大民屯凹陷烃源岩有机质丰度的恢复

烃源岩有机质丰度的恢复具有重要的现实和理论意义。笔者在对比多种方法的基础上,对大民屯凹陷的烃源岩的有机质丰度进行了恢复。     

对一种振冲碎石桩复合地基沉降计算方法——Priebe法的改进

通过对经典的Priebe沉降计算法分析,以及面积置换率的变化对桩体压缩性假设作了改进;对桩土重度差异及承受荷载时应力和变形与深度的关系作了分析,归纳出相应的数学计算公式,用工程实例进行了验证。得到的结果表明改进是合理、适用的,可为今后的设计和施工提供参考。     

Changes in hydrogeological properties of the River Choushui alluvial fan aquifer due to the 1999 Chi-Chi earthquake, Taiwan

Changes in hydrogeological properties of the River Choushui alluvial fan aquifer before and after the 1999 Chi-Chi earthquake, Taiwan, have been identified using pumping tests. Three wells, SH2, YL2 and SC2, located in a compressional zone with high coseismic groundwater levels, were tested. The threshold of the aquifer deformation with respect to transmissivity (T) is greater than that with respect to storage coefficient (S). Decreases in the post-earthquake S are approximately 60% at SH2 and SC2, indicating aquifer compression after the Chi-Chi earthquake. Changes in the post-earthquake T range from 61% increase to 0.8% decrease. Moreover, results from anisotropy analysis of T at SC2 further illustrate that normal stresses induced by the Chi-Chi earthquake have consolidated soil particles. Soil particles dilated laterally after the earthquake, resulting in an increase of the equivalent T. The changes in hydrogeological properties have a considerable influence on spatiotemporal fluid pressure and horizontal groundwater movement, resulting in different amounts of drawdown during post-earthquake pumping.     

非均匀月壤介质的被动微波辐射传输模拟

基于非均匀月壤物理模型和辐射传输方程,模拟月壤介质中的微波辐射传输特性,探讨频率、月壤厚度等与月表亮温的关系。结果表明:在低频段,月壤微波辐射亮温的动态变化范围较大,可探测的月壤厚度大,3 GHz时的最大可探测月壤厚度达12.4 m;在高频段对应的可探测月壤厚度较小,特别是从50GHz往后的频率段内,最大可探测月壤厚度均小于2 m。不同频率的亮温-厚度变化曲线没有交叉点,且频率越高,所能探测的月壤厚度越小。根据模拟结果,建立了月壤厚度与亮温的查找表。基于查找表,利用单个波段的亮温数据即可得到月壤厚度信息。     

Actinic flux and photolysis frequency comparison computations using the model PHOTOGT

The accurate radiative transfer model GOMETRAN, initially designed to yield radiances at TOA in the wavelength range 240–790 nm, has been extended to allow for the computation of actinic fluxes down to 175 nm and for the calculation of photolysis frequencies in the atmosphere. The capability of the extended model PHOTOGT (PHOTOGOMETRAN) is demonstrated in a number of successful comparison studies both with recent experiments (ground-based, balloonborne, airborne) and model calculations of radiances, actinic fluxes and photolysis frequencies in the stratosphere and troposphere. In an atmospheric case study, the impact of new quantum yield data for the O₃ » O₂+O(¹ d) photodissociation channel on the photolytic production of O(¹ d) atoms in the lower atmosphere has been quantified.     

Evolution of cool skin and direct air-sea gas transfer coefficient during daytime

Absorption of solar radiation within the thermal molecular sublayer of the ocean can modify the temperature difference across the cool skin as well as the air-sea gas transfer. Our model of renewal type is based on the assumption that the thermal and diffusive molecular sublayers below the ocean surface undergo cyclic growth and destruction, the heat and gas transfer between the successive burst events are performed by molecular diffusion. The model has been upgraded to include heating due to solar radiation. The renewal time is parameterized as a function of the surface Richardson number and the Keulegan number. A Rayleigh number criterion characterizes the convective instability of the cool skin under solar heating. Under low wind speed conditions, the solar heating can damp the convective instability, strongly increasing the renewal time and correspondingly decreasing the interfacial gas exchange. In the ocean, an additional convective instability caused by salinity flux due to evaporation becomes of importance in such cases. The new parameterization is compared with the cool skin data obtained in the western equatorial Pacific during the Tropical Ocean Global Atmosphere Coupled Ocean Atmosphere Response Experiment in February 1993. In combination with a model of the diurnal thermocline it describes main features of the field data both in nighttime and daytime. Under low wind speed conditions (< 5 m s^-1) diurnal variations of the sea surface temperature due to the formation of a diurnal thermocline were substantially larger than those across the cool skin. Under wind speeds > 5 m s^-1, diurnal variations of the surface temperature due to the variations of the thermal molecular sublayer become more important.     

Modelling of the vertical fluxes of nitric acid,ammonia, and ammonium nitrate

Results from numerical investigations regarding the exchange of HNO₃, NH₃, and NH₄NO₃ between the atmosphere and the biosphere are presented. The investigations were performed with a modified inferential method which is based on the generally accepted micrometeorological ideas of the transfer of momentum, sensible heat and matter near the Earth's surface and the chemical reactions among these nitrogen compounds. This modified inferential method calculates the micrometeorological quantities (such as the friction velocity and the fluxes of sensible and latent heat), the height-invariant fluxes of the composed chemically conservative trace species with group concentrationsc ₁=[HNO₃]+[NH₄NO₃] (total nitrate),c ₂=[NH₃]+[NH₄NO₃] (total ammonia), andc ₃=[HNO₃]-[NH₃] as well as the fluxes of the individual nitrogen compounds. The parameterization of the fluxes is based on the flux-gradient relationships in the turbulent region of the atmospheric surface layer. The modified inferential method requires only the data of wind velocity, temperature, humidity and concentrations (HNO₃, NH₃, and NH₄NO₃) measured at a reference height by stations of a monitoring network.     

The mass accommodation coefficient of ammonia on water

The mass accommodation coefficient of ammonia gas on water has been determined by measuring the absorption rate of 50–200 ppm NH₃ in one atm of air or helium into a liquid jet of 97 µm diameter as function of the exposed jet length, and comparing the results with numerical simulations which treat as the only free parameter. The model considers in detail transport of NH₃ by molecular diffusion, penetration of the gas/water interface, hydrolysis in the acidified water, and transport of the solutes from the surface into the jet. A correction is applied for the time evolution of the jet surface speed, using literature data on the fluid mechanics of liquid jets. The result of nine sets of independent measurements is

Trace gas exchange at the air/water interface: Measurements of mass accommodation coefficients

A liquid jet of 90 m diameter and variable length has been utilized to determine absorption rates and, hence, mass accommodation coefficients , of atmospheric trace gases. The compounds investigated are HCl (0.01), HNO₃ (0.01), N₂O₅ (0.005), peroxyacetyl nitrate (>0.001), and HONO (0.005). It is concluded that the absorption of these trace gases by liquid atmospheric water is not significantly retarded by interfacial mass transport. The strengths and limitations of the liquid jet technique for measuring mass accommodation coefficients are explored.