黑龙江省农业地球化学初步研究

本文采用对比分析等数据处理方法将黑龙江省1:50万区域地球化学资料应用于农业问题的研究。通过将该省主要农作物产量与土壤、水系沉积物中地球化学元素分布进行对比,发现农作物产量与微量元素含量之间存在一定关联,其中Co对大豆,Zn对甜菜、小麦、水稻等农作物产量具有明显的影响,由此初步提出了黑龙江省农业地球化学种植区划。     

苏州地区I-A型花岗岩特征与成因的对比研究

应用岩石学、矿物学、地球化学及岩浆物理学等的理论和方法，对苏州地区Ｉ型和Ａ型花岗岩的特征及成因进行了对比研究，得出以下主要结论：Ｉ型花岗岩为晚侏罗世火山弧压性环境产物，侵位较深；而Ａ型者为Ａ２型花岗岩，为早白垩世造山后张性环境产物，侵位较浅，具晶洞构造．Ａ型比Ｉ型花岗岩以酸度、碱度、Ａｌ，Ｆ含量高而Ｈ２Ｏ＋含量低，以ＲＥＥ及不相容元素丰度高，负Ｅｕ异常强，而ｗ（ＬＲＥＥ）／ｗ（ＨＲＥＥ）低为特色．Ａ型者矿物结晶顺序先浅色后暗色，暗色矿物以富铁贫镁、ＲＥＥ分配系数高及负Ｅｕ异常明显及长石富碱贫钙，而与Ｉ型花岗岩不同．Ａ型者副矿物４０余种，属锆石－褐帘石－萤石型，锆石结晶温度高，（１１０），（１１１）晶面发育；而Ｉ型者仅１０余种，属榍石－锆石－磷灰石型，锆石结晶温度低，（１００），（３１１）晶面发育．Ｉ型花岗岩为幔源岩浆与下地壳部分熔融岩浆混合及ＡＦＣ作用产物，而Ａ型花岗岩为残余下地壳（麻粒岩相）熔融后分离结晶产物，二者并非同源岩浆演化关系．Ａ型比Ｉ型岩浆来源浅，酸度大，含水少；故岩浆密度小，粘度大，上升慢，冷凝长．受密度筛影响，Ａ型花岗岩岩浆房及侵位深度小于Ｉ型     

CAPPS在太原市本地化过程中的改进和应用

该文针对CAPPS在太原市运行的误差问题，在分析其主要原因的基础上，变换地形背景场，依据不同季节、不同天气形势，在模式中增加对综合误差系数和扬尘系数的调节功能，进行多种数值模拟试验。结果表明:在误差分析基础上确定的模拟试验方案，使主要污染物SO₂、NO_X和PM₁₀的预报值与监测值的相关系数分别提高到0.96、0.91和0.89，最终使CAPPS成为预报准确率稳定在90%以上的业务化数值模式系统。     

High-pressure experimental growth of diamond using C–K2CO3–KCl as an analogue for Cl-bearing carbonate fluid

High-pressure, high-temperature diamond growth experiments have been conducted in the system C–K₂CO₃–KCl at 1050–1420 °C, 7.0–7.7 GPa. KCl is of interest because of the strong effect of halogens on the phase relations of carbonate-rich systems [Geophys. Res. Lett. 30 (2003) 1022] and because of the occurrence of KCl coexisting with alkali silicate–carbonate fluids in natural-coated diamond [Geochim. Cosmochim. Acta 64 (2000) 717]. We have used system C–K₂CO₃–KCl as an analogue for these mantle fluids in diamond growth experiments. The presence of KCl reduces the potassium carbonate liquidus to ≤1000 °C at 7.7 GPa, allowing it to act as a solvent catalyst for diamond growth at temperatures below the continental geotherm. This is a reduction on the minimum diamond growth temperature reported in the alkali-carbonate–C–O–H system [Lithos 60 (2002) 145]. Diamond growth using carbonate solvent catalysts is characterised by a relatively long induction period. However, the addition of KCl also reduced the period for diamond growth in carbonate to 5 min; no such induction period appears to be necessary. It is suggested that KCl destabilises carbonate, allowing greater solubility and diffusion of carbon.     

