A New Way to Study Water-Vapor Absorption Coefficient

In the visible spectrum, the atmospheric attenuations to sunlight mainly include aerosol scattering, atmospheric molecule Rayleigh scattering and ozone absorption, while in the near-infrared spectrum （from 650 nm to 1 000 nm）, we must take water-vapor absorption into account. Based on the atmospheric correction theory, using spectrum irradiance data measured by Instantaneous Ground spectrometer, ozone content measured by Microtops Ⅱ ozone monitor, water-vapor content and aerosol optical thickness measured by sun photometer, we give a new way to study water-vapor absorption to sunlight, and the result shows that the main peak values of water-vapor absorption coefficients are 0.025 cm^-1, 0.073 cm^-1, 0.124 cm^-1, 0.090 cm^-1, 0.141 cm^-1 and 0.417 cm^-1, which respectively lie at 692 nm, 725 nm, 761 nm, 818 nm, 912 nm and 937 nm.     

等离子体发射光谱法测定大气颗粒物中的无机元素

建立了用等离子体发射光谱（ＩＣＰ－ＡＥＳ）测定大气颗粒物中无机元素的分析方法,包括样品消解体系的选择,仪器的操作条件及采样滤膜的选择,产对自行采样分析测得的无机元素数据作了初步的讨论。实验结果表明：采用ＨＮＯ３－ＨＣｌＯ４消解体系,操作方便,样品消解较完全;选用石英滤膜查减低空白值,保证测定质量以及同时在一张滤膜上测定大气颗粒物中的有机碳、元素碳及无机元素;内标法可有效降低由于仪器漂移等因素对测定     

ANALYSIS OF THE ATMOSPHERIC AEROSOL OPTICAL DEPTH OVER CHINA IN 1980s*

This paper retrieves the yearly and monthly mean 0.75μm aerosol optical depth(AOD) of 41 A-class solar radiation stations over China from 1979 to 1990,and analyzes the spatial and temporal distribution of AOD over China mainland.The data employed are daily direct solar radiation and sunshine duration,as well as the TOMS version-7 ozone observation data in the same time.The results indicate that the Siehuan Basin is the largest center of yearly mean AOD over China.and the other two larger centers lie in Wuhan City and the South Xinjiang Basin,separately.AOD values are also relatively larger in the middle-and-lower reaches area of Changjiang River.Shandong Peninsula and coastal area of Guangdong Province:while in Yunnan Province,coastal area of Fujian Province.most parts of Northwest and Northeast China,AOD values are relatively smaller.The distribution of AOD varies with different months.In most parts of China.the maximum of AOD occurs in spring season;but the minimum varies in different regions,From 1979 to 1990.in the Qinghai-Xizang Plateau,West Siehuan Basin,North Guizhou Province.most areas of the middle-and-lower reaches of Changjiang River,Shandong Peninsula and west part of South Xinjiang Basin.AOD shows an increasing trend.But in Northeast China,most part of Northwest China,Yunnan-Guizhou Plateau,western Guangxi Region and the coastal areas of East China,AOD shows decreasing tendency.Generally,the seasonal variation characteristics of AOD in China can be classified into four typical models,i.e.,mono-modal types A and B,bimodal and Poly-modal.     

VERTICAL DISTRIBUTION CHARACTERISTICS OF ATMOSPHERIC AEROSOLS IN LIAONING*

16 aircraft missions were conducted for the measurement of atmospheric aerosols in separate days of late spring and early summer of 1996 and 1997.The paper deals with detailed analysis of the variation in vertical/horizontal distributions of the concentration of the particles and their size distribution at 0-5 km above ground,and with the relations to temperature and relative humidity documented in general.Evidence suggests that the concentrations show different distribution features in vertical above and below the cap of the mixed layer:the particle size distribution is subject to a range of forming mechanisms,displaying a multi-modal pattern:the horizontal concentration experiences remarkable variation:temperature and relative humidity stratifications have conspicuous influence on the concentration and size distribution of aerosols.     

中国地区硫酸盐气溶胶的分布特征

建立了一个三维欧拉型排放/输送/转化/沉降模式,其主要特点是采用独立的气相化学子模式计算各种不同条件下SO2的转化速率,建立转化率的数据库,直接为欧拉模式调用,并对液相化学和湿清除过程进行了参数化处理。这样使模式既考虑了大气化学过程的非线性,又具有较高的计算效率,能够方便地计算年（季）尺度的硫酸盐气溶胶SO2-4的浓度分布。利用中尺度气象模式MM4和欧拉输送模式模拟了中国地区硫酸盐气溶胶的时空分布,其结果可以方便地应用到考虑硫酸盐气溶胶气候效应的气候模式中去。     

