南京北郊气溶胶中多环芳烃的污染特征及来源解析

利用2010年8月采集的南京北郊气溶胶样品,使用GC-MS对美国环保总局推荐的16种优先控制的多环芳烃含量、分布特征进行了研究。在此基础上,用特征比值法、主因子分析法分析得到南京市北郊大气中PAHs的主要来源为车辆尾气、燃煤、天然气和草木秸秆燃烧,并应用绝对因子分析法进一步定量计算主要源对PAHs的浓度贡献率。结果表明:1)大气颗粒物中16种多环芳烃的平均总质量浓度为135.85 ng/m~3,多环芳烃以4环为主,在可吸入颗粒物中的浓度占总浓度的88.7%;2)PM10中多环芳烃呈双模态分布,在9~10μm的粗模态和0.65~1.10μm的积聚模态上各出现一个峰值;3)天然气等对PAHs的贡献率为5.7%~44.1%,燃煤源的贡献率为20.7%~57.8%,汽车尾气的贡献率为4.6%~46.7%,木材燃烧的贡献率为2.9%~38.1%。本地交通排放和燃料燃烧是南京北郊大气颗粒物中PAHs的主要来源,远距离输送也对南京北郊气溶胶中的PAHs有重要贡献。     

大气气溶胶中的铁及其溶解度研究综述

生物活性铁(Fe) 进入生物地球化学循环中能够调节碳循环,影响海洋初级生产力,间接影响全球气候变化。决定 Fe生物可利用度的关键因子是可溶Fe含量,其中大气气溶胶的长距离传输是上层海洋获取生物可利用Fe的重要来源。近年来,对气溶胶中的Fe及溶解度的研究取得了重要进展,包括对不同区域Fe质量浓度和溶解度的观测以及对Fe溶解度影响因素的讨论。基于以上研究成果,汇总了近二十年全球部分陆地和海洋站点观测所得的不同粒径气溶胶颗粒物中的Fe质量浓度及其溶解度数据;重点介绍了气溶胶沉降入海洋前影响Fe溶解度的主要因素,包括Fe的来源、大气物理过程以及大气化学和传输混合过程等,并就各影响因素间的关联及相对重要性展开讨论;对未来气溶胶 Fe的研究方向和方法提出建议。     

长江三角洲地区大气气溶胶柱单次散射反照率特性研究

利用OMI卫星资料2006—2017年的483.5 nm波长的气溶胶柱单次散射反照率日均数据,分析了整层大气气溶胶单次散射反照率在长三角地区的时空分布特征,特别是其年际、月、季节变化特征.长江三角洲地区的大气气溶胶柱单次散射反照率越靠近海洋越大,而越靠近内陆越小.日均气溶胶柱单次散射反照率在0.881~0.971范围内变化,多年的平均值为0.939±0.024,最大分布概率出现在0.965~0.970区间,其值约为25％.长三角地区大气气溶胶柱单次散射反照率的年平均值集中于0.938~0.940之间,年际变化很小,变化值小于1％;月均柱单次散射反照率在6、8、9月有最大值,其值为0.968,而在2月有最小值,其值为0.915;季节平均单次散射反照率在夏季最大,其值为0.968,而在冬季最小,其值为0.919.     

The Holocene Evolution of the Ebre Delta Catalonia, Spain

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BHA受压失稳的模型及临界钻压公式

在教学及实践中发现,欧拉压杆模型与底部钻具组合(BHA)受压失稳模型之间存在较大差别,使用欧拉模型计算钻具的临界失稳钻压有很大的局限性。为此,推导了钻具在自重作用下失稳的临界钻压及临界失稳长度公式,以便使公式更符合BHA自身的受力特点,提高计算准确性。      

冲绳海槽海底地形的补偿模式研究Ⅱ.冲绳海槽均衡响应函数的地质解释

本文从区域补偿模式和实验均衡理论出发,利用重力和地形资料计算了冲绳海槽的均衡响应函数.结果表明,冲绳海槽南段弹性板有效厚度和补偿深度明显大于中段.结合其他地质地球物理资料解释认为,产生这种差异的原因主要是南、中两段岩石圈温度和补偿机制的不同所致.     

