长江生源要素的输出通量

长江是太平洋西岸最大的河流,它源源不断地向东海输送大量物质,是舟山渔场的重要化学物质基础,不仅对长江口海区以至整个东海有举足轻重的影响,对太平洋的影响也是不可忽视的。本文报道颗粒有机碳(POC)、溶     

Design of ship's bow form by potential-based panel method

A surface panel method treating a boundary-value problem of the Dirichlet type with the free surface is presented to design a three-dimensional body corresponding to a prescribed pressure distribution. The free surface boundary condition is linearized with respect to the oncoming flow, and computed by four-point finite difference scheme. Sample designs for submerged spheroids and Wigley hull are carried out to demonstrate the stable convergence, the effectiveness and the robustness of the method. The design of a 5500TEU container carrier is performed with respect to reduction of the wave resistance. To reduce the wave resistance, calculated pressure on the hull surface is modified to have the lower fluctuation, and is applied as a Dirichlet type dynamic boundary condition on the hull surface. The designed hull form is verified to have the lower wave resistance than the initial one not only by computation but also by experiment.     

Carbon Isotope Geochemistry of the Orinoco Basin

Stable carbon isotope ratios have been used to study the sources of particulate organic carbon (POC) and total dissolved inorganic carbon in the Orinoco Basin. The isotopic composition of total dissolved inorganic carbon shows a range of from -8·1 to -23·0 ppt, an indication of dominance of biological processes. The isotopic composition of POC exhibits a range of from -24·1 to -34·6 ppt with little seasonal variation. The isotopic evidence indicates that the POC is predominantly of terrestrial origin rather than a result of in situ planktonic production. The similarity of isotopic composition of POC and coastal sediments suggests that riverine organic detritus has been transported 30-50 km offshore in a direction parallel to the Orinoco river channel.     

A Preliminary Study of Oceanic Bomb Radiocarbon Inventory in the North Pacific during the Last Two Decades

Radiocarbon and total carbonate data were obtained near the 1973 GEOSECS stations in the North Pacific along 30°N and along 175°E between 1993 and 1994. In these stations, we estimated radiocarbon originating from atomic bomb tests using tritium, trichlorofluoromethane and silicate contents. The average penetration depth of bomb radiocarbon during the two decades has deepened from 900 m to 1300 m. Bomb radiocarbon inventories above the average value for the whole North Pacific were found widely in the western subtropical region around 30°N both in the 1970s and 1990s, and its area in the 1990s was broader than that in the 1970s. In most of the North Pacific, while the bomb radiocarbon has decreased above 25.4, the bomb radiocarbon flux below 25.4 was over 1 × 10¹² atom m^-2yr^-1 in the subtropical region around 30°N. In the tropical area south of 20°N, the bomb radiocarbon inventory below 25.4 increased from zero to over 10 × 10¹² atom m^-2 during the last three decades. These distributions suggest that the bomb radiocarbon removed from the surface is currently accumulated with bomb ¹⁴C flux of over 1 × 10¹² atom m^-2yr^-1 below 25.4 in the subtropical region, mainly by advection from the higher latitude, and that part of the accumulated bomb ¹⁴C gradually spread southward with about 30 years.     

Nitrogen forms and decomposition of organic carbon in the southern Bohai Sea core sediments

Study on form characteristics of nitrogen in marine sediments is the primary method to research its biogeochemical cycling and nitrogen form characteristics in core sediments can reflect the process and results of early diagenesis in a certain degree. In this paper, Sequential extraction process in natural grain size was used for studying the existent forms of nitrogen in five core sediments of the southern Bohai Sea for the first time. Nitrogen was divided into two parts -transferable and fixed based on whether it could be extracted by the reagent. Distributions and early diagenesis of transferable nitrogen forms in the southern Bohai Sea were researched integratedly. Results indicate that IEF - N and OSF-N are predominant forms in transferable part in the studied core sediments. Contents of different nitrogen forms vary differently with depth, and have different diagenesis process. Decomposition constant of organic nitrogen (ON) and OC are about 15.51 × 10~(-3)a~(-1)and 4.79× 10~(-3)a~(-1) respective     

