青海对流云数值模拟分析

利用中国气象科学研究院三维对流云模式和2002年青海省河南县秋季外场试验取得的资料，进行了数值模拟试验。该地区秋季对流云降水主要为冷云降水，暖雨过程不易启动。降雨主要是由于霰落入暖层融化，雨水的蒸发是雨水减少的主要机制。霰在降水的产生中发挥了重要作用。霰的生成又与冰晶密切相关。冰晶是霰的主要来源，而且也是霰生长的主要因素。初始的霰粒主要由冰霰自动转化生成，而较少由雨滴冻结生成。霰胚通过收集过冷云水和冰晶与霰的碰并又促进了霰的进一步生长。冰晶的生成主要是由于自然冰核的核化，因此，自然冰核的数浓度对整个降水过程都有影响。霰是云中过冷水消耗的主要因素。     

北京市春夏季大气气溶胶的单颗粒分析表征

采集了北京市2000年春夏季大气气溶胶样品5个，采用扫描电镜X射线能谱技术分析大气气溶胶单颗粒约2500个。研究结果表明，沙尘期间，矿物尘是最主要的颗粒物种类，非沙尘期间，北京市大气气溶胶中主要检出矿物尘和含硫颗粒物。夏季随着颗粒物污染的加重，含硫颗粒物的数目百分数增加。是北京市大气颗粒物污染的重要特征。重点讨论了Ca-S颗粒、K-S颗粒和Ca-K-S颗粒三类典型含硫颗粒物的化学组成和粒径分布特征。数目可观的Ca-K-S颗粒以及其他硫酸盐颗粒的生成与相对湿度和云量等气象条件相关，这些颗粒物可能是云中过程的产物。减少SO2排放，减少含硫颗粒物，对于控制北京市的大气颗粒物浓度水平具有重要意义。     

四川新康风化淋滤型海泡石的热相变研究

以四川新康风化淋滤型海泡石为研究对象，利用X射线衍射分析和红外光谱分析技术，对海泡石的热相变过程及特征进行了研究。结果发现，四川新康风化淋滤型海泡石的相变过程与沉积型、热液型海泡石相变过程明显不同，其相变过程可以划分为两个阶段：800℃以下保持海泡石相；800℃以上海泡石相转化为斜顽辉石相。     

The magmatic to hydrothermal transition and its bearing on ore-forming systems

The exsolution of volatile phases from silicate magmas controls physical and chemical magma properties and influences large-scale geologic phenomena and processes having major societal and economic implications including the release of climate-altering gases to the atmosphere, the explosivity of volcanic eruptions, hydrothermal alteration, and the generation of magmatic–hydrothermal mineralization. These volatile phases exsolve from a wide variety of magmas and cover a very broad spectrum of compositions.

The transition from the orthomagmatic to the hydrothermal stages has important bearing on these fundamentally important geologic phenomena, and this report summarizes the published results of a dozen scientific investigations on the magmatic–hydrothermal transition as applied to volcanic eruption and magmatic–hydrothermal mineralization. These studies involve a variety of analytical and experimental methodologies, and many focus on fluid and melt inclusions from mineralized magmatic systems. A primary goal of each study is to better understand the role of magmatic volatiles and the importance of the magmatic–hydrothermal transition on these geologic processes.     

The structural role of Ti in aluminosilicate liquids in the glass transition range: insights from heat capacity and shear viscosity measurements

The shear viscosities and 1 bar heat capacities of glasses and melts along the 67mol% silica isopleth in the system SiO₂-Al₂O₃-Na₂O-TiO₂ have been determined in the temperature ranges 780-1140 K and 305-1090 K respectively. Anomalous behaviour of both these properties is observed for compositions rich in TiO₂ and/or Al₂O₃, an observation attributed to liquid-liquid phase separation followed by anatase crystallization. For samples which do not show anomalous behaviour, it is found that the partial molar heat capacity of the TiO₂ component previously determined in Al-free compositions reproduces our heat capacities to within 1.3%. Viscosity data show that addition of TiO₂ tends to increase viscosity and melt fragility at constant temperature. Furthermore, heat capacity and viscosity data may be combined within the framework of the Adam-Gibbs theory to extract values of the configurational entropy of the liquids and qualitative estimates of the variation of the average energy barrier to viscous flow. Configurational entropy at 900K is inferred to decrease upon addition of TiO₂, in contrast to previous results from Al-free systems. The compositional limit separating normal from anomalous behaviour, as well as the data for homogenous melts have been used to constrain the structural role of Ti in these samples. Our data are consistent with a majority of Ti in five-fold coordination associated with a titanyl bond, in agreement with previous spectroscopic studies. Furthermore, we find no evidence for a Ti-Al interaction in our samples, and we are led to the conclusion that Al and Ti are incompletely mixed, a hypothesis consistent with the observed reduction of configurational entropy upon addition of TiO₂, suggesting an important role of medium range order in controlling the variations in thermodynamic properties.     

