A Eulerian air pollution model for Europe with nonlinear chemistry

A long-range transport model with nonlinear chemical reactions is described. The model contains 35 pollutants and 70 chemical reactions. This is a Eulerian model defined on a space domain containing the whole of Europe. The spherical space domain (corresponding to the Earth's surface covered by the model) is mapped into a square plane domain and discretized by using a 32×32 grid. The grid increments are equidistant (both along the Ox axis and along the Oy axis). The choice of values of the physical parameters involved in the model and the numerical treatment of the model are shortly discussed. The model is tested with meteorological data for 1985 and 1989. The numerical results are compared with measurements at stations located in different European countries. Extensive comparisons of ozone concentrations for July 1985 with measurements taken at 24 European stations are also carried out. Results concerning three episodes in July 1985 as well as results obtained in the study of the sensitivity of the ozone concentrations to variations of NO _x and/or anthropogenic VOC emissions are presented. The advantages and the limitations of such a model are discussed. The model is continuously improved by adding new modules to it. The plans for improvements in the near future are outlined.     

Study of a model for correcting the effects of horizontal advection on surface fluxes measurement based on remote sensing

As well known, the methods of remote sensing and Bowen Ratio for retrieving surface flux are based on energy balance closure; however, in most cases, surface energy observed in experiment is lack of closure. There are two main causes for this: one is from the errors of the observation devices and the differences of their observational scale; the other lies in the effect of horizontal advection on the surface flux measurement. Therefore, it is very important to estimate the effects of horizontal advection quantitatively. Based on the local advection theory and the surface experiment, a model has been proposed for correcting the effect of horizontal advection on surface flux measurement, in which the relationship between the fetch of the measurement and pixel size for remote sensed data was considered. By means of numerical simulations, the sensitivities of the main parameters in the model and the scaling problems of horizontal advection were analyzed. At last, by using the observational data acquired in agricultural field with relatively homogeneous surface, the model was validated.     

西太平洋副热带高压影响下北京区域性暴雨的个例分析

北京地区大降水(≥25 mm/d)天气有72%出现在7~8月份,其中直接受西太平洋副热带高压(副高)影响的大降水占46%,它们主要产生在西风槽与副高相互作用的天气形势下。通过对该类暴雨的典型个例分析表明,由于受副高的影响,对流层低层副高南面的偏东气流将海上充沛的水汽输送到大陆,并折向北与偏北气流相遇,汇集在北京附近。同时,副高西北边缘与西风槽之间形成较强的能量锋区,该锋区南面的高温高湿气团蕴藏了较深厚的湿有效位能,在湿位涡的斜压项作用下转化为动能,倾斜垂直涡度发展激发了强烈的上升运动。在斜压扰动作用下,对流层中层差动涡度平流和副高西侧的暖平流破坏了北京及邻近区域的准地转平衡,动力强迫和热力强迫共同作用激发了次级环流,该处的上升运动得到加强。暴雨就是产生在强的能量锋附近低层气旋性涡度发展、高层辐散显著的地方。此外,副高西侧低层的暖湿气流北上,较强的差动假相当位温平流促使大气层结向对流不稳定发展,这对于暴雨局地的再增强是不可忽视的因素。由此,形成对该类暴雨天气预报的着眼点。     

Importance of advective zone in longitudinal mixing experiments

One-dimensional Fickian dispersion models such as the advection diffusion equation (ADE) are commonly used to analyse and predict concentration distributions downstream of contamination events in watercourses. Such models are only valid once the tracer had entered the equilibrium zone. This paper compares previous theoretical, experimental and numerical estimates of the distance to reach the equilibrium zone with new experimental values, obtained by examining the change of skewness in a tracer profile, downstream of a cross-sectionally well mixed source. Closer agreement was found with Fischers’ theoretical estimate than prior experimental and numerical studies.     

Estimation of Sensible Heat Flux from Surface Temperature Wave and One-Time-of-Day Air Temperature Observation

By means of the algorithm presented here, the temporal course H(t) and the daily mean H¯ of the sensible heat flux H can be estimated from measurements of the thermodynamic surface temperature (as a function of time) and from a one-time-of-day air temperature observation. In addition to these temperatures, one needs estimates for daily mean wind speed, for the roughness lengths of momentum and heat transfer, and for the displacement height. First, a quite general solution of the equation for heat conductance (equation for the vertical profile of potential temperature (z,t)) in the dynamic sublayer will be presented. The undetermined parameters in this solution will be defined with the aid of the above mentioned measurements. The influence of horizontal advection will be taken into account. After that, the sensible heat flux can be evaluated from the temperature difference between surface and air with the well known resistance formulae. In this paper the algorithm is derived for areas with homogeneous surfaces, i.e., with uniform surface temperatures. Finally, the method will be verified by measurements taken during the field campaigns HIBE 89 (Hildesheimer Börde in Germany) and EFEDA 91 (Spain). The root mean square errors (RMSE) for the comparison between measurement and model with regard to the temperature difference of surface and air amount to one or two degrees Kelvin, and the error of H¯ reaches 10 to 25 per cent. The method can be used to determine the sensible heat flux from measurements of surface temperatures by satellites (e.g., METEOSAT), but can also be applied to ground based measurements. For instance, horizontal temperature advection can be estimated from measurements at a single location, especially if more than one near-surface air temperature is available. The procedure can be generalized for larger areas, which consist of various surface types with different surface temperatures. This generalization of the algorithm is in progress and will be addressed in a subsequent paper. It will allow us to improve the estimates for H(t) by means of temperature measurements from, e.g., NOAA/AVHRR or LANDSAT/TM, taking into account the heterogeneity of the area that is contained in one METEOSAT pixel.     