全球海洋与大气界面的熵通量估算

给出并讨论了海洋系统中由于热量交换、物质交换以及外力做功引起的熵通量的表达式;同时,根据新近调整的全球海 气界面的气候平均资料,估计了全球海洋与大气界面气候年平均的熵通量(熵流),这一熵通量主要取决于海 气界面的热量和物质交换的空间不均匀性。计算结果显示,由热量交换分量引起的熵通量对海洋系统的总熵通量起到主要的贡献作用,其值约为-555.6mW·(m2·K)-1;由海表风应力做功引起的熵通量相对较小,约为-0.09mW·(m2·K)-1;由物质交换引起的熵通量最小,仅为-0.02mW·(m2·K)-1。总的来说,海洋系统从外界获得的总熵通量为-555.7mW·(m2·K)-1,这也就意味着在气候平均定态下,海洋系统内部的熵产生在量值上等于系统的熵交换,即为555.7mW·(m2·K)-1。海洋系统的负熵流与其内部的各种不可逆过程引起的熵产生取得平衡,确保了全球海洋系统处于非平衡热力学定态,并维持着海洋系统中各种尺度的时 空有序现象的消长过程。     

Sources and distribution of organic matter in a river-dominated estuary (Winyah Bay, SC, USA)

The sources and distribution of organic matter (OM) in surface waters and sediments from Winyah Bay (South Carolina, USA) were investigated using a variety of analytical techniques, including elemental, stable isotope and organic biomarker analyses. Several locations along the estuary salinity gradient were sampled during four different periods of contrasting river discharge and tidal range. The dissolved organic carbon (DOC) concentrations of surface waters ranged from 7 mg l⁻¹ in the lower bay stations closest to the ocean to 20 mg l⁻¹ in the river and upper bay samples. There was a general linear relationship between DOC concentrations and salinity in three of the four sampling periods. In contrast, particulate organic carbon (POC) concentrations were significantly lower (0.1–3 mg l⁻¹) and showed no relationship with salinity. The high molecular weight dissolved OM (HMW DOM) isolated from selected water samples collected along the bay displayed atomic carbon:nitrogen ratios ([C/N]a) and stable carbon isotopic compositions of organic carbon (δ¹³C_OC) that ranged from 10 to 30 and from −28 to −25‰, respectively. Combined, such compositions indicate that in most HMW DOM samples, the majority of the OM originates from terrigenous sources, with smaller contributions from riverine and estuarine phytoplankton. In contrast, the [C/N]a ratios of particulate OM (POM) samples varied significantly among the collection periods, ranging from low values of 5 to high values of >20. Overall, the trends in [C/N]a ratios indicated that algal sources of POM were most important during the early and late summer, whereas terrigenous sources dominated in the winter and early spring.In Winyah Bay bottom sediments, the concentrations of the mineral-associated OM were positively correlated with sediment surface area. The [C/N]a ratios and δ¹³C_OC compositions of the bulk sedimentary OM ranged from 5 to 45 and from −28 to −23‰, respectively. These compositions were consistent with predominant contributions of terrigenous sources and lesser (but significant) inputs of freshwater, estuarine and marine phytoplankton. The highest terrigenous contents were found in sediments from the river and upper bay sites, with smaller contributions to the lower parts of the estuary. The yields of lignin-derived CuO oxidation products from Winyah Bay sediments indicated that the terrigenous OM in these samples was composed of variable mixtures of relatively fresh vascular plant detritus and moderately altered soil OM. Based on the lignin phenol compositions, most of this material appeared to be derived from angiosperm and gymnosperm vascular plant sources similar to those found in the upland coastal forests in this region. A few samples displayed lignin compositions that suggested a more significant contribution from marsh C₃ grasses. However, there was no evidence of inputs of Spartina alterniflora (a C₄ grass) remains from the salt marshes that surround the lower sections of Winyah Bay.     

