Hydrochemical characterization of groundwater in Balad district,Salah Al-Din Governorate,Iraq

The assessment of hydrochemical quality of groundwater is very important to explore its nature and usefulness. In this paper, groundwater quality evaluation is carried out in the Balad district, Salah Al-Din Governorate, Iraq. A total of 28 groundwater samples are collected from shallow tube wells and analyzed for various physicochemical parameters. Groundwater suitability for drinking is evaluated based on the World Health Organization (WHO) and Iraqi standards, and suitability of groundwater for irrigation is assessed based on various hydrochemical parameters. The results reveal that the dominant types of groundwater based on piper diagram are mixed CaMgCl and CaCl. Gibbs ratio indicates that the groundwater in the studied area is affected by the evaporation process. The cation-anion exchange reaction in the studied area demonstrates that 54% of the groundwater samples indicate a direct base (cation-anion) exchange reaction, while 46% of the groundwater samples indicating the chloro-alkaline disequilibrium. Furthermore, generally all of the groundwater samples are unsuitable for drinking and irrigation. Cluster analysis reveals two different groups of similarities between the groundwater samples, reflecting different pollution levels in the studied area.     

Evaluation of groundwater quality and pollution in Daqing Oilfield

Daqing Oilfield is located in the northeast of Songnen Plain in Daqing City, Heilongjiang Province, which is a petrochemical industry gathering place based on petroleum refining, chemical industry, chemical fiber and fertilizer. In recent years, the quantity demand of petroleum and petrochemical production for groundwater in Daqing Oilfield is growing, and it’s of great significance to analyze and study the quality and pollution degree of groundwater for groundwater exploitation, utilization and protection. In this paper, groundwater quality of Daqing Oilfield evaluated by Nemerow Index is poor, and most points are Class IV groundwater; When evaluating groundwater pollution by hierarchical ladder method, the results show that the severe and extremely severe pollution points account for 34.48% in shallow phreatic water and 20% in deep confined water, showing that shallow groundwater is more seriously polluted than the deep. The main components influencing the quality of groundwater in the study area are total hardness, total dissolved solids, Cl-, SO42- and so on, which are affected by both the native environment and human activities; The main pollution components in groundwater are nitrite and nitrate nitrogen which are affected by human activities. Daqing Oilfield groundwater pollution is characterized by inorganic pollution, while organic components related to human activities contribute less to the groundwater pollution currently.     

微波消解-电感耦合等离子体质谱法测定海泡石中的稀土元素

海泡石是一种纤维状含水的富镁硅酸盐黏土矿,其中的稀土元素含量在1×10~(-7)～1×10~(-5)之间,目前还没有建立海泡石中稀土元素的国家标准分析方法。测定岩石中的稀土元素主要是采用电感耦合等离子体质谱法(ICP-MS),样品前处理一般采用封闭溶矿和碱熔,但这两种处理方法耗时较长,效率不高。本文通过比较硝酸-氢氟酸-过氧化氢、硝酸-氢氟酸、硝酸-过氧化氢三种样品前处理方法,确定使用硝酸-氢氟酸溶矿,然后进行微波消解同时赶去氢氟酸,避免氢氟酸与稀土元素生成难溶的氟化物,再采用ICP-MS法测定15种稀土元素的含量。由于海泡石中的镁含量较高,为降低基体效应,以~(103)Rh和~(185)Re作内标补偿基体效应和校正灵敏度漂移,各元素测定值的准确性显著提高,回收率为91. 2%～110. 9%,检出限为0. 002～0. 011μg/L,精密度≤2. 79%。本方法与封闭酸溶ICP-MS法的分析结果吻合较好,且用酸量少(7 mL),溶矿效率高(1 h),检出限更低。     

