基于灰色模糊聚类分析的吉林省黑土结构综合评价

通过对黑土结构指标的定量研究,确定颗粒组成、团聚性和孔隙性3个方面的9个结构指标,建立结构综合评价体系,并采用灰色模糊聚类分析法对黑土的结构进行综合评价,确定吉林黑土的结构质量及肥力状况。结果表明,肥力中-低等样品数量占总量的53%,吉林黑土总体肥力状况不容乐观。以灰色模糊聚类分析法评价土壤结构不需要建立评价的分级标准,可以根据评价对象的实际情况进行最优聚类分析,采用结构性指标对黑土肥力和退化进行评价是可行的。     

The dynamics and thermodynamics of large ash flows

 Ash flow deposits, containing up to 1000 km³ of material, have been produced by some of the largest volcanic eruptions known. Ash flows propagate several tens of kilometres from their source vents, produce extensive blankets of ash and are able to surmount topographic barriers hundreds of metres high. We present and test a new model of the motion of such flows as they propagate over a near horizontal surface from a collapsing fountain above a volcanic vent. The model predicts that for a given eruption rate, either a slow (10–100 m/s) and deep (1000–3000 m) subcritical flow or a fast (100–200 m/s) and shallow (500–1000 m) supercritical flow may develop. Subcritical ash flows propagate with a nearly constant volume flux, whereas supercritical flows entrain air and become progressively more voluminous. The run-out distance of such ash flows is controlled largely by the mass of air mixed into the collapsing fountain, the degree of fragmentation and the associated rate of loss of material into an underlying concentrated depositional system, and the mass eruption rate. However, in supercritical flows, the continued entrainment of air exerts a further important control on the flow evolution. Model predictions show that the run-out distance decreases with the mass of air entrained into the flow. Also, the mass of ash which may ascend from the flow into a buoyant coignimbrite cloud increases as more air is entrained into the flow. As a result, supercritical ash flows typically have shorter runout distances and more ash is elutriated into the associated coignimbrite eruption columns. We also show that one-dimensional, channellized ash flows typically propagate further than their radially spreading counterparts. As a Plinian eruption proceeds, the erupted mass flux often increases, leading to column collapse and the formation of pumiceous ash flows. Near the critical conditions for eruption column collapse, the flows are shed from high fountains which entrain large quantities of air per unit mass. Our model suggests that this will lead to relatively short ash flows with much of the erupted material being elutriated into the coignimbrite column. However, if the mass flux subseqently increases, then less air per unit mass is entrained into the collapsing fountain, and progressively larger flows, which propagate further from the vent, will develop. Our model is consistent with observations of a number of pyroclastic flow deposits, including the 1912 eruption of Katmai and the 1991 eruption of Pinatubo. The model suggests that many extensive flow sheets were emplaced from eruptions with mass fluxes of 10⁹–10¹⁰ kg/s over periods of 10³–10⁵ s, and that some indicators of flow "mobility" may need to be reinterpreted. Furthermore, in accordance with observations, the model predicts that the coignimbrite eruption columns produced from such ash flows rose between 20 and 40 km. Received: 25 August 1995 / Accepted: 3 April 1996     

Commentary and critique of “accounting for mineral resources: Issues and BEA's initial estimates”

The Bureau of Economic Analysis (BEA), U.S. Department of Commerce, in keeping with broad international efforts to green national gross domestic product (GDP) accounts, has attempted to create satellite accounts for mineral depletion. The present paper criticizes the BEA's unit rent measure of resource depletion, which is based upon Hotelling's pure theory of exhaustion. Following a thorough criticism of Hotelling's theory as a real-world model of mineral prices, practical issues related to the treatment of recycling, exploration, definition of reserves/resources, and their valuation/exploitation are introduced. For crude oil and natural gas and the nonfuel minerals, specific application problems of joint products and residuals complicate BEA's assumptions and efforts.     

