measured in each. It was found that metal retention was the highest in the clayey fraction, whose clay minerals were identified by XRPD after K+ and Mg2+ saturation, glycerol treatment and heating to 550°C. The clayey fraction was also the richest in TOC, and a direct correlation between TOC amount and metal retention was observed.