台湾海峡西部海域大气中金属的特征──Ⅱ.大气颗粒金属的来源和入海通量

通过因子分析和相关回归分析,台湾海峡海域大气中颗粒物中金属的来源特征为:Fe主要来自地壳风化尘土,少量来自污染物.Pb和Cd主要来自污染源,少量Pb来自尘土和海水.Na主要来自海水,但也有少量来自尘土和次生气溶胶.Cu主要来自尘土,部分来自污染物,少量来自海水.比较台湾海峡西部海域来自大气和来自河流的金属通量,大气中的Cu低于河流,Pb高于河流,Cd略高于河流.     

海洋气团对沿海城市大气环境影响与识别研究

本研究通过识别海洋气团特征及沿海城市大气受到海洋气团的影响方式与程度,为评价沿海城市空气环境质量提供科学依据。以青岛市为例,收集大气气溶胶样品中放射性核素~(210)Pb、40K数据及采集时段当地大气颗粒物数据;分析~(210)Pb活度浓度与气溶胶颗粒物浓度变化;对当地当时大气气团进行溯源分析。研究表明:(1)研究期间青岛沿岸地区2015年4月至2016年6月与2016年6月至2017年6月大气污染特征显著不同,前者~(210)Pb活度浓度与污染颗粒物浓度显著相关,而后者~(210)Pb活度浓度与污染颗粒物无相关关系;(2)穿越海洋的陆地气团呈现出高活度浓度、低颗粒物浓度的特征;来自海洋气团的气溶胶呈现出低活度浓度、低颗粒物浓度的特征;(3)海洋气团气溶胶中~(210)Pb活度浓度较低。临近大陆的海洋(黄海、东海)上层大气受到大陆气团的影响,其海洋气团的特征有所减弱。~(210)Pb活度浓度、颗粒物浓度(PM2.5)可作为判断海洋气团的指标,识别"来自海洋的气团"与"经过海洋的气团"。     

Nitrogen and sulfur species in Antarctic aerosols at Mawson,Palmer Station,and Marsh (King George Island)

High volume bulk aerosol samples were collected continuously at three Antarctic sites: Mawson (67.60° S, 62.50° E) from 20 February 1987 to 6 January 1992; Palmer Station (64.77° S, 64.06° W) from 3 April 1990 to 15 June 1991; and Marsh (62.18° S, 58.30° W) from 28 March 1990, to 1 May 1991. All samples were analyzed for Na⁺, SO ₄ ^2– , NO ₃ ^– , methanesulfonate (MSA), NH ₄ ⁺ ,²¹⁰Pb, and⁷Be. At Mawson for which we have a multiple year data set, the annual mean concentration of each species sometimes vary significantly from one year to the next: Na⁺, 68–151 ng m^–3; NO ₃ ^– , 25–30 ng m^–3; nss SO ₄ ^2– , 81–97 ng m^–3; MSA, 19–28 ng m^–3; NH ₄ ⁺ , 16–21 ng m^–3;²¹⁰Pb, 0.75–0.86 fCi m^–3. Results from multiple variable regression of non-sea-salt (nss) SO ₄ ^2– with MSA and NO ₃ ^– as the independent variables indicates that, at Mawson, the nss SO ₄ ^2– /MSA ratio resulting from the oxidation of dimethylsulfide (DMS) is 2.80±0.13, about 13% lower than our earlier estimate (3.22) that was based on 2.5 years of data. A similar analysis indicates that the ratio at Palmer is about 40% lower, 1.71±0.10, and more comparable to previous results over the southern oceans. These results when combined with previously published data suggest that the differences in the ratio may reflect a more rapid loss of MSA relative to nss SO ₄ ^2– during transport over Antarctica from the oceanic source region. The mean²¹⁰Pb concentrations at Palmer and Marsh and the mean NO ₃ ^– concentration at Palmer are about a factor of two lower than those at Mawson. The²¹⁰Pb distributions are consistent with a²¹⁰Pb minimum in the marine boundary layer in the region of 40°–60° S. These features and the similar seasonalities of NO ₃ ^– and²¹⁰Pb at Mawson support the conclusion that the primary source regions for NO ₃ ^– are continental. In contrast, the mean concentrations of MSA, nss SO ₄ ^2– , and NH ₄ ⁺ at Palmer are all higher than those at Mawson: MSA by a factor of 2; nss SO ₄ ^2– by 10%; and NH ₄ ⁺ by more than 50%. However, the factor differences exhibit substantial seasonal variability; the largest differences generally occur during the austral summer when the concentrations of most of the species are highest. NH ₄ ⁺ /(nss SO ₄ ^2– +MSA) equivalent ratios indicate that NH₃ neutralizes about 60% of the sulfur acids during December at both Mawson and Palmer, but only about 30% at Mawson during February and March.     