基于主成分分析的青藏高原多年冻土区高寒草地土壤质量评价

土壤质量评价是提高对土壤质量理解的关键环节。为了了解青藏高原多年冻土区高寒草地土壤质量的基本情况,在青藏高原腹地西大滩至安多地区,根据不同海拔梯度和植被盖度共采集了154个土壤样品。通过主成分分析（PCA）法确定了影响青藏高原多年冻土区高寒草地土壤质量的最小数据集（MDS）：全氮、全磷、全钾。根据影响土壤质量的最小数据集对青藏高原多年冻土区高寒草地土壤质量进行评价,得出了不同海拔、不同植被盖度下的土壤质量指数（SQI）。通过对不同海拔、不同植被盖度的土壤质量指数进行对比研究表明：随着海拔的升高,SQI呈增加的趋势,即海拔4 300～4 600 m（0.270±0.043） < 海拔4 600～4 900 m（0.326±0.061） < 海拔4 900～5 200 m（0.410±0.075）;随着植被盖度的增加,SQI也呈现增加的变化趋势,即植被盖度小于50%（0.262～0.265） < 植被盖度大于50%（0.336～0.344）。在分别考虑了有机质、盐分、土壤水分对土壤质量的影响下得出的土壤质量指数值与基于最小数据集得到的土壤质量指数相一致,说明基于主成分分析的最小数据集可以对青藏高原多年冻土区高寒草地土壤质量做出较准确的评价。     

江苏灌河入海口附近重金属元素环境地球化学质量分析

以往对灌河口附近海域进行地球化学调查发现,海底沉积物及海水质量总体良好,但局部沉积物中Cr含量高于一类标准,Cu、As、Pb、Hg等其他重金属元素含量也明显高于其他地区,个别重金属元素已接近一类标准最高限,存在潜在生态风险。为进一步了解其与人类活动是否有关,对灌河靠近入海口40 km长的河水进行了地球化学调查,发现灌河河水中Hg、Cu、Pb等重金属元素存在一定程度的超标现象。结合其他证据认为,人类活动不仅对灌河下游河水质量产生了负面影响,还对入海口附近的海域环境质量产生了潜在威胁。借鉴内梅罗综合指数评价思路对灌河下游及入海口的重金属元素环境质量进行评价,并对如何降低、消除生态风险提出了若干建议。     

基于支持向量机的喀斯特山区土壤环境质量评价——以贵州北部一茶叶园区为例

以贵州北部一茶叶园区80个表层土壤样品为研究对象,对其Hg、As、Cd、Pb、Cr和Cu含量进行测定,在MATLAB中应用支持向量机构建土壤环境质量评价模型,并与模糊综合评价法和内梅罗综合污染指数法的评价结果对比分析,探究支持向量机模型在喀斯特山区土壤环境质量评价中的适用性,其结果表明:研究区土壤质量Ⅰ类与Ⅱ类样品比例为33∶7,土壤环境质量大多数为I类;支持向量机方法的评价结果与模糊综合评价法和内梅罗综合污染指数法结果的相同率分别达到82.5%和80.0%,并分析结果有差异的样品,发现支持向量机评价结果更符合实际情况,这说明该模型适用于土壤环境质量的评价。      

山东省优质地下水资源评价研究

地下水是水资源的重要组成部分,山东省作为我国的北方大省,近年来随着人口的增长和经济发展,地下水环境问题日渐突出,表现为水质型缺水和水源型缺水两方面。本文以山东省地下水为研究对象,对全省富水地段及已建水源地逐一进行水质评价及开采潜力评价研究,结果显示:山东省优质水占49.53%,主要分布在鲁中南山区和鲁东低山丘陵区,新圈定的优质地下水富水地段及有开采潜力水源地共计88处,优质地下水允许开采量184.095×10~4m^3/d,可满足一千余万居民生活用水需求。应急情况下富水地段(水源地)允许开采量为434.299×10~4m^3/d,应急开采潜力为279.295×10~4m^3/d,可解决两千余万人生活用水困难。     

A location-aware GIServices quality prediction model via collaborative filtering

The quality of GIServices (QoGIS) is an important consideration for services sharing and interoperation. However, QoGIS is a complex concept and difficult to be evaluated reasonably. Most of the current studies have focused on static and non-scalable evaluation methods but have ignored location sensitivity subsequently resulting in the inaccurate QoGIS values. For intensive geodata and computation, GIServices are more sensitive to the location factor than general services. This paper proposes a location-aware GIServices quality prediction model via collaborative filtering (LAGCF). The model uses a mixed CF method based on time zone feature from the perspectives of both user and GIServices. Time zone is taken as the location factor and mapped into the prediction process. A time zone-adjusted Pearson correlation coefficient algorithm was designed to measure the similarity between the GIServices and the target, helping to identify highly similar GIServices. By adopting a coefficient of confidence in the final generation phase, the value of the QoGIS most similar to the target services will play a dominant role in the comprehensive result. Two series of experiments on large-scale QoGIS data were implemented to verify the effectivity of LAGCF. The results showed that LAGCF can improve the accuracy of QoGIS prediction significantly.     

