小型多功能生态氡室的设计与研制

本文介绍了智能型测氡仪器标定装置——HD 5型多功能生态氡室的结构及氡浓度定值的计量过程,并分析了该氡室的性能指标。     

Isolating and identifying atmospheric ice-nucleating aerosols: a new technique

Laboratory studies examined two key aspects of the performance of a continuous-flow diffusion chamber (CFD) instrument that detects ice nuclei (IN) concentrations in air samples: separating IN from non-IN, and collecting IN aerosols to determine chemical composition. In the first study, submicron AgI IN particles were mixed in a sample stream with submicron non-IN salt particles, and the sample stream was processed in the CFD at −19°C and 23% supersaturation with respect to ice. Examination of the residual particles from crystals nucleated in the CFD confirmed that only AgI particles served as IN in the mixed stream. The second study applied this technique to separate and analyze IN and non-IN particles in a natural air sample. Energy-dispersive X-ray analyses (EDS) of the elemental composition of selected particles from the IN and non-IN fractions in ambient air showed chemical differences: Si and Ca were present in both, but S, Fe and K were also detected in the non-IN fraction.     

长白山天池火山研究进展

长白山天池火山距今４１０５年以来至少发生过两次大规模喷发。其最近的一次大喷发发生于公元８５０～１０４０年间。估计了这次喷发的喷发物体积和Ｃ１，Ｆ，Ｓ等的释放量。数值模拟表明，该次大喷发对全球气候变化产生过重要影响，最近的地球物理探测结果显示，在该火山下面存在地壳和上地幔双层岩浆房。认为该火山现在仍是一座具潜在灾害性大喷发危险的现代活动火山。     

岩浆囊的地震学探测技术概述

在过去的２０年里，探测和勾画岩浆囊的科学有了长足的进步。多种地震技术，包括速度和衰减的层析成像，地震活动性映像，反射和折射，势场技术，如重力，大地测量和电磁观测，都提供了关于在几个火山下面的岩浆囊的大小，形状和物理状态的有用信息。本文对这些技术进行了讨论和综述。我国已在Ｐ波波速层析成像方面开展了一系列工作。特别是在云南地区已得到了该省及其邻近地区的三维速度图像。由于现有台网不够密集，获得的速度图像分辨较低。尽管如此，在腾冲地区从２０ｋｍ到４５０ｋｍ深度都有低速度结构的显示。要想系统地研究腾冲火山地区的火山构造和地震活动性，以及探测该地区的岩浆囊，必须在该地区布设较密集的地震观测台网。     

A smog chamber for studies of the reactions of terpenes and alkanes with ozone and OH

The design and performance of a smog chamber for the study of photochemical reactions under simulated environmental conditions is described. The chamber is thermostated for aerosol experiments, and it comprises a gas chromatographic sample enrichment system suitable for monitoring hydrocarbons at the ppbv level. By irradiating NO _x /alkane-mixtures rate constants for the reaction of OH radicals with n-alkanes are determined from n-pentane to n-hexadecane to be (k±2)/10^–12 cm³ s^–1=4.29±0.16, 6.2±0.6, 7.52 (reference value), 8.8±0.3, 10.2±0.3, 11.7±0.4, 13.7±0.3, 15.1±0.5, 17.5±0.6, 19.3±0.7, 22.3±1.0, and 25.0±1.3, respectively at 312 K. Rate constants, (k±2)/10^–17 cm³ s^–1, for the reaction of ozone with trans-2-butene (21.2±1.0), cis-3-methylpentene-(2) (47.2±1.7), cyclopentene (62.4±3.5), cyclohexene (7.8±0.5), cycloheptene (28.3±1.5), -pinene (8.6±1.3), and -pinene (1.4±0.2) are determined in the dark at 297 K using cis-2-butene (13.0) as reference standard.     

Laboratory studies of some environmental variables controlling sulfur emissions from plants

Several trace sulfur gases that can have a significant influence on atmospheric chemistry are emitted from biological systems. In order to begin to address biological questions on the mechnisms of production of such gases, laboratory-scale experiments have been developed that reproduce such emissions under controlled conditions. Using a flux chamber technique, flats containing soil, or soil plus plants were sampled for the net fluxes of sulfur gases. The major sulfur gas emitted from all the plants tested (corn, alfalfa, and wheat) was dimethyl sulfide (DMS). Alfalfa and wheat also emitted lesser amounts of methanethiol, variable amounls of hydrogen sulfide, and in some experiments wheat emitted carbon disulfide. The use of a plant incubator allowed a systematic study of the effects of variables such as temperature, photon flux, and carbon dioxide levels, on these emissions. Fluxes of all the emitted sulfur gases increased exponentially with increasing air temperature, and increased with increasing photon flux up to a saturation level of \~300 E/m^–2 sec^-1. Three to four-fold changes in DMS flux were observed during light to dark or dark to light transitions. By varying the CO₂ content of the chamber flush gas, it was shown that the observed sulfur fluxes from corn and alfalfa were not related to the CO₂ concentration. Growing these crop plants through holes in a Teflon soil-covering film allowed a separate determination of soil and foliage emissions and substantiation of the light dependent uptake of COS by growing vegetation observed in previous field studies.     

