合成磷灰石的去氟机理研究

用固相反应法和sol-gel法合成了不同类型的磷灰石（AP），并采用TEM、XRD、IR、BET比表面积法及静、动态吸附等方法研究了不同AP的比表面积、结晶度、晶胞参数、结晶尺寸、晶格缺陷度、Ca/P摩尔比和煅烧温度等与吸氟能力的关系，结果表明：结晶度高、晶粒大的AP有较小的吸氟量，属表面单分子层化学络合吸附机理；酸活化的AP有较大的吸氟量，属溶解-沉淀与沉淀物表面纳米尺寸效应吸附的复合去氟机理；具纳米尺寸的HAP在常温、常压、无二次污染、小于11mg/L的低含氟浓度废水中且不酸化情况下有较大吸氟量，属纳米尺寸效应吸附机理。     

使用价值分析优化方法在功能-技术矩阵求解中的应用

功能-技术矩阵,经众多工作者的努力研究,已渐趋成熟与实用。但如何利用功能-技术矩阵构造在广义现代设计领域中适用的科学模式,解决多学科设计方案的组成与评价问题,还存在薄弱环节。本文利用\     

近30年来长江源区土地覆被变化特征分析

长江源区是我国重要的水源涵养地。本文利用20世纪70年代中后期、90年代初期、2004年和2008年共4期土地覆被数据,通过土地覆被转类途径与幅度、土地覆被状况指数和土地覆被转类指数,分析评价了长江源区近30年来土地覆被与生态状况的时空变化特征。结果表明：草地是长江源区主要的土地覆被类型,2008年草地面积占该区总面积的66.93%。在70年代中后期-90年代初期、90年代初期-2004年和2004-2008年的3个时段内,土地覆被状况指数变化率分别为-0.15、-0.24和0.01;土地覆被转类指数分别为-0.20、-0.66和0.08。近30年来,长江源区土地覆被和生态状况总体经历了变差-显著变差-略有好转的过程。2004-2008年,长江源区年平均温度比前期（70年代中后期-2004年）升高了0.57℃,年平均降水量比前期增加了17.63mm。区域气候变化有助于自然生态系统的恢复。后期生态保护与建设工程的实施,对植被恢复产生了一定的积极作用。     

2013年河北中南部PM_(10)和PM_(2.5)浓度时间变化特征及其影响气象条件分析

对2013年河北省中南部的石家庄、保定、沧州、衡水、邢台和邯郸6个地市市区各站点逐小时PM10和PM2.5监测资料及相应气象资料分析结果表明:6个地市中邢台年污染日数最多,对应其年平均风速最小;沧州的最少,年平均风速最大。各地市各个级别污染日数不同,五、六级重污染天气均集中在10月—次年3月。首要污染物主要是PM10和PM2.5,但比例不尽相同。特殊的地理位置、污染源差异和气象条件的差异造成各地市污染日数、级别的差异。6个地市污染天气过程时段大都相同,区域性污染明显。各地市PM10和PM2.5浓度平均最大值均出现在冬季,PM10浓度平均最小值均出现在夏季,各市PM2.5浓度平均最小值出现的季节不同。6个地市PM10和PM2.5浓度值的月变化趋势相似。不同季节各地市PM10和PM2.5浓度日变化趋势不同,极值出现的时间也各不相同,极值出现的时间与气象条件和人类活动关系密切。秋、冬季各地市PM10和PM2.5浓度日较差多大于春、夏季的。各地市PM10和PM2.5浓度日均值与当地的日均气温、风速、能见度呈负相关关系,与相对湿度呈正相关关系且相关性比较显著。     

Recent progress in estimating uncertainty in geomagnetic field modeling

Abstract

Recent work pertaining to estimating error and accuracies in geomagnetic field modeling is reviewed from a unified viewpoint and illustrated with examples. The formulation of a finite dimensional approximation to the underlying infinite dimensional problem is developed. Central to the formulation is an inner product and norm in the solution space through which a priori information can be brought to bear on the problem. Such information is crucial to estimation of the effects of higher degree fields at the Core-Mantle boundary (CMB) because the behavior of higher degree fields is masked in our measurements by the presence of the field from the Earth's crust. Contributions to the errors in predicting geophysical quantities based on the approximate model are separated into three categories: (1) the usual error from the measurement noise; (2) the error from unmodeled fields, i.e. from sources in the crust, ionosphere, etc.; and (3) the error from truncating to a finite dimensioned solution and prediction space. The combination of the first two is termed low degree error while the third is referred to as truncation error.

The error analysis problem consists of “characterizing” the difference δz = z—z, where z is some quantity depending on the magnetic field and z is the estimate of z resulting from our model. Two approaches are discussed. The method of Confidence Set Inference (CSI) seeks to find an upper bound for |z—?|. Statistical methods, i.e. Bayesian or Stochastic Estimation, seek to estimate E(δz² ), where E is the expectation value. Estimation of both the truncation error and low degree error is discussed for both approaches. Expressions are found for an upper bound for |δz| and for E(δz² ). Of particular interest is the computation of the radial field, B., at the CMB for which error estimates are made as examples of the methods. Estimated accuracies of the Gauss coefficients are given for the various methods. In general, the lowest error estimates result when the greatest amount of a priori information is available and, indeed, the estimates for truncation error are completely dependent upon the nature of the a priori information assumed. For the most conservative approach, the error in computing point values of B_r at the CMB is unbounded and one must be content with, e.g., averages over some large area. The various assumptions about a priori information are reviewed. Work is needed to extend and develop this information. In particular, information regarding the truncated fields is needed to determine if the pessimistic bounds presently available are realistic or if there is a real physical basis for lower error estimates. Characterization of crustal fields for degree greater than 50 is needed as is more rigorous characterization of the external fields.     

