Hydrogeochemical controls on surface and groundwater chemistry in naturally acidic, porphyry-related mineralized areas, southern Rocky Mountains

In southern Rocky Mountains, catchments characterized by acidic, metalliferous waters that are relatively unaffected by human activity usually occur within areas that have active or historical mining activity. The US Geological Survey has utilized these mineralized but unmined catchments to constrain geochemical processes that control the surface- and ground-water chemistry associated with near surface acid weathering as well as to estimate premining conditions. Study areas include the upper Animas River watershed, Lake City, Mt. Emmons, and Montezuma in Colorado and Questa in New Mexico. Although host-rock lithologies range from Precambrian gneisses to Cretaceous sedimentary units to Tertiary volcanic complexes, mineralization is Tertiary in age and associated with intermediate to felsic composition, porphyritic plutons. Pyrite is ubiquitous. Variability of metal concentrations in water is caused by two main factors： mineralogy and hydrology. Parameters that potentially affect water chemistry include： host-rock lithology, intensity of hydrothermal alteration, sulfide mineralogy and chemistry, gangue mineralogy, length of flow path, precipitation, evaporation, and redox conditions. Springs and headwater streams have pH values as low as 2.5, sulfate up to 3700 mg/L and high dissolved metal concentrations （for example： Al up to 170 mg/L; Fe up to 250 mg/L; Cu up to 3.5 mg/L and Zn up to 14 mg/L）. With the exception of evaporative waters, the lowest pH values and highest Fe and Al concentrations occur in water draining the most intense hydrothermally altered areas consisting of the mineral assemblage quartz-sericite-pyrite. Stream beds tend to be coated with iron floc, and some reaches are underlain by ferricrete. When iron-rich ground water interacts with oxygenated waters in the stream or hyporheic zone, ferrous iron is oxidized to ferric iron, which is less soluble, leading to the precipitation of iron oxyhydroxides.     

Effects of human activities on mercury in the environment in Xi＇an area, China

Effects of mercury on ecosystems and human health are well documented. Human activities have significant impacts on transport, transformation, and fate of mercury in the natural environment. In this study, a gold mining area （Tongchuan）, an urban area （Xi＇an）, and a historical site （Qinshihuan Tomb） in Shaanxi Province, China, was chosen to study the effects of human activities on the transport, transformation, and fate of mercury in the area. Samples of atmospheric precipitate, soil, sediment, pomegranate, corn and those from wells and the rivers that flow through or flow by the city and from the mining area were collected. The EPA methods were used for sample preparation and analysis of these samples. These methods combine acid digestion, chemical reduction, purge and trap with Cold Vapor Atomic Fluorescence Spectrometry （CVAFS）. Preliminary results showed high total mercury concentrations in the water samples collected from a river in Tongguan County. The total mercury concentrations ranged from 133 to 188 ng/L in the water samples collected from the rivers flowing through Xi＇an City. The amount of total mercury in the soil/sediment samples which were collected in the vicinity of Xi＇an ranged from 31.8 to 83.2 ng/g. The total mercury concentrations in the samples of atmospheric precipitate （including rain and snow collected from Sep. 2005 to Jan. 2006） ranged from 106-298 ng/L.     

An approximate projection of availability of the fresh groundwater resources in the South West district of NCT Delhi, India: a case study

The future availability and sustainability of fresh groundwater resources in the South West district of the national capital territory (NCT) Delhi, India, have been projected. Due to a rapid decline in groundwater level and quality, the district has been required by the Government of India to regulate development of groundwater resources. Shallow groundwater is mostly saline and water resources in the area are limited. The methodology applied here involves microzonation of the district in terms of thickness of fresh groundwater and then quantification of present and future availability of freshwater in different freshwater zones, including tentative timescales. The calculation method has been aided by data on historic trends in water level at representative groundwater monitoring stations, located either in fresh groundwater zones or near to them. It is estimated that the presently available 481 million m³ of resources will be reduced to 374 million m³ by year 2007 and to 303 million m³ by the year 2012, and by the year 2022 the district will have only 176 million m³ of available fresh groundwater resources.     

Study of geothermal water intrusion due to groundwater exploitation in the Puebla Valley aquifer system, Mexico

Significant intrusion of geothermal water into fresh groundwater takes place in the Puebla Valley aquifer system, Mexico. The decline in the potentiometric surface due to the overexploitation of the groundwater induces this intrusion. This hydrological system comprises three aquifers located in Plio-Quaternary volcanic sediments and Mesozoic calcareous rocks. The hydraulic balance of the aquifer shows that the annual output exceeds the natural inputs by 12 million m³. Between 1973 and 2002, a drop in the potentiometric surface, with an 80 m cone of depression, was identified in a 5-km-wide area located southwest of the city of Puebla. Chemical analyses performed on water samples since 1990 have shown an increase in total dissolved solids (TDS) of more than 500 mg/L, coinciding with the region showing a cone of depression in the potentiometric surface. A three-dimensional flow and transport model, based on the hydrogeological and geophysical studies, was computed by using the MODFLOW and MT3D software. This model reproduces the evolution of the aquifer system during the last 30 years and predicts for 2010 an additional drawdown in the potentiometric surface of 15 m, and an increase in the geothermal water intrusion.     