低Peclet数下剪切流中气溶胶粒子的传质率

本文研究了低Péclet数下剪切流中气溶胶粒子的传质率。Péclet数(Pe)是物质浓度的对流输送项对分子扩散项的比。它等于Reynolds数(Re)与Schmidt数的(Sc)之积。本文应用奇异扰动方法得到了无因次传质率Nu(Nusselt数)在小Péclet数条件下的四项渐近展式，因而?改进了前人的结果。     

BALLOON-BORNE MEASUREMENTS OF AEROSOL VERTICAL DISTRIBUTIONS OVER BEIJING DURING THE SUMMER AND AUTUMN OF 1993

The results of two balloon soundings during the summer and autumn of 1993 from the Xianghe Observation Station are being utilized in a study of the temporal and spatial distribution of the atmospheric aerosols.The balloon,gondola,instrumentation and atmospheric conditions during the observation period are described.The temporal and spatial characteristics of aerosol concentration,size ratio,mixing ratio,and size distribution for both troposphere and strato-sphere are presented and analyzed.     

NOAA WP-3D instrumentation and flight operations on AGASP-II

The second Arctic Gas and Aerosol Sampling Program (AGASP-II) was conducted across the non-Soviet Arctic in March and April 1986, to study the aerosol, gaseous, chemical, and optical properties of Arctic haze. One component of the program was supported with an instrumented NOAA WP-3D atmospheric research aircraft. Measurements of wind, temperature, ozone, water vapor, condensation nucleus concentration, and aerosol scattering extinction coefficient were used to determine the locations and properties of haze layers. The first three NOAA WP-3D research flights were conducted north of Barrow, Alaska, and over the Beaufort Sea northeast of Barter Island, Alaska. The next three sampled conditions in the high Arctic near Alert, Northwest Territories, Canada. All basic meteorological, gas, and aerosol systems are described. The WP-3D flight tracks and operations are presented.     

Interpretation of Mauna Loa atmospheric transmission relative to aerosols,using photometric precipitable water amouts

Precipitable water measurements made coincident in time and space with direct broadband solar irradiance measurements are used in conjunction with an atmospheric transmission model to derive a parameter whose major dependence is on total aerosol extinction. Irradiance measurements are used to calculate an atmospheric transmission factor (ATF) that is independent of the instrument calibration and the extraterrestrial solar constant. The dependency of the ATF on precipitable water is determined using LOWTRAN5, an atmospheric transmission model with high spectral resolution. Precipitable water measurements are then used to adjust the measured ATF to correspond to an ATF value obtained for a constant precipitable water amount. The remaining variability in the adjusted ATF is due mostly to aerosol extinction. The technique is applied to a 6-year period (1978–1983) for clear-sky mornings at Mauna Loa, Hawaii (MLO). MLO ATF aerosol residuals are compared with independently measured monochromatic aerosol optical depth. Results show that the ATF aerosol residual is nearly equal to the 500 nm aerosol optical depth prior to the eruption of E1 Chichon, at which time a nonlinear time-dependent relationship between the two quantities is evident. ATF aerosol residuals reflect the spectrally integrated aerosol influence on transmission and, therefore, could indicate better than monochromatic optical depth the radiation balance perturbations due to aerosols. The 6-year precipitable water record for MLO, determined from a dual-channel sunphotometer, has a mean value of 0.3 cm. An annual cycle in precipitable water is evident, as is a 4-month 5-standard-deviation drought from December 1982 through March 1983.     

从全波段太阳直射辐射确定大气气溶胶光学厚度 II：实验研究

本文通过比较太阳直射表和太阳光度计探测的大气柱气溶胶光学厚度，分析了从太阳直射表探测的全波段太阳直射光强信息确定大气柱气溶胶光学厚度的误差，并应用北京观象台的太阳直射表观测资料，反演得到了 1990—1993年北京大气柱气溶胶光学厚度，分析了该光学厚度月与年变化规律以及1991年菲律宾皮纳图博火山爆发对北京大气气溶胶含量的影响。本文还提出了关于有效水汽含量的一个经验关系式，用于确定水汽对太阳辐射的吸收率。     

Aerosol concentrations and size distribution in the troposphere and lower stratosphere over Thumba

Rocket-borne ultraviolet photometers operating at =0.31 m have been used at Thumba (8°33N, 76°52E) to make measurements of atmospheric scattering at tropospheric and lower stratospheric altitudes. Measurements could be made of the amplitude of the scattered fluxes and the angular distribution up to an altitude of about 24 km on three rocket flights conducted as part of the 16 February 1980 solar eclipse campaign. These measurements have been used to study the size distribution as well as the number densities of aerosols in the troposphere and lower stratosphere over Thumba.