Under‐ice salinity and stable isotope distribution of Saroma‐ko Lagoon,Hokkaido, northern Japan

In winter, lakes and lagoons at high altitudes or high latitudes have interesting hydrological cycles that differ from those in other seasons or in other regions, because water surfaces are covered with ice. Hydrological balances of lakes and lagoons are complex dynamic systems, and to elucidate them, isotopic tracers of water have been used as effective tools along with observations of precipitation, evaporation, inflows, and outflows. Here, to understand hydrological processes during freezing periods in the brackish Saroma‐ko Lagoon, Hokkaido, northern Japan, we examined horizontal and vertical distributions of salinity and isotope compositions of lagoon water and ice in 2005 and 2006. Horizontal and vertical gradients of salinity and isotope compositions were observed from the river mouth to the sea channel, and factors determining these distributions were considered. The mixing of freshwater and seawater and a freezing effect were presumed to be factors in relationships between salinity and isotopes and in relationships between surface waters and ice just above the water. A simple box model for water balance was constructed based on these putative factors to reproduce the distributions of salinity and isotope compositions of surface waters and ice. An evaluation of the model revealed that this hydrological system is controlled primarily by horizontal advection of the epilimnion, freshwater influx, and the ice growth rate. Copyright © 2009 John Wiley & Sons, Ltd.     

2007-2019年太湖藻型和草型湖区叶绿素a变化特征及影响因子

基于太湖31个站点的逐月监测数据,分析了2007-2019年太湖藻型湖区和草型湖区的叶绿素a变化特征,并分析研究不同环境因子对不同类型湖区叶绿素a的影响.结果表明,近年来太湖不同类型湖区的总磷浓度和叶绿素a浓度变化基本一致,均呈波动上升趋势.不同类型湖区的总磷浓度拐点均为2015年,叶绿素a浓度拐点均为2016年.最低月平均水温、前冬积温、年平均水温、年均风速与藻型湖区和草型湖区叶绿素a浓度均呈显著相关.沉水植物分布面积与草型湖区叶绿素a浓度之间呈显著相关.湖西区年内和年度降雨剧烈变化,湖西区年降雨量与不同类型湖区当年叶绿素a浓度的关系不明显,5日极端降雨量与不同类型湖区下年度叶绿素a浓度均呈显著正相关.太湖蓝藻水华强度在短期内可能仍会处于较高水平,迫切需要高度重视高温时段太湖蓝藻打捞处置工作,保障饮用水安全;同时,要进一步加强湖西区强降雨期间的非点源污染防控措施研究,推动入湖污染通量稳步降低,并探索东西山之间及东茭咀附近水域沉水植物生态修复技术,降低风浪扰动作用,尽快恢复相关重要水域的沉水植物.     

广西近海灾害地质因素及声学反射特征

利用高分辨率地球物理资料及相关历史资料,对北部湾北部的广西近海灾害地质因素进行了地质地球物理解译,识别出海底沙波、海底沙脊、塌陷洼地、冲刷沟槽、浅层气、残积砂体、地层间断、埋藏丘、埋藏古河道等多种灾害地质因素.根据它们出现的频率、规模及声学特征可知:浅层气和埋藏古河道是广西近海最为发育的灾害地质因素,其对海洋工程的施工与建设有较大的危害性.     

南海西部断裂系研究及其物理模拟实验证据

南海西部断裂系是由四条典型的走滑断裂所组成的断裂系统,是南海扩张的西部边界.此断裂系主要是在白垩纪以来的印-藏碰撞、新生代印支挤出和南海扩张的共同作用下形成的.通过模拟实验,探讨此断裂系的成因、演化过程,认识到此断裂系经历了五期构造运动.     

我国西北地区多年降水的氢氧同位素分布特征研究

降水是干旱区水文循环研究不可缺少的水文要素,为了揭示我国西北地区大气降水的氢氧同位素时空分布特征,合理开展不同尺度水文循环研究和建立对比标准,系统搜集分析了乌鲁木齐、银川、张掖、兰州、平凉、西安和拉萨七个地区多年大气降水的氢氧同位素数据资料。分析结果表明:乌鲁木齐、银川、张掖和兰州四个地区的δ18O值夏半年明显高于冬半年,从全年尺度上来看只是受到了温度效应的影响;而位于关中盆地的西安地区则由于复杂的水汽来源,冬半年表现出受温度效应的控制,夏半年转为雨量效应控制为主。平凉地区δ18O与其它海拔相近地区(如兰州)相比5~9月份均偏负,这与平凉地区较弱的城市热岛效应有关。西北地区大气降水δD和δ18O的变化范围均在全球大气降水的变化范围之内,除平凉和拉萨外,其它几个地区大气降水线方程的斜率和截距均小于全球大气降水线,说明这些地区的降水是在干旱环境下经历较强程度的蒸发条件下进行的,且在降水过程中还可能受到了局地二次蒸发凝结等水汽循环的影响。而该区域大气降水的氘盈余(d值)表现出冬半年高、夏半年低的特点,表明冬半年和夏半年水汽来源不同或者水源地的蒸发条件不同。