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131.
Nour-Eddine Laftouhi Marnik Vanclooster Mohammed Jalal Omar Witam Mohamed Aboufirassi Mohamed Bahir Étienne Persoons 《Comptes Rendus Geoscience》2003,335(3):307-317
The Essaouira Basin (Morocco) contains a multi-layered aquifer situated in fractured and karstic materials from the Middle and Upper Cretaceous (the Cenomanian, Turonian and Senonian). Water percolates through the limestone and dolomite formations of the Turonian stage either through the marls and calcareous marls of the Cenomanian or through the calcareous marly materials of the Senonian. The aquifer system may be interconnected since the marl layer separating the Turonian, Cenomanian and Senonian aquifers is thin or intensively fractured. In that case, the water is transported through a network of fractures and stratification joints. This paper describes the extent of the nitrate pollution in the area and its origin. Most of the wells and drillholes located in the Kourimat perimeter are contaminated by nitrates with some concentrations over . Nitrate contamination is also observed in the surface water of the Qsob River, which constitutes the natural outlet of the multi-layered complex aquifer system. In this area, agriculture is more developed than in the rest of the Essaouira Basin. Diffuse pollution of the karstic groundwater body by agricultural fertiliser residues may therefore partially explain the observed nitrate pollution. However, point pollution around the wells, springs and drillholes from human wastewater, livestock faeces and the mineralisation of organic debris close to the Muslim cemeteries cannot be excluded. 相似文献
132.
A three‐dimensional numerical model was used to simulate the impact of different well‐field configurations on pump‐and‐treat mass removal efficiency for large groundwater contaminant plumes residing in homogeneous and layered domains. Four well‐field configurations were tested, Longitudinal, Distributed, Downgradient, and natural gradient (with no extraction wells). The reductions in contaminant mass discharge (CMDR) as a function of mass removal (MR) were characterized to assess remediation efficiency. Systems whose CDMR‐MR profiles are below the 1:1 relationship curve are associated with more efficient well‐field configurations. For simulations conducted with the homogeneous domain, the CMDR‐MR curves shift leftward, from convex‐downward profiles for natural gradient and Longitudinal to first‐order behaviour for Distributed, and further leftward to a sigmoidal profile for the Downgradient well‐field configuration. These results reveal the maximum potential impacts of well‐field configuration on mass‐removal behaviour, which is attributed to mass‐transfer constraints associated with regions of low flow. In contrast, for the simulations conducted with the layered domain, the CMDR‐MR relationships for the different well‐field configurations exhibit convex‐upward profiles. The nonideal mass‐removal behaviour in this case is influenced by both well‐field configuration and back diffusion associated with low‐permeability units. 相似文献
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Douglas H. Adams 《Marine pollution bulletin》2010,60(1):148-151
Wahoo, Acanthocybium solandri, are predatory oceanic fish that occur and are harvested in all tropical and subtropical oceans. Total mercury concentrations analyzed in dorsal muscle tissue of 208 wahoo from offshore waters of the southeastern United States and the Bahamas ranged from 0.021 to 3.4 mg/kg (wet weight), with a mean of 0.50 mg/kg (± 0.595 SD). Analyses indicated significant positive linear relationships between mercury and length, as well as, age of wahoo. The piscivorous nature, generally high trophic position, fast growth rate, and associated high metabolism of wahoo within tropical offshore pelagic environments may lead to comparatively higher concentrations of mercury over relatively short time periods. Mercury in wahoo, a highly mobile species consisting of one world-wide population, is regionally influenced by large-scale spatial differences in available mercury in selected prey fish species - many of which have been found to contain relatively high concentrations of mercury. 相似文献
136.
《Marine pollution bulletin》2013,77(1-2):139-145
The sorption of phenanthrene on the Yangtze Estuary sediment was studied under varying conditions of particle size, sediment organic contents, salinity, and dissolved organic matter (DOM) concentrations. Small sediment particles showed higher trapping capacity for phenanthrene due to the higher organic contents associated. The organic carbon-based partition coefficient of phenanthrene to the Yangtze Estuary sediment was obtained as 7120 L/kg, lower than the values for other soils or sediments reported in previous studies. The magnitude and direction of the salt effect were complicated by the specific DOM studied. The sediment sorption capacity was greatly increased in saline water in the absence of DOM but decreased in the presence of DOM. Given the conditions in the Yangtze Estuary, the equilibrium sorption of phenanthrene would be decreased with increasing salinity. Overall, the nature and content of both sediment-bound and dissolved organic matter dominate the sorption of hydrophobic organic contaminants in the estuary. 相似文献
137.
兰健 《中国海洋大学学报(自然科学版)》1996,(3)
根据基本的扩散方程,以污染物质输入量为已知条件,给出了一种近区稀释的半解析解。该半解析解摆脱了流速是单向的、持续的和定常的条件限制,反映了近区稀释在以潮流场为背景场的状态下,随时间的可变性。 相似文献
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A method has been developed to simulate the long‐term migration of radionuclides in the near‐surface of a river catchment, following their release from a deep underground repository for radioactive waste. Previous (30‐year) simulations, conducted using the SHETRAN physically based modelling system, showed that long‐term (many decades) simulations are required to allow the system to reach steady state. Physically based, distributed models, such as SHETRAN, tend to be too computationally expensive for this task. Traditional lumped catchment‐scale models, on the other hand, do not give sufficiently detailed spatially distributed results. An intermediate approach to modelling has therefore been developed which allows flow and transport processes to be simulated with the spatial resolution normally associated with distributed models, whilst being computationally efficient.The approach involves constructing a lumped model in which the catchment is represented by a number of conceptual water storage compartments. The flow rates to and from these compartments are prescribed by functions that summarize the results from physically based distributed models run for a range of characteristic flow regimes. The physically based models used were, SHETRAN for the subsurface compartments, a particle tracking model for overland flow and an analytical model for channel routing. One important advantage of the method used in constructing the lumped model is that it makes down scaling possible, in the sense that fine‐scale information on the distributed hydrological regime, as simulated by the physically based distributed models, can be inferred from the variables in the lumped model that describe the hydrology at the catchment scale. A 250‐year flow simulation has been run and the down scaling process used to infer a 250‐year time‐series of three‐dimensional velocity fields for the subsurface of the catchment. This series was then used to drive a particle tracking simulation of contaminant migration. The concentration and spatial distribution of contaminants simulated by this model for the first 30 years were in close agreement with SHETRAN results. The remaining 220 years highlighted the fact that some of the most important transport pathways to the surface carry contaminants only very slowly so both the magnitude and spatial distribution of concentration in surface soils are not apparent over the shorter SHETRAN simulations. Copyright © 1999 John Wiley & Sons, Ltd. 相似文献
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