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61.
62.
2002年11月30至12月4日,北京持续4天大雾天气,空气污染物在持续的稳定层结条件下,空气质量连续3天达5级以上。文中分析了大雾天气各主要污染物的变化特征,以及此次过程中天气形势的特点及演变,并对造成大雾日空气污染天气的物理量分布特征进行分析。结果表明:高空WNW气流、稳定性持续增加、逆温层结持续存在、低空风速较小、相对湿度大,导致局地污染物不能及时随大气扩散;1000~700hPa有弱的上升气流形成和维持,与500hPa高空下沉气流之间在低空的某层高度上形成稳定层结(逆温层),导致大雾及重污染的形成;850hPa为暖区,850~500hPa为冷平流,有利于大雾的形成和加重。 相似文献
63.
文章介绍了广东省气象系统开展空气质量预报的概况,包括使用的预报工具,其预报能力与业务运行的预报质量分析,以及进一步提高预报水平的一些设想。 相似文献
64.
A case study of warm air advection over the Arctic marginalsea-ice zone is presented, based on aircraft observations with direct flux measurements carriedout in early spring, 1998. A shallow atmospheric boundary layer (ABL) was observed, which wasgradually cooling with distance downwind of the ice edge. This process was mainly connected with astrong stable stratification and downward turbulent heat fluxes of about 10–20 W m-2, but wasalso due to radiative cooling. Two mesoscale models, one hydrostatic and the other non-hydrostatic,having different turbulence closures, were applied. Despite these fundamental differences betweenthe models, the results of both agreed well with the observed data. Various closure assumptions had amore crucial influence on the results than the differences between the models.Such an assumption was, for example,the parameterization of the surface roughness for momentum (z0) and heat (zT). This stronglyaffected the wind and temperature fields not only close to the surface but also within and abovethe temperature inversion layer. The best results were achieved using a formulation for z0 that took intoaccount the form drag effect of sea-ice ridges together withzT = 0.1z0. The stability within theelevated inversion strongly depended on the minimum eddy diffusivity Kmin. A simple ad hocparameterization seems applicable, where Kmin is calculated as 0.005 timesthe neutral eddy diffusivity. Although the longwave radiative cooling was largest within the ABL, theapplication of a radiation scheme was less important there than above the ABL. This was related to theinteraction of the turbulent and radiative fluxes. To reproduce the strong inversion, it wasnecessary to use vertical and horizontal resolutions higher than those applied in most regional andlarge-scale atmospheric models. 相似文献
65.
The development of the boundary layer during a cold air outbreak in the FramStrait is documented by aircraft measurements. The convection was organisedinto roll vortices with aspect ratios increasing from 2.9 near the ice edgeto more than 6 at 100 km further downstream. This increase coincides with anincrease of the latent heat release in the cloud layer. The stability parameter-zi/L varies from about zero at the ice edge to 30 at a distance of 200 kmdownstream over open water where the satellite picture still shows cloudstreets. The increase is mainly due to the deepening of the boundary layer.The turbulent vertical sensible and latent heat fluxes near the surface amountto 400 W m-2 within a 300 km off-ice zone. 25% of the upward heat fluxin the subcloud layer is carried out by organised roll motions. Experimentswith a 2-dimensional non-hydrostatic model show a similar roll aspect ratio inthe first 50 km, but further downstream where condensational heating is moreimportant the modelled roll wavelengths are distinctly smaller than the observedones. 相似文献
66.
Organic pollutants associated with macromolecular soil organic matter: Mode of binding 总被引:2,自引:0,他引:2
H. H. Richnow R. Seifert J. Hefter M. Link W. Francke G. Schaefer W. Michaelis 《Organic Geochemistry》1997,26(11-12)
A study of ether-linked moieties in macromolecular bound residues of polycyclic aromatic hydrocarbons (PAH) generated in bioremediation experiments was performed using high temperature hydrolysis degradation with subsequent analysis of the products by GC-MS. This hydrolysis reaction was specifically designed to cleave ether bonds including relatively stable diarylether structures. Among the reaction products, aromatic alcohols representing typical microbiologically derived metabolites of PAH were found in addition to natural compounds. Thus, parts of the bound residues appeared to be linked within the macromolecular material by ether bonds. Model experiments with an oxidoreductase enzyme and aromatic alcohols indicate the formation of these ether bonds to be an enzyme-catalysed process. 相似文献
67.
采用单道扫描等离子体发射光谱法测定了大洋多金属结核及深海沉积物中的稀土元素与钪,比较了不同功率下各稀土元素的检测限,研究了低功率下的稳定性,拟定了可靠的样品处理方法。方法经多金属结核及深海沉积物国家标准GBW07313、GBW07249分析验证,结果与标准值相符。测定精度(RSD)在13%~53%。已用此法为第2批多金属结核和深海沉积物标准物质提供了定值数据,其结果无剔除值 相似文献
68.
锇粉中杂质元素分析方法研究 总被引:2,自引:0,他引:2
利用ICP_MS技术建立了锇粉中痕量杂质元素的分析方法。在浓HNO3介质中,锇以OsO4形式挥发除去,分离锇基体后,可直接测定的痕量元素达50余种。取样量0.1g,测定限为0.2~246ng/g,可实现质量分数w(Os)为99.9999%锇粉中杂质元素测定。结合ICP_AES测定K、Na、Ca、Mg、Al、Fe、Si和P,可实现锇粉原料及产品的纯度分析。 相似文献
69.
R. M. Godinho M. C. Freitas H. Th. Wolterbeek 《Journal of Atmospheric Chemistry》2004,49(1-3):355-361
The present work evaluates the stress effects in two epiphytic lichen species with different thallus morphology, the foliose Parmelia caperata and the fruticose Evernia prunastri, as resulting from transplanting from an unpolluted to an air-polluted area. Lichen samples were collected in Portugal in a clean area, during the spring 2003, and transplanted (1) to the same zone nearby and (2) to a polluted area as affected by an industrial complex. Transplant samples were taken periodically during four months in both places. At the same time lichen samples from the clean-air site native (in-situ) populations were also collected. For each sample were measured the chlorophyll content, the chlorophyll degradation and the cell membrane damage, the latter represented by leacheate conductivity. During the experiment the meteorological conditions were registered. The results indicate the absence of stress effects of transplanting as such, and suggest that leachate conductivity may be the more sensitive indicator of general lichen vitality. 相似文献
70.
In permafrost regions of Qinghai-Tibetan Plateau, the critical embankment height must be considered in the process of the construction of highway, especially for the global climatic warming. In this paper, the two-dimensional numerical analysis for the critical embankment height (for gravel road surface and coarse-grained soil) has been performed by using thefinite element method. In the calculation, we think that the service life of the construction is at least 50 years. The mean annual air temperatures applied to the calculation model are -6.5 ℃, -6.0 ℃, -5.5 ℃, -5.0 ℃, -4.5 ℃ and -4.0 ℃, respectively, and the value of temperature rise are taken as 1.10℃ in the coming 50 years. The minimum embankment heights derived from the analysis are 0.85 m, 0.92 m, 1.01 m, 1.18 m, 1.60 m and 2.66 m for the different mean annual air temperatures and the maximum embankment heights are 7.68 m,7.55 m, 7.34 m, 7.00 m, 6.45 m and 5.85m, accordingly. On condition that the service life of embankment is 50 years, the critical value of the mean annual air temperature is -3.5 ℃. Namely, in the areas where the mean annual air temperature is higher than -3.5 ℃, the critical embankment height does not exist. 相似文献