Inviscid behaviour of fines-rich pyroclastic flows inferred from experiments on gas-particle mixtures

Experiments were carried out on granular flows generated by instantaneous release of gas-fluidised, bidisperse mixtures and propagating into a horizontal channel. The mixture consists of fine (< 100 μm) and coarse (> 100 μm) particles of same density, with corresponding grain size ratios of ∼ 2 to 9. Initial fluidisation of the mixture destroys the interparticle frictional contacts, and the flow behaviour then depends on the initial bed packing and on the timescale required to re-establish strong frictional contacts. At a fines mass fraction (α) below that of optimal packing (∼ 40%), the initial mixtures consist of a continuous network of coarse particles with fines in interstitial voids. Strong frictional contacts between the coarse particles are probably rapidly re-established and the flows steadily decelerate. Some internal friction reduction appears to occur as α and the grain size ratio increases, possibly due to particle rolling and the lower roughness of internal shear surfaces. Segregation only occurs at large grain size ratio due to dynamical sieving with fines concentrated at the flow base. In contrast, at α above that for optimal packing, the initial mixtures consist of coarse particles embedded in a matrix of fines. Flow velocities and run-outs are similar to that of the monodisperse fine end-member, thus showing that the coarse particles are transported passively within the matrix whatever their amount and grain size are. These flows propagate at constant height and velocity as inviscid fluid gravity currents, thus suggesting negligible interparticle friction. We have determined a Froude number of 2.61 ± 0.08 consistent with the dam-break model for fluid flows, and with no significant variation as a function of α, the grain size ratio, and the initial bed expansion. Very little segregation occurs, which suggests low intensity particle interactions during flow propagation and that active fluidisation is not taking place. Strong frictional contacts are only re-established in the final stages of emplacement and stop the flow motion. We infer that fines-rich (i.e. matrix-supported) pyroclastic flows propagate as inviscid fluid gravity currents for most of their emplacement, and this is consistent with some field data.     

海峡两岸旅游管理比较研究

中国大陆和台湾的旅游业都有良好的发展前景,由于体制和区情的不同,两地在旅游发展和旅游管理上有着诸多差异;由于文化上的同根同源,两地在旅游发展与管理上也存在着互补共融的关系.如何处理好竞争与合作、经济利益和可持续发展之间的关系,成为两岸学术界和旅游业工作者共同关注的课题.通过重点比较两岸在旅游管理方面的特点,找出了两岸的差异及差异存在的部分原因,以期能为两岸旅游业取长补短、互相促进、共同发展提供有价值的参考.     

智能卡和出租车轨迹数据中蕴含城市人群活动模式的差异性分析

当前采用交通流数据量化城市人群活动模式研究已经取得了丰硕的研究成果,但是对于同一区域、同一时段不同类型交通流数据反映城市人群活动模式的共性与差异性仍然知之甚少,直接影响了城市人群活动模式挖掘结果的可解释性与实际应用效果。为此,本文旨在对目前广泛采用的智能卡数据（公交和地铁刷卡）和出租车轨迹数据2种重要的交通流数据,从时空分布模式的差异性、行程距离及距离衰减效应的差异性、空间社团结构的差异性3个方面,探索二者反映城市人群活动模式的差异性：① 采用北京市六环以内区域2016年5月9日至15日的智能卡和出租车轨迹数据进行实验分析,研究发现：① 2种交通流反映出行需求的空间分布呈现出高度相关性,但是在同一空间单元上,2种交通流反映出行需求的时间相关性较低;② 2种交通流的使用率在不同空间位置存在明显差异,仅在城市中心区域使用率较为均衡;③ 2种交通流反映人群行程距离的空间分布、距离衰减效应存在明显差异,公共交通对于促进长距离出行更为重要;④ 从2种交通流发现的空间社团结构都显示了城市的多中心结构特征,但是二者发现社团结构存在的差异性表明两种交通方式对城市空间交互起着不同的作用。本研究有助于深入理解多源交通流反映城市人群活动的内在机理,提升城市人群活动模式在城市规划、交通管理等领域的应用效果。     