The project “spice”

Proposed to both the French and the European Space Agency as one possible small mission, SPICE is a project for a dedicated small satellite for a near-IR spectroscopic all-sky survey. The instrument would cover the spectral range 1.8 - 3.6µm, possibly extended to 1.8 - 7µm, at a resolution of 100, with pixels of 1 arc-min. The excellent sensitivity (0.02 MJy sr-1) results from: i) the quasi-zero level of background due to the efficient passive cooling of the whole experiment; ii) the use of large format arrays; iii) the non-stop observing mode (drift-scanning). The spectral domain, complementing the one of ISO, partially opaque from the ground, is specially rich in spectral features tracing stars and all components of the Interstellar Medium (molecular, atomic and ionized gas, dust). With a cooling below 80 K of the focal instrument, then it becomes possible to consider doubling the spectral domain and to cover the whole 1.8 - 7µm range.     

The almost constant-speed two-body problem with resistance

The almost constant-speed motion of a mass acted upon by a Newtonian attraction and a resisting force is treated. The equation of orbit is derived for a specific type of resistance which covers the familiar case of Danby's drag(=r ^–2) whilst the vector invariants are obtained by direct operation on the vector form of the equation of motion.     

Numerical study of droplet size dependent chemistry in oceanic,wintertime stratus cloud at southern mid-latitudes

Cloud droplet chemistry is modelled for the first 150 m of rise in a wintertime, mid-latitude, marine stratus cloud using observations made at and near the Cape Grim Baseline Station as a source of input parameters. The emphasis in this work was to study the variation in droplet chemistry as a function of both droplet size and nucleus composition, with a particular focus on the way in which oxidation of dissolved sulfur dioxide varied.At 150 m above the condensation level, solute concentration as a function of droplet size was found to increase by as much as 2 to 3 orders of magnitude for only a factor of 2 increase in droplet radius, primarily as a consequence of the 1/r dependence in the droplet growth equation. This type of size dependence exists at all levels in the model cloud, and has a significant influence on oxidation rate of sulfur dioxide in droplets growing on sulfate nuclei, oxidation by ozone being favoured in the smallest droplets, but oxidation by hydrogen peroxide being favoured in the larger droplets. Oxidation by ozone is favoured at all sizes in droplets formed on sea-salt nuclei as a result of the initially high alkalinity of these droplets, and in the cloud overall is calculated to be the more important oxidation pathway. Although based on a simplified chemical scheme, these results suggest that both size-dependent and nucleus-dependent chemistry of cloud droplets may need to be considered explicitly in cloud modelling work.Volume-weighted mean pH values in the range 5 to 6 were predicted from sensitivity studies in which input variables were varied over reasonable ranges, in agreement with two sets of bulk cloud-water pH data obtained by aircraft near Cape Grim.     

Tectonic relation between northeastern China and the Korean peninsula revealed by interpretation of GRACE satellite gravity data

The major continental blocks in northeastern Asia are the North China block and the South China block, which have collided starting from the Korean peninsula. Geologic and geophysical interpretations reveal a well defined suture zone in northeastern China from Qinling through Dabie to Jiaodong. The discovery of high-pressure metamorphic rocks in the Hongseong area of the Korean peninsula, prominent evidence for the collision zone, indicates extension of the collision zone in northeastern China into the Korean peninsula. Interpretation of the GRACE satellite gravity dataset shows two prominent structural boundaries in the Yellow Sea. One extends from the Jiaodong Belt in eastern China to the Imjingang Belt in the Korean peninsula. The other extends from near Nanjing, eastern China, to Hongseong. Tectonic movement in or near the suture zone may be responsible for seismic activity in the western Korean peninsula and the development of the Yellow Sea sedimentary basin.     

