民居CO中毒事件气象条件分析及数值模拟

应用伯努利原理和CFD应用软件FLUENT,对影响北方民居通风排烟和CO中毒事件的气象因子进行分析和数值模拟,研究基于气象条件的CO中毒事件预警方法。结果表明：影响民居通风排烟的气象条件主要有风速、气温（室内外温度差）、变压和相对湿度等。风速是影响通风排烟和CO中毒的主要气象因素;在弱风条件下,室内外温度差和气压的变化对通风排烟也有重要影响。在上述工作基础上,建立了民居通风排烟气象指数的计算方法和基于气象条件的CO中毒事件预警方法,经检验表明该方法对中毒事件有一定的预警能力。     

温室气体源汇及其对气候影响的研究进展

从与人类活动密切相关的温室气体（CO2、CH4、N2O）源汇研究以及温室气体对气候环境的影响等方面论述温室气体研究进展.介绍了国内外有关温室气体源和汇研究,如岩溶系统碳循环、黄土中温室气体组分特征、森林和大陆边缘海二氧化碳、稻田和湿地甲烷排放等方面的研究成果和认识.介绍了冰芯温室气体的部分研究成果和国内外温室气体与气候关系研究中涉及的一些模式及重要结论.结合温室气体源汇及其与气候变化,指出了目前应重视的一些研究内容,如研究陆地和海洋生态系统的碳氮循环问题,温室气体浓度变化与气候变化的相互关系以及气候变化机制.     

Ab initio study on carbon Kinetic Isotope Effect (KIE) in the reaction of CH4+Cl•

Recent studies suggest that the destruction of methane by Cl in the marine boundary layer could be accounted for as another major sink besides the methane destruction by OH. High level ab initio molecular orbital calculations have been carried out to study the CH₄+Cl reaction, the carbon Kinetic Isotope Effect (KIE) is calculated using Conventional Transition-State Theory (CTST) plus Wigner and Eckart semiclassical tunneling corrections. The calculated KIE is around 1.026 at 300 K and has a small temperature variation. This is by far the largest KIE among different processes involving atmospheric methane destruction (e.g., OH, soil). A calculated mass balance of atmospheric methane including the KIE for the CH₄+Cl reaction is found to favor those methane budgets with enhanced biological methane sources, which have relatively lighter carbon isotope composition.     

Trace Gas Measurements Between Moscow and Vladivostok Using the Trans-Siberian Railroad

Using a laboratory wagon traveling along the Trans-Siberian railroad, O₃, NO, NO₂, CO, CH₄, SF₆ and black carbon aerosol have been measured during the summer of 1996. The expedition from Niznij Novgorod (500 km east of Moscow) to Vladivostok (and back to Moscow) has shown the great potential of the train method; here the first results are presented and discussed. A wealth of boundary layer air data was obtained during the over 18000 km travel without serious contamination problems from the electric train itself. The diurnal O₃ cycle peaked generally below 50 nmole/mole, showed the effects of changes in J(NO₂), and often dropped to a few nmole/mole at night time during inversions. Over the vast Siberian lowlands situated between the Ural mountains and the river Yenisey, CH₄ levels were consistently elevated at around 1.95 µmole/mole, which we mainly attribute to wetland emissions. Over eastern Siberia, however, CH₄ levels were generally lower at 1.85 µmole/mole. In contrast, over the west Siberian lowlands, CO levels were relatively low, often reaching values of only 110 nmole/mole, whereas over eastern Siberia CO levels were higher. Very high CO levels were detected over a 2000 km section east of Chita, along the river Amur, which represented an enormous polluted air mass. ¹⁴C analysis performed on several CO samples confirms that the origin was biomass burning. SF₆, which was measured as a general conserved tracer, showed an eastward attenuation from 4.0 to 3.9 pmole/mole, with peaks in a number of places due to local Russian emissions.     