Elastoplastic model with loading memory surfaces (LMS) for monotonic and cyclic behaviour of geomaterials

A new elastoplastic model called loading memory surface based on the critical state concept and the multi‐surface framework is proposed for geomaterials. The model uses a hypoelastic formulation and two plastic mechanisms. The formulations of the model are made in three‐dimensional stress–strain space and work under both monotonic and cyclic loadings. A newly introduced formalism makes it possible to obtain the cyclic response directly from the monotonic loading one. This formalism gives a three‐dimensional generalization of the well‐known Masing rule. The model has been validated against test results of Hostun sand under several conditions: monotonic and cyclic, drained and undrained, tests in compression and in extension, and at different confining pressures and different densities. Copyright © 2014 John Wiley & Sons, Ltd.     

Modelling and experimental study of coupled exchange of p,p′‐DDE and colloids in a flume simulated stream–streambed system

Stream–subsurface exchange plays a significant role in the fate and transport of contaminants in streams. It has been modelled explicitly by considering fundamental processes such as hydraulic exchange, colloid filtration, and contaminant interactions with streambed sediments and colloids. The models have been successfully applied to simulate the transport of inorganic metals and nutrients. In this study, laboratory experiments were conducted in a recirculating flume to investigate the exchange of a hydrophobic organic contaminant, p,p′‐dichloro‐diphenyl‐dichloroethane (DDE), between a stream and a quartz sand bed. A previously developed process‐based multiphase exchange model was modified by accounting for the p,p′‐DDE kinetic adsorption to and desorption from the bed sediments/colloids and was applied to interpret the experimental results. Model input parameters were obtained by conducting independent small‐scale batch experiments. Results indicate that the immobilization of p,p′‐DDE in the quartz sand bed can occur under representative natural stream conditions. The observed p,p′‐DDE exchange was successfully simulated by the process‐based model. The model sensitivity analysis results show that the exchange of p,p′‐DDE can be sensitive to either the sediment sorption/desorption parameters or colloidal parameters depending on the experimental conditions tested. For the experimental conditions employed here, the effect of colloids on contaminant transport is expected to be minimal, and the stream–subsurface exchange of p,p′‐DDE is dominated by the interaction of p,p′‐DDE with bed sediment. The work presented here contributes to a better mechanistic understanding of the complex transport process that hydrophobic organic contaminants undergo in natural streams and to the development of reliable, predictive models for the assessment of impacted streams. Copyright © 2015 John Wiley & Sons, Ltd.     

Diffusive mass exchange of non‐reactive substances in dual‐porosity porous systems – column experiments under saturated conditions

Diffusive mass exchange into immobile water regions within heterogeneous porous aquifers influences the fate of solutes. The percentage of immobile water is often unidentified in natural aquifers though. Hence, the mathematical prediction of solute transport in such heterogeneous aquifers remains challenging. The objective of this study was to find a simple analytical model approach that allows quantifying properties of mobile and immobile water regions and the portion of immobile water in a porous system. Therefore, the Single Fissure Dispersion Model (SFDM), which takes into account diffusive mass exchange between mobile and immobile water zones, was applied to model transport in well‐defined saturated dual‐porosity column experiments. Direct and indirect model validation was performed by running experiments at different flow velocities and using conservative tracer with different molecular diffusion coefficients. In another column setup, immobile water regions were randomly distributed to test the model applicability and to determine the portion of immobile water. In all setups, the tracer concentration curves showed differences in normalized maximum peak concentration, tailing and mass recovery according to their diffusion coefficients. These findings were more pronounced at lower flow rates (larger flow times) indicating the dependency of diffusive mass exchange into immobile water regions on tracers' molecular diffusion coefficients. The SFDM simulated all data with high model efficiency. Successful model validation supported the physical meaning of fitted model parameters. This study showed that the SFDM, developed for fissured aquifers, is applicable in porous media and can be used to determine porosity and volume of regions with immobile water. Copyright © 2015 John Wiley & Sons, Ltd.