2010—2020年黄河下游河南典型灌区浅层地下水中砷和氟的演化特征及变化机制

黄河下游典型灌区河南段是豫北平原重要的农业种植区。该地区浅层水质整体较差,因常用于作物灌溉或家畜饮用,会对人体健康产生风险,因此对该地区地下水中砷与氟浓度变化特征和机制的研究将有助于提高对该地区地下水污染的认识水平。本文基于2010年和2020年在灌区范围内采集的327组浅层地下水样品,研究区内地下水砷和氟分布情况,并在此基础上对比研究十年间灌区浅层地下水中砷、氟的演化特征,探索分析砷与氟浓度及空间变化机制。研究结果表明：该地区浅层地下水中存在砷与氟超标问题,2020年浅层地下水中高砷（砷浓度大于10μg/L）和高氟（氟浓度大于1mg/L）的样品数量分别占总数的26.1%和26.06%。高砷水分布在太行山前洼地与黄河冲积平原等泥沙互层结构的沉积环境中,还原性较强,同时地下水径流不畅,较强的阳离子交换作用使得其所处环境中Ca²⁺浓度较高。近十年间砷浓度增加的水样占总数31.8%,砷浓度减少的水样占36.7%。砷浓度的增长（减少）是地下水还原性增强（减弱）使得锰氧化物溶解释放（吸附）导致。近十年间不同地区农业灌溉和水源置换等用水方式导致水位变化是引起砷浓度变化的潜在因素。高氟水主要分布在河南新乡与濮阳的黄河沿线,氟离子浓度受到沉积物中萤石等钙质矿物溶解影响,使得高氟地下水出现在低钙环境中。近十年间研究区中氟离子浓度减少的占总数60.2%,氟离子浓度增加的占32.1%,整体变化趋势向好,但是高氟区中氟离子浓度继续增加。氟浓度的变化同样受到Ca²⁺变化影响,在Ca²⁺浓度降低（升高）时氟浓度进一步升高（降低）。地下水中氟升高地区分布在黄河沿线,因此受到黄河水补给影响较大,地下水径流条件较好,阳离子交换作用减弱,使得Ca²⁺浓度降低,此时地下水中砷浓度受到环境影响而降低,因此研究区氟增加地区中砷与氟的分布和演化呈现反向关系。     

Dissolution characteristics of deep?buried dolostone in the Member 5 of Ordovician Majiagou Formation in southern Ordos Basin

The different types of deep-buried dissolution process in the Member 5 of Ordovician Majiagou Formation in the southern Ordos Basin and its influence on the reservoir properties are studied in this paper. It shows that three types of mechanisms include organic acid fluid, hydrothermal fluid and TSR are identified through studies of core observation, thin section analysis, inclusion temperature, trace elements and rare earth elements. It is found that the dissolution of organic acid fluid causes the stratified dissolution pores, film-like asphaltene and ring-like asphaltene, while hydrothermal fluid causes the non-selective dissolution pores without petrofabric, veins of pyrites, massive pyrites and the association of hypothermal minerals. Four occurrence models of dissolution include, (1) the deep-buried dissolution of low-temperature hydrothermal fluid occurs in Zhiluo Period of Middle Jurassic; (2) the deep-buried dissolution of organic acid fluid started from the late Middle Jurassic followed by the first hydrocarbon injection; (3) the deep-buried dissolution of middle-high temperature hydrothermal fluid occurred in the Dongsheng Period of Early Cretaceous; (4) TSR occurred at the end of Early Cretaceous with the second larger hydrocarbon injection. Both organic acid fluid and hydrothermal fluid can improve the porosity and permeability of reservoir, but the hydrothermal fluid is more effective than that of organic acid fluid.