Correction of atmospheric effect on ADEOS/OCTS ocean color data: Algorithm description and evaluation of its performance

This paper first describes the atmospheric correction algorithm for OCTS visible band data used at NASDA/EOC. Sharing a basic structure with Gordon and Wang’s Sea WiFS algorithm, it uses 10 candidate aerosol models including the “Asian dust model” introduced in consideration of the unique feature of aerosols over the east Asian waters. Based on the observations at 670 and 865 nm bands, the algorithm selects a pair of aerosol models that account best for the observed spectral reflectances, and synthesizes the aerosol reflectance used for the atmospheric correction. Two different schemes for determining the value of the parameter for the aerosol model selection are presented and their anticipated estimation error is analyzed in terms of retrieved water reflectance at 443 nm. The results of our numerical simulation show that the standard deviation of the estimation error of the “weighted average” scheme is mostly within the permissible level of ±0.002, reducing the error by 18% on average compared to the “simple average” scheme. The paper further discusses the expected error under the old CZCS-type atmospheric correction, which assumes constant aerosol optical properties throughout the given image. Although our algorithm has a better performance than the CZCS algorithm, further analysis shows that the error induced by the assumption taken in the algorithm that the water-leaving radiance at 670 nm band is negligibly small may be large in high pigment concentration waters, indicating the necessity for future improvements.     

香河地区亚微米气溶胶粒子尺度谱分布特征

为了解香河地区气溶胶尺度谱的基本特征,自2012年5月起,利用扫描电迁移率粒径谱仪(SMPS)对河北香河地区的亚微米(13.8~723.4 nm)气溶胶尺度谱分布进行了近2 a的测量。基于该数据集,分析了气溶胶尺度谱的季节变化和日变化特征及气象要素对气溶胶浓度的影响。结果发现,观测期间埃根核模态(20.0~100.0 nm)、积聚模态(100.0~723.4 nm),以及总的气溶胶数浓度、表面积浓度和体积浓度均值分别为7.0×103cm~(-3)、7.5×103cm~(-3)、14.9×103cm~(-3)、1125μm2·cm~(-3)和50μm~3·cm~(-3)。香河地区积聚模态的粒子数浓度接近华北地区其他污染测站的结果,但高于发达国家的测值。冬季气溶胶的平均浓度最高(18.1×10~3cm~(-3)),而春季最低(12.3×10~3cm~(-3))。不同季节,气溶胶的数谱分布主要为单峰分布,平均峰值直径约为105 nm。气溶胶浓度的日变化受机动车排放的影响显著,存在早晚两个高值中心,分别出现在早上的06:00—09:00和晚上的19:00—21:00。风速、风向对气溶胶数浓度的影响较大,低风速(2 m/s)和南风条件,尤其是吹西南风时,气溶胶浓度的增加显著。     

Observation of Filterable Bromine Variabilities During Arctic Tropospheric Ozone Depletion Events in High (1hour) Time Resolution

The halogen ions Br^- and Cl^- together with NO₃ ^-, SO₄ ⁼, MSA^- (methane sulfonate), Na⁺ and NH₄ ⁺ were analysed by ion chromatography in extracts of more than 800 aerosol cellulose filter samples taken at Ny Ålesund, Svalbard (79°N, 12°E) in spring 1996 (March 27 - May 16) within the European Union project ARCTOC (Arctic Tropospheric Ozone Chemistry). Anticorrelated variations between f-Br (filterable bromine, i.e. water soluble bromine species that can be collected by aerosol filters) and ozone within the arctic troposphere were evaluated at a resolution of 1 or 2 hours for periods with depleted ozone and 4 hours at normal ozone. A mean f-Br concentration of 11 ng m^-3 (0.14 nmol m^-3) was observed for the whole campaign, while maximum concentrations of 80 ng m^-3 (1 nmol m^-3) were detected during two total O₃-depletion events (O₃ drop to mixing ratios below the detection limit of < 2 ppb). Anticorrelation between f-Br and O₃ was also seen during minor O₃-depletion episodes (sudden drop in O₃ by at least 10 ppb, but O₃ still exceeding the detection limit) and even for ozone variations near its background level (40-50 ppb). A time lag of about 10 hours between the change of ozone and of f-Br concentrations could only be found during a total ozone depletion event, when f-Br reached its maximum values several hours after ozone was totally destroyed. Bromine oxide (BrO) concentrations, measured by DOAS (Differential Optical Absorption Spectroscopy), and f-Br showed a coincident variability during almost the entire campaign (except in the case of total O₃-loss). Frequently enhanced anthropogenic nitrate and sulphate concentrations were observed during O₃-depletion periods. At O₃ concentrations < 10 ppb sulphate and nitrate exceed their typical mean level by 54% and 77%, respectively. This may indicate a possible connection between acidity and halogen release.