Fourier transform infrared studies of the reaction of Cl atoms with PAN,PPN, CH3OOH,HCOOH, CH3COCH3 and CH3COC2H5 at 295±2 K

The relative rate technique has been used to measure rate constants for the reaction of chlorine atoms with peroxyacetylnitrate (PAN), peroxypropionylnitrate (PPN), methylhydroperoxide, formic acid, acetone and butanone. Decay rates of these organic species were measured relative to one or more of the following reference compounds; ethene, ethane, chloroethane, chloromethane, and methane. Using rate constants of 9.29×10^–11, 5.7×10^–11, 8.04×10^–12, 4.9×10^–13, and 1.0×10^–13 cm³ molecule^–1 sec^–1 for the reaction of Cl atoms with ethene, ethane, chloroethane, chloromethane, and methane respectively, the following rate constants were derived, in units of cm³ molecule^–1 s^–1: PAN, <7×10^–15; PPN, (1.14±0.12)×10^–12; HCOOH, (2.00±0.25)×10^–13; CH₃OOH, (5.70±0.23)×10^–11; CH₃COCH₃, (2.37±0.12)×10^–12; and CH₃COC₂H₅, (4.13±0.57)×10^–11. Quoted errors represent 2 and do not include possible systematic errors due to errors in the reference rate constants. Experiments were performed at 295±2 K and 700 torr total pressure of nitrogen or synthetic air. The results are discussed with respect to the previous literature data and to the modelling of nonmethane hydrocarbon oxidation in the atmosphere.In recent discussions with Dr. R. A. Cox of Harwell Laboratory, UKAEA, we learnt of a preliminary value for the rate constant of the reaction of Cl with acetone of (2.5±1.0)×10^–12 cm³ molecule^–1 sec^–1 measured by R. A. Cox, M. E. Jenkin, and G. D. Hayman using molecular modulation techniques. This value is in good agreement with our results.     

Characteristics of chlorine isotope distribution and analysis on sylvinite deposit formation based on ancient salt rock in the western Tarim Basin

The Tarim Basin, located in Xinjiang (Fig. 1), is the largest deposit basin with an area of about 560000 km2 in China. From late Triassic period to early Miocene, two huge subbasins developed, named the Kuqa sub-basin at the foot of the Tianshan Mountains in the north and the Shaqa subbasin at the foot of the Kunlun Mountains in the south of the Tarim Basin. During the late Cretaceous to early Tertiary period, the Paleo-me- diterranean seawater repetitively invaded into the Shaqa subbas…     

Diurnal cycling of carbon monoxide (CO) in the upper ocean near Bermuda

A coupled photochemical–physical model for the upper ocean carbon monoxide concentration is presented. The coupled model uses a spectral optical model and a number of different mixing parameterizations. It is run using the meteorological forcing conditions measured during a 9-day investigation near Bermuda in the Sargasso Sea in March 1993 in the declining phase of the spring bloom. The baseline runs of the model are successful in simulating measurements made during the campaign, and form the basis of an optimization routine to find better estimates of the production and destruction constants of the photochemical tracer. The optimized values derived in this inverse procedure depend on the mixing parameterization and the assumed dark production rate of carbon monoxide.     

有机氯农药的零价铁脱氯降解研究进展

结合氯代有机物的零价铁脱氯降解研究进展,综述了国内外在零价铁脱氯降解有机氯农药领域的研究情况,大多研究表明零价铁降解有机氯农药的反应符合准一级反应动力学方程,普遍认同氢解反应机理但尚有争议,研究降解过程需考虑溶液pH值和铁表面活性作用的影响,尤其是铁表面的吸附作用不可忽略。最后提出了该技术存在的一些值得思考的问题,探讨了该研究领域的发展前景。     

滨海电厂钢筋混凝土腐蚀防护应用

某滨海电厂钢筋混凝土结构在海洋大气环境中腐蚀较重,通过分析已破坏的混凝土,确定腐蚀原因主要是二氧化碳腐蚀和氯离子腐蚀,采用TPEI——乳液砂浆和喷射混凝土两种方案,对钢筋混凝土结构进行修复,确保电厂设施正常安全运行。