人工合成宝石级翡翠的研究

本文以对化学试剂为原料，用静奇谈怪论同温高压固相转变法合成宝石级翡翠的机理和工艺条件进行了实验研究，测定了与硬玉化学组分相同的玻璃物质的高压熔融曲线和固相转变的区域，提出了在熔融曲线左侧附近固相区生长优质硬玉的观点，以及在宝石级悲翠合成中的若干技术问题。     

Aerosol polarized phase function and single-scattering albedo retrieved from ground-based measurements

Aerosol optical parameters, polarized phase function and single-scattering albdeo, have been retrieved from ground-based sun photometer measurements in Beijing 2003. The measured aerosol optical thickness varies from 0.12 to 0.77 with an average value of 0.39. The measured Ångström coefficient ranges from 0.75 to 1.47 with an average value of 1.21. The retrieved single-scattering albedo at 870 nm is within the 0.76–0.94 range and the average value is 0.85, suggests there are considerable aerosol absorptions in Beijing. The maximum value of retrieved polarized phase function at 870 nm ranges from 0.068 to 0.225 with an average value of 0.16, and it illustrates good correlations with the Ångström coefficient, i.e. the relative size of aerosol particles. Analyses of measurements and theoretical calculations show the polarized phase function is sensitive to aerosol size distribution and complex refractive index, especially the imaginary part of the refractive index which denotes aerosol light absorbing effects. These results suggest that the polarized phase function is an effective and unique aerosol optical parameter and is able to improve the retrieval of aerosol physical properties.     

Molecular modeling of the 10-Å phase at subduction zone conditions

Molecular dynamics (MD) modeling of the 10-Å phase, Mg₃Si₄O₁₀(OH)₂·xH₂O, with x=2/3, 1.0 and 2.0 shows complex structural changes with pressure, temperature and water content and provides new insight into the structures and stabilization of these phases under subduction zone conditions. The structure(s) of this phase and its role as a reservoir of water in the mantle have been controversial, and these calculations provide specific predictions that can be tested by in situ diffraction studies. At ambient conditions, the computed structures of talc (x=0) and the 10-Å phases with x=2/3 and 1.0 are stable over the 350-ps period of the MD simulations. Under these conditions, the 10-Å phases show phlogopite-like layer stacking in good agreement with previously published structures based on powder X-ray diffraction data for samples quenched from high-pressure and high-temperature experiments. The calculations show that the 10-Å phase with x=2.0 is unstable at ambient conditions. The computed structures at P=5.5 GPa and T=750 K, well within the known stability field of the 10-Å phase, change significantly with water content, reflecting changing H-bonding configurations. For x=2/3, the layer stacking is talc-like, and for x=1.0, it is phlogopite-like. The calculations show that transformation between these two stackings occurs readily, and that the talc-like stacking for the x=2/3 composition is unlikely to be quenchable to ambient conditions. For x=2.0, the layer stacking at P=5.5 GPa and T=750 K is different than any previously proposed structure for a 10-Å phase. In this structure, the neighboring basal oxygens of adjacent magnesium silicate layers are displaced by b/3 (about 3 Å) resulting in the Si atoms of one siloxane sheet being located above the center of the six-member ring across the interlayer. The water molecules are located 1.2 Å above the center of all six-member rings and accept H-bonds from the OH groups located below the rings. The b/3-displaced structure does not readily transform to either the talc-like or phlogopite-like structure, because neither of these stackings can accommodate two water molecules per formula unit. There is likely to be a compositional discontinuity and phase transition between the b/3-displaced phase and the phase with phlogopite-like stacking. The simulations reported here are the first to use the recently developed CLAYFF force field to calculate mineral structures at elevated pressures and temperatures.     

应用GMS5多通道云图估计降水技术的研究

对近两年来5～8月中国东部地区120多个测站雨量观测资料和对应4400多幅GMS-5四个通道云图的研究发现：红外亮温的时间、空间变率、红外和水汽通道亮温差等云图衍生资料对消除卷云，弥补夜间缺少可见光云图的不足起到明显作用。从而，应用双判据双重MOS多元回归法建立四通道云图因子、衍生因子与降水量之间的回归方程，进行6小时分级降水估计。为了进一步消除厚卷云和特殊地形的影响，提出使用逐日实时资料自动建立多元回归方程估计降水量，从而对双判据双重MOS多元回归法估计结果进行校正。上海中心气象台的业务使用表明，总体估计的准确率达70％左右。     

用混合和扩散云室对大气冰核浓度的观测分析

继1963年用混合云室对春季冰核浓度观测之后，1994～1996年，在同季节、同地点用混合和静力扩散云室又做了同步观测。对取得的资料进行整理分析，得出了凝华核浓度在不同天气背景下占总冰核浓度的百分比，两种云室测值的对应关系；分析了扩散云室的容积效应及冰核浓度随气压、能见度等气象因子的变化。     

青海对流云数值模拟分析

利用中国气象科学研究院三维对流云模式和2002年青海省河南县秋季外场试验取得的资料，进行了数值模拟试验。该地区秋季对流云降水主要为冷云降水，暖雨过程不易启动。降雨主要是由于霰落入暖层融化，雨水的蒸发是雨水减少的主要机制。霰在降水的产生中发挥了重要作用。霰的生成又与冰晶密切相关。冰晶是霰的主要来源，而且也是霰生长的主要因素。初始的霰粒主要由冰霰自动转化生成，而较少由雨滴冻结生成。霰胚通过收集过冷云水和冰晶与霰的碰并又促进了霰的进一步生长。冰晶的生成主要是由于自然冰核的核化，因此，自然冰核的数浓度对整个降水过程都有影响。霰是云中过冷水消耗的主要因素。     

北疆降雹云团卫星云图特征的分类研究

北疆降雹云团按其卫星云图特征分为对流性和系统性两大类，又将对流性降雹云团按尺度大小分为雷暴云和对流云，系统性降雹云团按所处位置分为冷云核、云系云区和云系边缘。据此方法对1998-2001年4-9月期间北疆出现310个降雹云团进行归类分析。北疆降雹云团以对流性云团为主，它们尺度小、形状不规则、云顶亮温较高。主要出现在北疆西部和北疆沿天山中段。各类降雹云团在各地区的出现机率不同。     

北京市春夏季大气气溶胶的单颗粒分析表征

采集了北京市2000年春夏季大气气溶胶样品5个，采用扫描电镜X射线能谱技术分析大气气溶胶单颗粒约2500个。研究结果表明，沙尘期间，矿物尘是最主要的颗粒物种类，非沙尘期间，北京市大气气溶胶中主要检出矿物尘和含硫颗粒物。夏季随着颗粒物污染的加重，含硫颗粒物的数目百分数增加。是北京市大气颗粒物污染的重要特征。重点讨论了Ca-S颗粒、K-S颗粒和Ca-K-S颗粒三类典型含硫颗粒物的化学组成和粒径分布特征。数目可观的Ca-K-S颗粒以及其他硫酸盐颗粒的生成与相对湿度和云量等气象条件相关，这些颗粒物可能是云中过程的产物。减少SO2排放，减少含硫颗粒物，对于控制北京市的大气颗粒物浓度水平具有重要意义。