Geochemistry of soils derived from black shale, central Hunan, China

The black shale formed under anoxic conditions usually contains high concentrations of many metals. Weathering of such black shale might cause the emission of many metals. Moreover, soils derived from black shale （SBS） are believed to be affected by black shale weathering. In recent years, many studies such as Lee et al. （2002）, Woo et al. （2002）, Fang et al. （2002）, Pasava et al. （2003）, and Peng et al. （2004） have approached the heavy metal contaminations of SBS, but systematical geochemical study is rare. Presently, the SBS and its corresponding black shales （CBS） were both sampled from central Hunan （China）, and analyzed for a large number of elements, using an Elan6000 ICP-MS/AES machine at Guangzhou Institute of Geochemistry, CAS. In this paper, some preliminary results are reported. The analytical results show that the SBS in central Hunan contains very high concentrations of heavy metals such as Co, Cu, Hg, Mo, Pb, Zn, U, Th, Sb, T1, Cd, Cr, Sc, V, Sn, As, Se, and Ni.     

东北漫岗黑土区春季冻融期浅沟侵蚀

浅沟侵蚀是东北漫岗黑土区农耕地上常见的水蚀类型,往往对坡耕地造成严重的破坏。2005年春季,通过对两个小流域浅沟侵蚀的调查测量,发现该区浅沟侵蚀相当严重,两流域分别形成浅沟14条、16条,浅沟总长度分别达3 269 m、2 146 m,浅沟密度分别为908 m/km2、766 m/km2,侵蚀深度分别为0.17 mm、0.16 mm,侵蚀模数分别达181.8 t/km2、173.6 t/km2。2005年春季两流域浅沟侵蚀期的径流深分别是6.8 mm、7.7 mm。分析表明,研究区在春季表层土壤解冻、地表裸露和存在季节性冻土层的条件下,春季融雪及强降水易造成强烈的浅沟侵蚀。在分布上,浅沟一般位于坡面的中下部,而且多发育在瓦背状坡面的集流水路上。另外,耕作措施对浅沟的形成和发展也有重要影响。     

Attenuation of aqueous metal transport at two natural acid rock drainage occurrences in the Yukon Territory, Canada

Naturally acidic drainage associated with pyritic black shale has been observed in many locations in the Yukon Territory. While not necessarily linked to known mineral deposits, most of these natural acid rock drainage occurrences show elevated dissolved concentrations of trace elements, especially zinc, nickel, copper, cadmium and arsenic. Based on field observations, microbial investigation, chemical analyses and geochemical modeling, the fate and transport of potentially deleterious elements at two natural acid drainage occurrences with slightly different settings are examined. The Macintosh Creek is a small, acidic stream （pH 2.98-3.40）, 2 km long, located in the Macmillan Pass area of east-central Yukon amidst known sedimentary exhalative massive sulfide mineralization but remains undisturbed by exploration activities. Its trace metal content is apparently derived from groundwater discharges, which gave as much as 5.0, 2.5, 0.7, 0.13 and 0.03 mg/L ofZn, Ni, Cu and As, respectively. Interaction and sorption reactions with algal mats, biofilms and iron oxyhydroxides appear to be the dominant mechanisms attenuating aqueous contaminant transport along the stream. Cryogenic precipitation further consolidates the ferricrete formation and reduces the mobility of the sorbed metals. The tributaries of the Engineering Creek along the Dempster Highway in northern Yukon drain through a series of dolomite, phyllite, argillite, limestone, black shale, sandstone and conglomerate with no known concentration of mineralization. In this area, the water chemistry fully reflects the local geology with acidic streams invariably associated with black shale occurrences. Groundwater seeps in the headwaters area of the km-180 Creek completely enclosed in black shale gave pH 3.0 and as much as 148, 39, 2.9 and 9.1 mg/L of Zn, Ni, Cu and As, respectively. Sorption with iron oxyhydroxide and organic matter appear to dominate the attenuation of contaminant transport along the stream. However, once entered into carbonate-dominated terrains, secondary carbonate minerals exercise additional geochemical control on the local water chemistry as a result of neutralization.