华南沿海地区太阳直接辐射、能见度及大气气溶胶变化特征分析

分析了中国华南地区福州、广州、海口、南宁等地1961～1990年太阳直接辐射总量、日照时数、总云量、大气能见度和地面水汽压等资料,并利用这些资料反演了该地区大气气溶胶的光学厚度值。结果表明：近30年来,华南地区太阳直接辐射总量和日照时数呈明显下降趋势。与60年代相比,80年代各站太阳直接辐射总量的年平均值均下降20%以上,其中广州下降29.2%;日照时数,广州减少了1.1 h,福州1 h,南宁0.9 h,海口0.5 h。分析发现,造成下降的原因不是由于云量或大气中水汽含量的变化,而是由于地面能见度的明显减小和大气气溶胶的增加。4站中,14时地面能见度均以夏季最好,最高值出现在7月;而地面能见度最差的季节海口、南宁两站在冬季,福州和广州两站在春季3、4月份。相比较而言,海口能见度最好,福州和南宁次之,广州最差。4站大气气溶胶光学厚度值的大小、年及季节变化与地面能见度有密切的关系,但两者不尽一致,因此,在研究气溶胶的辐射和气候效应时必须合理地考虑中高层大气气溶胶的分布。     

沙尘气溶胶对直接太阳辐射的衰减研究

基于在腾格里沙漠东南端进行的太阳辐射与气象要素观测,探讨晴空无云时沙尘气溶胶对直接太阳辐射的衰减;并利用太阳辐射观测资料,给出沙漠边缘垂直上空的大气混浊度的变化。根据4月份至9月份的观测资料,只选取天空无云(可测的太阳辐射)的气象条件,研究沙尘气溶胶造成的直接太阳辐射的衰减。结果表明,在晴好天气约为47.0%~2.6%,平均衰减约为16.9%;在沙尘天气约为90%~10%,平均衰减约为38%;沙尘天气气溶胶对太阳辐射衰减变化较大。大气混浊度(atmospheric turbidity:τ_a)在晴好天气下约为0.048~0.631,平均约为0.260;沙尘天气约为0.177~2.475,平均约为0.741。     

南京市PM2.5物理化学特性及来源解析

在夏、冬两季,分别在南京市4个站点进行为期7天的气溶胶PM2.5采样,同步采集并分离主要排放源的PM2.5样品,用X射线荧光光谱仪(XRF)分析得到气样及源样中PM2.5的化学成分,对南京市PM2.5的物理化学特性、富集因子进行了分析,并应用化学质量平衡法(CMB)计算各类源对气溶胶PM2.5的贡献。结果表明,南京市PM2.5的夏、冬平均值分别为69.1、139.5μg.m-3,PM2.5/PM10的全年平均值为63.9%;富集成分中,S、As、Zn、Pb等主要来源于人为污染源,Na则主要来源于海洋。来源解析的结果表明,各类污染源对南京市气溶胶PM2.5的贡献率分别为:扬尘37.28%、煤烟尘30.34%、硫酸盐9.87%、建筑尘7.95%、汽车尘2.98%、冶炼尘2.57%、其他源9.01%。作者还对扬尘中的PM2.5进行了来源解析。     

基于气溶胶激光雷达观测的人工消减雾霾作业效果分析

利用气溶胶激光雷达观测的消光系数数据,对2019年12月北疆沿天山的石河子市开展人工消减雾霾作业效果进行分析,主要采用了符号检验、成对秩和检验等非参数性检验法,以及参数性t检验法等人工影响天气的物理统计检验方法,得出了基于气溶胶激光雷达消光系数为依据的人工消减雾霾作业效果。结果为：符号检验法检验得出飞机人工消减雾霾作业后20 min,400 m以下不同高度消光系数平均值减小的可信度达到非常显著的99.5%,进一步按照95%的可信度阈值得出减小值为0.05,减小率为9.8%;成对秩和检验法得出的作业正效果可信度达到97.5%,很显著;但是参数性t检验得出作业正效果的可信度只有90%～80%,未达到99.5%的阈值,显著性一般。这与作业采用了不同类型的催化剂如只用吸湿性干粉催化剂,以及播撒作业高度偏高导致作为样本的消光系数变化效果不能满足检验效率相关。进一步分析表明,飞机人工消减雾霾作业后20 min,400 m以下不同高度消光系数的减小响应效果自上而下递减,这与人工影响作业播撒的催化剂作用的物理机制自上而下逐步响应的过程相一致。     

激光雷达反演参数k值的研究

采用532 nm激光雷达2006年在兰州市不同天气状况下的观测数据,结合能见度因子、CE318太阳光度计观测数据,对利用Klett法求解时,k在不同天气状况下的取值进行了初步研究,结果表明:只有当0.7≤k≤1.0时,气溶胶消光系数的大小与能见度估算出的值相接近。但在k=0.7时,计算出的气溶胶消光系数正、负参半;k=1.0时,消光系数廓线在晴天无云的天气状况下同实际情况不符。通过进一步分析研究激光雷达和光度计的同期观测资料发现:k=0.8时,较合理的数据所占比例为100%,k=0.9为84%,k=1.0仅为12%。对兰州市区而言,利用激光雷达分析气溶胶光学特性时,取k=0.8或k=0.9较为合理。