Damage Survey of Water Supply Systems and Fragility Curve of PVC Water Pipelines in the Chi–Chi Taiwan Earthquake

Substantial damage to water supply systems, including water delivery pipelines, water treatment plants, reservoirs, and water storage tanks, was reported after the 1999 Chi–Chi Taiwan Earthquake. This paper first summarizes the damage survey and then presents the results of seismic fragility analysis for underground pipelines. Construction blueprints of the water delivery pipelines and repair work orders of 11 townships and cities in the disastrous area were digitized into a Geographical Information System (GIS) for analysis and assessment. With the aid of the GIS system, we found that PVC pipes made up 86% of water delivery pipelines while steel, cast iron, ductile iron, PE and others took the rest. Therefore, this paper focuses on the fragility analysis of PVC pipes. Three different methods were applied to derive the fragility relations between the PVC water pipes having nominal diameters (approximately inner diameters) greater than or equal to 65 mm and earthquake intensity parameters such as peak ground acceleration and peak ground velocity. The results were then examined with those of other countries. The discrepancy between our results and the empirical equation used by HAZUS, an earthquake loss estimation software developed by the Federal Emergency Management Agency was not significant.     

紫色丘陵区水土保持林低效化的土壤成因

四川盆地紫色丘陵区的水土保持林低效化问题已较严重。研究了其土壤方面的成因。通过对土壤构造、土壤肥力特性、土壤结构性评价等研究，指出该区人工林地的土壤构造发育不正常，土壤腐殖质胶体积累量低。土壤结构质量差等林地土壤退化是土壤水土保持功能降低的主要原因。根据研究的初步结果，提出了相应的对策建议。     

Planning for source water protection in Ontario

Ontario began developing a drinking water source protection planning process in 2000, after a rural community's water supply was contaminated by pathogens from agricultural runoff. An expert committee report has recommended legislating a new source protection “sphere of jurisdiction” for municipalities; however, no specific new municipal tools or authorities have been proposed as yet. This paper reports findings from an evaluation of the extent to which existing institutional arrangements for land use planning and water management facilitate or constrain source protection by municipalities. A case study of the Regional Municipality of Waterloo suggests there is the potential to link land use planning more strongly to water management through creative use of existing tools, forgoing the need for major institutional changes.     

Transparency: aid or obstacle to effective defence of vulnerable environments from reservoir construction? Dam decisions and democracy in North East England

Public participation in transparent decisionmaking has been proposed as a panacea for environmental protection. Bargaining theory suggests drawbacks to transparency such as hardening of attitudes and intransigence. Yet achievement of consensus on environmental values for integrated water resource management demands public involvement. Historical study of attempts to prevent reservoir construction in upland valleys designated for protection of nature suggests that 'closed-door' bargaining proved more effective for environmentalists than open, public debate. Records now open for analysis of disputes over Teesdale and Farndale, 1950–1970, allow comparisons to be made between behind-the-scenes deliberations and 'open-door' public discussion. The ambition of progressing from public participation to devolution of environmental decisionmaking and responsibility to the local scale demands more conceptualization of the process of decisionmaking on water resource development.     

Subaltern strategies and development practice: urban water privatization in Ghana

This paper is concerned with subaltern actions providing alternatives to development practice. I use Ghana's attempt at urban water privatization to illustrate that Ghana's development practice is characterized by a dependence on foreign sources of capital and expertise that illustrates a psyche and mindset of Eurocentrism associated with the elite and decisionmakers of the country. The rationale for water privatization, the how of privatization, and the anti-development opposition to privatization not only demonstrate this dependency but also the extent to which decisionmakers are willing to sacrifice sovereignty and culturally sensitive ways of doing things, to global capital, in exchange for development funds. In the state's zeal for Western or Occidental development, subalterns in Ghana have devised hybridities that are post-traditional and Oriental in nature to solve their water problems. These development solutions are couched within structures provided to human agency and suggest that development practice should therefore listen to subalterns in terms of how they imagine and solve their problems. The concern with subaltern voices shows the relationship between postcolonial studies and development practice.     

Dissolved trace elements in river water: spatial distribution and the influencing factor, a study for the Pearl River Delta Economic Zone, China

Twenty-nine water samples were collected from different river channels of the Pearl River Delta Economic Zone, China. An inductively coupled plasma-mass spectromonitor (ICP-MS) was used to measure concentrations of the trace elements in these samples. The results suggest that the average concentrations of rare earth elements in river water show an increasing trend from the West River, the North River, the rivers of the Pearl River Delta, and the Shenzhen River to the East River. Relatively high concentrations of heavy metals appear in the East River, the rivers of the Pearl River Delta and the Shenzhen River, while the West River and the North River have relatively low heavy metal concentrations. Trace element concentrations in samples collected near urban or industrial areas are much higher than those of samples collected from distant areas, away from urban and industrial areas. After natural conditions, human activities have significant influence on the trace element concentrations in river water. This trace element concentration’s spatial distribution in the river water from the Pearl River Delta Economic Zone is actually an integrated effect of natural conditions and human activity.