2007年红河州一次典型两高辐合区强降水过程分析

2007年7月,红河州多受两高间辐合区影响,产生强降水,选取7月18～20日强降水过程进行分析,得出:单纯的两高辐合区并不一定能产生强降水。虽然此次过程中有深厚的西南涡从四川东南移,但强降水的触发机制并不是西南涡,而是高空冷平流,且高空冷平流具有高层强、低层弱的特点。水汽、能量条件表现出在高层随着环流背景场南移、中低层少变的特点,较强的上升运动也集中在对流层中上层。MM5对于此次过程较强降水发生的时间、区域有较好的预报能力,但降水量级偏小。     

伴随对流层中低层气温持续下降的雪转雨过程分析

利用欧洲中期天气预报中心（ECMWF）0.25°×0.25°分辨率细网格模式产品、探空观测资料和风廓线雷达等资料,对2014年2月18日浙江嘉兴雨雪天气过程中降水相态先由雨转雪、再由雪转雨的变化条件进行了分析,并对ECMWF细网格模式产品进行了预报性能检验,结果表明：模式形势预报准确,但未能预报出雪转雨过程。在对流层中低层气温持续降低的情况下,水汽凝结高度不同是造成两次相态转换的主要原因。上午垂直运动加强,水汽充沛,降水粒子的凝结高度高,足以形成大的雪花,在较低的零度层高度以下降落时不至于融化;下午垂直运动减弱,水汽集中在低层,尽管这一高度层的气温在-3～-2 ℃,但是不足以凝结成固态降水,同时地面气温受海上暖平流影响而回升,因此降水相态由雪转雨。     

Beach tar accumulation, transport mechanisms, and sources of variability at Coal Oil Point, California

A new field method for tar quantification was used at Coal Oil Point (COP), California to study the mechanisms transporting oil/tar from the nearby COP natural marine hydrocarbon seep field. This method segregates tar pieces into six size classes and assigns them an average mass based on laboratory or direct field measurements. Tar accumulation on the 19,927m(2) survey area was well resolved spatially by recording tar mass along twelve transects segmented into 4-m(2) blocks and then integrating over the survey area. A seasonal trend was apparent in total tar in which summer accumulations were an order of magnitude higher than winter accumulations. Based on multiple regression analyses between environmental data and tar accumulation, 34% of tar variability is explained by a combination of onshore advection via wind and low swell height inhibiting slick dispersion.     

Improvement of the semi-Lagrangian advection scheme in the GRAPES model: Theoretical analysis and idealized tests

ABSTRACT The Global/Regional Assimilation and PrEdiction System （GRAPES） is the newgeneration numerical weather predic- tion （NWP） system developed by the China Meteorological Administration. It is a fully compressible non-hydrostatical global/regional unified model that uses a traditional semi-Lagrangian advection scheme with cubic Lagrangian interpola tion （referred to as the SL_CL scheme）. The SL_CL scheme has been used in many operational NWP models, but there are still some deficiencies, such as the damping effects due to the interpolation and the relatively low accuracy. Based on Reich＇s semi-Lagrangian advection scheme （referred to as the R2007 scheme）, the Re_R2007 scheme that uses the low- and high-order B-spline function for interpolation at the departure point, is developed in this paper. One- and two-dimensional idealized tests in the rectangular coordinate system with uniform grid cells were conducted to compare the Re..R2007 scheme and the SL_CL scheme. The numerical results showed that： （1） the damping effects were remarkably reduced with the Re_R2007 scheme; and （2） the normalized errors of the Re_R2007 scheme were about 7.5 and 3 times smaller than those of the SL_CL scheme in one- and two-dimensional tests, respectively, indicating the higher accuracy of the Re..R2007 scheme. Furthermore, two solid-body rotation tests were conducted in the latitude-longitude spherical coordinate system with non uniform grid cells, which also verified the Re_R2007 scheme＇s advantages. Finally, in comparison with other global advection schemes, the Re_R2007 scheme was competitive in terms of accuracy and flow independence. An encouraging possibility for the application of the Re_R2007 scheme to the GRAPES model is provided.     

Peat porewater chloride concentration profiles in the Everglades during wet/dry cycles from January 1996 to June 1998: field measurements and theoretical analysis

Water quality is a key aspect of the Everglades Restoration Project, the largest water reclamation and ecosystem management project proposed in the United States. Movement of nutrients and contaminants to and from Everglades peat porewater could have important consequences for Everglades water quality and ecosystem restoration activities. In a study of Everglades porewater, we observed complex, seasonally variable peat porewater chloride concentration profiles at several locations. Analyses and interpretation of these changing peat porewater chloride concentration profiles identifies processes controlling conservative solute movement at the peat–surface water interface, that is, solutes whose transport is minimally affected by chemical and biological reactions. We examine, with an advection–diffusion model, how alternating wet and dry climatic conditions in the Florida Everglades mediate movement of chloride between peat porewater and marsh surface water. Changing surface water–chloride concentrations alter gradients at the interface between peat and overlying water and hence alter chloride flux across that interface. Surface water chloride concentrations at two frequently monitored sites vary with marsh water depth, and a transfer function was developed to describe daily marsh surface water chloride concentration as a function of marsh water depth. Model results demonstrate that porewater chloride concentrations are driven by changing surface water chloride concentrations, and a sensitivity analysis suggests that inclusion of advective transport in the model improves the agreement between the calculated and the observed chloride concentration profiles. Published in 2007 by John Wiley & Sons, Ltd.