电感耦合等离子体质谱法测定铅合金中的微量杂质元素镉和锡

铅合金中的镉和锡由于含量较低,国家标准方法均为单一元素分析,步骤繁琐,检出限高,难以达到理想的检出要求。本文建立了应用电感耦合等离子体质谱法(ICP-MS)测定铅合金中微量级(μg/g级)杂质元素镉和锡的分析方法。采用单一的低浓度硝酸溶解铅合金,用低温慢溶的方式使样品溶解更加完全,减少了多离子对仪器的干扰;通过铅基体匹配和加入酒石酸保证了标准与样品介质的一致性,同时避免了锡的水解;以~(103)Rh作为内标元素,~(111)Cd和~(118)Sn作为测量同位素克服了质谱干扰。方法检出限为镉0.05 ng/g、锡0.04 ng/g,比国家标准方法的检出限(1~6μg/g)低,精密度小于4%。该方法试剂用量少,减少了处理样品的复杂性,实现了合金中微量级元素的准确测定。     

The Atacama Cosmology Telescope project: A progress report

The Atacama Cosmology Telescope is a project to map the microwave background radiation at arcminute angular resolution and high sensitivity in three frequency bands over substantial sky areas. Cosmological signals driving such an experiment are reviewed, and current progress in hardware construction is summarized. Complementary astronomical observations in other wavebands are also discussed.     

航空矢量重力测量水平分量的带限直接地形影响

基于第二类Helmert凝聚法的级数展开式,独立推导了航空矢量重力测量水平分量带限直接地形影响的计算公式。在中国西部山区选取了两条沿纬圈方向4000m航线高度上的航线,采用 的数字高程模型基于解析核计算了水平分量的直接地形影响,经低通滤波后与基于带限公式计算的地形影响进行了比较。数值计算结果表明,二者吻合较好,本文给出的带限地形影响公式可用于航空矢量重力测量水平分量的地形归算。     

大型射电望远镜主反射面调整方法研究

随着毫米波天文学和空间通信的重要性日益提高, 对天线性能提出了越来越高的要求, 而天线性能往往受到其反射器表面精度的限制. 微波全息技术是一种快速有效的检测反射面天线表面轮廓的测量技术. 通过微波全息测量得到天线口径场, 计算天马65m射电望远镜反射面与理想抛物面的偏差. 天马65m射电望远镜的主反射面板是放射状的, 有14圈. 面板的每个角都固定在面板下方促动器的螺栓上进行上下移动, 且相邻面板交点处的拐角共用一个促动器. 采用平面拟合的方法可以计算各块面板拐角处的调整值, 但是同一个促动器会得到4个不同的调整量. 通过平面拟合, 同时以天线照明函数为权重的平差计算方法得到相邻面板拐角的一个平差值, 即天马65m射电望远镜1104个促动器的最佳调整值. 通过多次调整和新算法的应用, 天马65m射电望远镜反射面的面形精度逐渐提高到了0.24mm.     

机载激光测深精度外部检核方法

给出了单波束测深的原理,分析了单波束观测数据预处理模型,提出了采用单波束测深成果检核机载激光数据质量的技术方法,并以我国自行研制的机载激光测深系统为例,给出了该系统在某海区试验数据的外部检核结果.针对两种测深手段之间明显存在系统性偏差的问题,提出了以单波束测深成果为控制,对机载激光测深数据系统偏差进行校正和补偿的处理方...     

TMI、AMSR-E全球海表温度与Argo近海表温度的比较

本文将TMI（Tropical Rainfall Measuring Mission （TRMM）Microwave Imager）和AMSR-E（Advanced Microwave Scanning Radiometer for the Earth Observing System）卫星观测的全球海表温度与Argo浮标观测的近海表温度进行了比较。并检验了影响海温变化的因素,包括风速、水汽含量、液态云和地理位置。结果显示,TMI、AMSR-E海表温度与Argo近海表温度均明显相关。在低风速时,TMI、AMSR-E海表温度整体比Argo近海表温度高。在低风速时,TMI比AMSR-E海表温度更接近Argo近海表温度,但TMI海表温度在高纬可能没有经过良好校正。温度差异显示,在低水汽含量时,TMI和AMSR-E海表温度显示出暖的差异,代表TMI和AMSR-E海表温度在高纬均没有经过良好校正。黑潮延伸区的海表温度变化要比海潮区明显。春季在黑潮延伸区,卫星观测的海表温度与Argo近海表温度差异较小。在低风速时,TMI和AMSR-E海表温度均经过了良好校正,而TMI比AMSR-E效果更好。     