Kinetics of the reactions of hydroxyl radicals with alkyl nitrates and with some oxygen-containing organic compounds studied under simulated atmospheric conditions

Rate constants have been measured for the reactions of hydroxyl radicals with alkyl nitrates and with some oxygen-containing organic compounds by a competitive technique. Mixtures of synthetic air containing a few ppm of nitrous acid, ethylene and the organic substrate were photolysed in a Teflon bag smog chamber. Based on the value k _HO+C2H₄}=8.1×10^-12 cm³ molecule^-1 s^-1 the following rate constants were obtained for the hydroxyl radical reactions at 750 Torr and at 303 K in units of 10^-12 cm³ molecule^-1: CH₃ONO₂, 0.37±0.09; C₂H₅ONO₂, 0.48±0.20; n-C₃H₇ONO₂, 0.70±0.22; C₂H₅OH, 3.6±0.4; CH₃COCH₃, 0.26±0.08; CH₃CO₂ i-C₃H₇, 3.0±0.8; CH₃CO₂ n-C₃H₇, 2.4±0.2. The results are discussed in relation to the available literature data and the implications of the results are considered in terms of the smog reactivity of these molecules.     

攀西裂谷构造─岩浆活动及其成因探讨

本文主要讨论弯窿一火山型攀西裂谷的成因，岩浆深成作用与火山作用过程;弩窿梅 造的发生、发展的演化历史，岩浆分异趋势及双峰式岩浆演化系列及其成因。 攀西裂谷曾经历了岩石圈弯窿一除壳弯窿一次火山弯窿三个发展演化阶段。碱性岩浆作用与 地壳隆开、地慢去气、热流汇聚作用有着密切的成因联系，成弯作用最盛，岩浆碱度最高。随着 陆壳破裂、开放、挥发分散逸，岩浆性质从强碱质一弱碱质一碱酸性转化。 弯窿构造的发展演化阶段有机地控制了岩浆源和二次岩浆房的深度和岩浆演化特点，随着弯 窿构造的发展演化，岩浆活动由深成慢源→中浅成慢源加嵌轻微混染→超浅成壳慢混合源逐渐 演化，因而可以认为:弯窿一火山型裂谷发育的各个阶段，存在有低位→中位→高位的二次岩浆 房. 攀西裂谷属不发育的夭折裂谷，以演化时间长为特点，有利于岩浆深源(二次岩浆房内)结 晶分异、液体不混容性分离作用和陆壳的同化混染作用等得以彻底进行，最终形成“双峰式”岩 浆组合。     

An FTIR product study of the photooxidation of dimethyl disulfide

The products of the 254 nm photolysis of ppm levels of DMDS have been studied as a function of the O₂ partial pressure at 760 Torr (N₂ + O₂) and 298±2 K. The major sulfur containing compounds detected were SO₂ and CH₃SO₃H (methane sulfonic acid, MSA) and the major carbon containing compounds were CO, HCHO, CH₃OH and CH₃OOH (methyl hydroperoxide). Within the experimental error limits the observed sulfur and carbon balances were approximately 100%. CH₃OOH has been observed for the first time in such a photooxidation system. Its observation provides evidence for the formation of CH₃ radicals by the further oxidation of the CH₃S radicals formed in the primary photolysis step.From the behavior of the DMDS photolysis products as a function of the O₂ partial pressure, O₃ concentration and added OH radical source it is postulated that the further reactions of CH₃SOH (methyl sulfenic acid), formed in the reaction OH + CH₃SCCH₃ CH₃SOH + CH₃S, are the main source of MSA in the 254 nm photolysis of DMDS.Some of the possible implications of the results of this study for the degradation mechanisms of other atmospherically important organic sulfur compounds, in particular DMS, are briefly considered.     

云室中两种检测冰晶方法的比较

通过实验比较了在云室中检测冰晶的两种方法－糖盘法和玻片法，结果表明玻璃片测到的冰晶数比糖盘高数倍，讨论了两种方法检测的上下限，优缺点及应用范围。