Deposition Rates of Terrestrial and Marine Organic Carbon in the Osaka Bay, Seto Inland Sea, Japan, Determined Using Carbon and Nitrogen Stable Isotope Ratios in the Sediment

Carbon and nitrogen stable isotope ratios (¹³C and ¹⁵N) of surface sediments were measured within Osaka Bay, in the Seto Inland Sea in Japan, in order to better understand the sedimentation processes operating on both terrestrial and marine organic matter in the Bay. The ¹³C and ¹⁵N of surface sediments in the estuary of the Yodo River were less than –23 and 5 respectively, but increased in the area up to about 10 km from the river mouth. At greater distances they became constant (giving ¹³C of about –20 and ¹⁵N about 6). It can be concluded that large amounts of terrestrial organic matter exist near the mouth of the Yodo River. Stable isotope ratios in the estuary of the Yodo River within 10 km of the river mouth were useful indicators allowing study of the movement of terrestrial organic matter. Deposition rates for total organic carbon (TOC) and total nitrogen (TN) over the whole of the Bay were estimated to be 63,100 ton C/year and 7,590 ton N/year, respectively. The deposition rate of terrestrial organic carbon was estimated to be 13,200 (range 2,000–21,500) ton C/year for the whole of Osaka Bay, and terrestrial organic carbon was estimated to be about 21% (range 3–34) of the TOC deposition rate. The ratio of the deposition rate of terrestrial organic carbon to the rate inflow of riverine TOC and particulate organic carbon (POC) were estimated to be 19% (range 3–31) and 76% (range 12–100), respectively.     

Seasonal and annual variations of marine sinking particulate flux during 1993~1996 in the central South China Sea

A total of 67 samples from the upper and lower sediment traps in the central South China Sea were analyzed, which were collected during 1993~1996. It is indicated that the distribution of stable isotope values, surface primary productivity, fluxes of total particulate matter, carbonate, biogenic opal, organic carbon, planktonic foraminiferal species and their total amount exhibit obviously seasonal and annual fluctuations. High values of the fluxes occurred in the prevailing periods of the northeastern and southwestern monsoons, and the low values occurred during the periods between the two monsoons. The fluxes of some planktonic foraminiferal species (Globigerinoides sacculifer, G. ruber, Globigerinita glutinata, Neogloboquadrina dutertrei) and their percentages also exhibit two prominent peaks during the prevailing periods of the northeastern and southwestern monsoons respectively, while those of Globigerina bulloides, Globorotalia menardii and Pulleniatina obliquiloculata only exhibit one peak in the prevailing periods of the northeastern monsoon. In addition, fluxes and percentages of Globigerinoides sacculifer and Globorotalia menardii as well as the fluxes of carbonate and total amount of planktonic foraminifera decrease gradually from 1993 to 1996, and those of Globigerina bulloides, Globigerinita glutinata and biogenic opal increase gradually from 1993 to 1996. The fluxes of carbonate and organic carbon in the upper trap are higher than those in the lower one. The study indicates that the seasonal and annual variations of the sediment fluxes and planktonic foraminiferal species are mainly controlled by the changes of surface primary productivity and hydrological conditions related to the East Asian monsoon. The lower carbonate and organic carbon fluxes in the lower trap are related to the dissolution.     

黄河利津水文站不同粒径悬浮颗粒物中有机碳含量的研究

估算不同粒径TSS中POC的入海日通量,对黄河利津水文站悬浮颗粒物(total suspended solid,TSS)样品,采用基于stokes原理的沉降法分为Ⅴ级,对分级后的样品测其有机碳(particulate organic carbon,POC)含量和粒度组成。在此基础上,用多元线性回归法对数据进一步处理,准确得到样品中不同粒径TSS中POC的含量。研究表明,黄河口淡水端水体TSS,<8μm的粘土和极细粉砂、8~16μm的细粉砂中,POC的含量为0.600%和0.400%左右;16~32μm的中粉砂中,POC的含量不足0.200%;而32~63μm的粗粉砂和>63μm砂中POC含量仅为0.050%和0.004%左右,80%以上的POC主要集中在<16μm的TSS中,而<32μm的TSS承载了95%以上的POC。