Assessing the Measurement Consistency Between the Jason-2/AMR and SARAL/AltiKa/DFMR Microwave Radiometers Using Simultaneous Nadir Observations

SARAL/AltiKa has a Dual Frequency Microwave Radiometer (DFMR), and Jason-2 has an Advanced Microwave Radiometer (AMR). Both microwave radiometer sensors include a 23.8 GHz primary water sensing channel. The measurement consistencies between DFMR and AMR are important for establishing a consistent altimetry data set between SARAL/AltiKa and Jason-2 in order to accurately assess sea level rise in a long-term time series. This study investigates the measurement consistency in the 23.8 GHz channel between DFMR and AMR at the Simultaneous Nadir Overpasses (SNO's) between the two satellites and also at coldest ocean brightness temperature locations. Preliminary results show that while both instruments show no significant trends over the one year since the launch of SARAL, a consistent relative bias of 2.88 K (DFMR higher than AMR) with a standard deviation of 0.98 K is observed. The relative bias at the lowest brightness temperature from the SNO method (-3.82 K) is consistent with that calculated from coldest ocean method (-3.74 K). The relative bias exhibits strong latitude (and scene temperature) dependency, changing from -3.82 K at high latitudes to -0.92 K near the equator. There also exists an asymmetry between the northern and southern hemisphere. The relative bias increases toward the lower end of brightness temperature.     

水热条件下利用微波加热从粉煤灰合成沸石研究

着重选用NaOH水溶液为反应前驱物, 通过改变反应温度、NaOH浓度与合成时间等参数, 在水热条件下利用微波加热直接对粉煤灰进行晶化, 合成得到了浊沸石、菱沸石、NaP1沸石3种沸石.粉煤灰转化为沸石率约15%~40%.研究表明: (1) 反应体系在15min左右即有合成沸石产生, 30min左右合成沸石转化率达到最佳; (2) 为保证沸石晶核生成和晶体的生长, 反应体系的溶液/粉煤灰比不应低于2.5; (3) 在溶液/粉煤灰比为2.5时, 应控制加热时间在30min左右.      

Optimisation of the Population Monte Carlo algorithm: Application to constraining isocurvature models with cosmic microwave background data

We optimise the parameters of the Population Monte Carlo algorithm using numerical simulations. The optimisation is based on an efficiency statistic related to the number of samples evaluated prior to convergence, and is applied to a D ‐dimensional Gaussian distribution to derive optimal scaling laws for the algorithm parameters. More complex distributions such as the banana and bimodal distributions are also studied. We apply these results to a cosmological parameter estimation problem that uses CMB anisotropy data from the WMAP nine‐year release to constrain a six parameter adiabatic model and a fifteen parameter admixture model, consisting of correlated adiabatic and isocurvature perturbations. In the case of the adiabatic model and the admixture model we find that the number of sample points increase by factors of 3 and 20, respectively, relative to the optimal Gaussian case. This is due to degeneracies in the underlying parameter space. The WMAP nine‐year data constrain the admixture model to have an isocurvature fraction of 36.3 ± 2.8 %. (© 2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

弱流场调制下的海面微波散射模拟研究

根据海面微波散射的多尺度模型以及波流相互作用理论,对一维弱流场调制下的海面微波散射截面进行了数值模拟。结果表明,利用数值方法直接求解波作用量方程获得的海浪调制谱并结合多尺度模型可以较好地模拟弱流场引起的雷达散射截面的变化。内波等海洋现象调制了海浪谱,使得雷达散射截面反映出这些海洋特征,整个调制过程的模拟对于分析这些海洋现象并更好地利用其雷达数据具有重要意义。