海洋平流的季节变化对La Nia事件成熟位相锁定的作用

用一个中等复杂程度的热带海气耦合模式模拟LaNi na事件成熟位相锁定在年底左右的特征并研究其形成的机制。结果表明 ,模式能很好地模拟观测到的LaNi na事件成熟位相锁定在年底左右的特征。LaNi na事件成熟位相锁定在年底主要由海洋气候基本态引起。海洋垂直平均流是LaNi na事件成熟位相锁定在年底左右的最主要因子。由海洋气候基本态的季节变化所引起的冷平流的季节变化是LaNi na事件成熟位相锁定在年底的机制。在LaNi na事件期间 ,1～ 5月份 ,赤道中东太平洋地区的冷平流较弱 ,它不能平衡海气热量交换过程的影响 ,因而海洋表面温度增加。这一过程使海气耦合不稳定度减弱 ,从而使LaNi na事件衰减。 6～ 12月份 ,赤道中东太平洋地区的冷平流较强。海气热量交换过程的影响不能平衡较强冷平流的影响 ,因而海洋表面温度减小。这一过程使海气耦合不稳定度加强 ,从而使LaNi na事件发展。这样 ,LaNi na事件成熟位相容易出现在年底左右。     

闽东北地区夏季对流云特征的初步分析

利用新一代天气雷达资料分析闽东北地区夏季对流云的回波特征。分析表明:多单体合并对流云在生命史、回波高度、强度、尺度等方面都超过了单体对流云,其液态水总量也更大,自然降水条件和人工影响潜力都优于单体对流云,是夏季降水和人工催化的重要云系。分析得到对流云发展的不同阶段、不同高度层辐合辐散特点,为进一步研究夏季对流云结构和降水原理提供科学依据。通过对两个个例的天气形势分析,指出冷空气对对流发展有一定的激发作用。     

Variation of the plasma turbulence in the central plasma sheet during substorm phases observed by the interball/tail satellite

Fluctuations of the plasma bulk velocity across the plasma sheet are studied using single-point measurements from the Corall instrument on board the Interball/Tail satellite. Several hour-long intervals of continuous data corresponding to quiet geomagnetic conditions and different phases of isolated substorms are analyzed. The plasma sheet flow appears to be strongly turbulent, i.e. dominated by fluctuations that are unpredictable. Corresponding eddy diffusion coefficients were obtained as a function of the autocorrelation time and rms velocity of the fluctuations. It was found that the amplitude of the turbulence and the values of eddy-diffusion coefficients increase significantly during substorm growth and expansion phases and they decrease to their initial level during the recovery phase. We also studied a relationship between the eddy-diffusion coefficients and the absolute value of the geomagnetic field, also measured by the Interball/Tail satellite. It was found that this relationship varies depending on the phase of substorm, indicating possible change in the turbulence regimen with substorm phase.     

Experimental and theoretical study of stability of dense hydrous magnesium silicates in the deep upper mantle

Fluid-undersaturated experiments were conducted to determine the phase relations in the simplified peridotite system MgO-SiO₂-H₂O (MSH) at 11.0-14.5 GPa and 800-1400 °C. Stability relations of dense hydrous magnesium silicates (DHMSs) under fluid-undersaturated conditions were experimentally examined. From the fluid-absent experimental results, we retrieved thermodynamic data for clinohumite, phase A, phase E, and hydrous wadsleyite, consistent with the published data set for dry mantle minerals. With this new data set, we have calculated phase equilibria in the MSH system including dehydration reactions. The dehydration reactions calculated with lower water activities of 0.68-0.60 match the fluid-present experiments of this study above 11.0 GPa and 1000 °C, indicating that considerable amounts of silicate component were dissolved into the fluid phase. The calculated phase equilibria illustrate the stability of the post-antigorite phase A-bearing assemblages. In the cold subducting slab peridotite, phase A + enstatite assemblage survives into the transition zone, whereas phase A + forsterite + enstatite assemblage forms hydrous wadsleyite at a much shallower depth of about 360-km. The slab is subducted with no dehydration reactions occurring when entering the transition zone. The phase equilibria also show the high temperature stability of phase E. Phase E is stable up to 1200 °C at 13.5 GPa, a plausible condition in the mantle of relatively low temperature, i.e., beneath subduction zones. Phase E is a possible water reservoir in the mantle as well as wadsleyite and ringwoodite.