Soil respiration in tropical seasonal rain forest in Xishuangbanna, SW China

With the static opaque chamber and gas chromatography technique, from January 2003 to January 2004 soil respiration was investigated in a tropical seasonal rain forest in Xishuangbanna, SW China. In this study three treatments were applied, each with three replicates: A (bare soil), B (soil+litter), and C (soil+litter+seedling). The results showed that soil respiration varied seasonally, low from December 2003 to February 2004, and high from June to July 2004. The annual average values of CO2 efflux from soil respiration differed among the treatments at 1% level, with the rank of C (14642 mgCO2· m-2. h-1)＞B (12807 mgCO2· m-2. h-1)＞A (9532 mgCO2· m-2. h-1). Diurnal variation in soil respiration was not apparent due to little diurnal temperate change in Xishuangbanna. There was a parabola relationship between soil respiration and soil moisture at 1% level. Soil respiration rates were higher when soil moisture ranged from 35% to 45%. There was an exponential relationship between soil respiration and soil temperature (at a depth of 5cm in mineral soil) at 1% level. The calculated Q1o values in this study,ranging from 2.03 to 2.36, were very near to those of tropical soil reported. The CO2 efflux in 2003was 5.34 kgCO2· m-2. a-1 from soil plus litter plus seedling, of them 3.48 kgCO2· m-2. a-1 from soil (accounting for 62.5%), 1.19 kgCO2· m-2. a-1 from litter (22.3%) and 0.67 kgCO2·m-2. a-1 from seedling (12.5%).     

对羟基苯甲酸异丙酯合成的研究

以浓硫酸为催化剂，研究了对羟基苯甲酸和异丙醇合成对羟基苯甲酸异丙酯的工艺条件。对影响产率的因素进行了探讨：实验表明，在以7％的浓硫酸为催化剂，反应温度为120℃，醇酸摩尔比为4：1，反应时间为5h的最佳条件下，合成了羟基苯甲酸异丙脂，通过多次重结晶的方法纯化产品，产率可达85．5％，并通过熔点仪、红外光谱等手段对产品加以表征，验证了产品具有较高的纯度。该法简单、快速、产率高、纯度好，具有较高的实用价值。     

Nine thousand years of upper montane soil/vegetation dynamics from the summit of Caratuva Peak,Southern Brazil

Biodiversity loss, climate change, and increased freshwater consumption are some of the main environmental problems on Earth. Mountain ecosystems can reduce these threats by providing several positive influences, such as the maintenance of biodiversity, water regulation, and carbon storage, amongst others. The knowledge of the history of these environments and their response to climate change is very important for management, conservation, and environmental monitoring programs. The genesis of the soil organic matter of the current upper montane vegetation remains unclear and seems to be quite variable depending on location. Some upper montane sites in the very extensive coastal Sea Mountain Range present considerable organic matter from the late Pleistocene and other from only the Holocene. Our study was carried out on three soil profiles (two cores in grassland and one in forest) on the Caratuva Peak of the Serra do Ibitiraquire (a sub-range of Sea Mountain Range – Serra do Mar) in Southern Brazil. The δ¹³C isotopic analyses of organic matter in soil horizons were conducted to detect whether C₃ or C₄ plants dominated the past communities. Complementarily, we performed a pollen analysis and ¹⁴C dating of the humin fraction to obtain the age of the studied horizons. Except for a short and probably drier period (between 6000 and 4500 cal yr BP), C₃ plants, including ombrophilous grasses and trees, have dominated the highlands of the Caratuva Peak (Pico Caratuva), as well as the other uppermost summits of the Serra do Ibitiraquire, since around 9000 cal yr BP. The Caratuva region represents a landscape of high altitude grasslands (campos de altitude altomontanos or campos altomontanos) and upper montane rain/cloud forests with soils that most likely contain some organic matter from the late Pleistocene, as has been reported in Southern and Southeastern Brazil for other sites. However, our results indicate that the studied deposits (near the summit) are from the early to late Holocene, when somewhat wetter and warmer conditions (since around 9000 cal yr BP) enabled a stronger colonization of the ridge of Pico Caratuva by mainly C₃ plants, especially grassland species. However, at the same time, even near the summit, the soil core from the forest site already presented the current physiognomy (or a shrubby/elfin or successional forest), indicating that the colonization of the neighboring uppermost saddles and valleys were probably populated mainly by upper montane forest species.     

Diagnosing snow accumulation errors in a rain‐snow transitional environment with snow board observations

Diagnosing the source of errors in snow models requires intensive observations, a flexible model framework to test competing hypotheses, and a methodology to systematically test the dominant snow processes. We present a novel process‐based approach to diagnose model errors through an example that focuses on snow accumulation processes (precipitation partitioning, new snow density, and snow compaction). Twelve years of meteorological and snow board measurements were used to identify the main source of model error on each snow accumulation day. Results show that modeled values of new snow density were outside observational uncertainties in 52% of days available for evaluation, while precipitation partitioning and compaction were in error 45% and 16% of the time, respectively. Precipitation partitioning errors mattered more for total winter accumulation during the anomalously warm winter of 2014–2015, when a higher fraction of precipitation fell within the temperature range where partition methods had the largest error. These results demonstrate how isolating individual model processes can identify the primary source(s) of model error, which helps prioritize future research.     

Why asymptotic limit of the acid dissolution capacity can lead to a sharp dissolution front in chemical dissolution of porous rocks?

The use of the asymptotic limit can greatly simplify the theoretical analysis of chemical dissolution front instabilities in fluid‐saturated rocks and therefore make it possible to obtain mathematical solutions, which often play a crucial role in understanding the propagation behavior of chemical dissolution fronts in chemical dissolution systems. However, there has been a debate in recent years that the asymptotic limit of the acid dissolution capacity (i.e., the acid dissolution capacity number approaching zero) alone cannot lead to a sharp dissolution front of the Stefan type in the acidization dissolution system, in which the dissolvable minerals of carbonate rocks are chemically dissolved by the injected acid flow. The acid dissolution capacity number is commonly defined as the ratio of the volume of the carbonate rock dissolved by an acid to that of the acid. In this paper, we use four different proof methods, including (i) direct use of the fundamental concepts; (ii) use of the mathematical governing equations of an acidization dissolution system; (iii) use of the different time scaling approach; and (iv) use of a moving coordinate system approach, to demonstrate that the asymptotic limit of the acid dissolution capacity can indeed lead to sharp dissolution fronts of the Stefan type in acidization dissolution systems on a much larger time scale (than the dissolution time scale). Our new finding is that on the reaction time scale, the condition of the conventional time derivative of porosity approaching zero alone can ensure that the acidization dissolution front has a sharp shape of the Stefan type. Copyright © 2017 John Wiley & Sons, Ltd.     

Rain on snow induced urban floods in cold maritime climate: Risk,indicators and trends

Urban floods pose a societal and economical risk. This study evaluated the risk and hydro-meteorological conditions that cause pluvial flooding in coastal cities in a cold climate. Twenty years of insurance claims data and up to 97 years of meteorological data were analysed for Reykjavík, Iceland (64.15°N; <100 m above sea level). One third of the city's wastewater collection system is combined, and pipe grades vary from 0.5% to 10%. Results highlight semi-intensive rain (<7 mm/h; ≤3 year return period) in conjunction with snow and frozen ground as the main cause for urban flood risk in a climate which undergoes frequent snow and frost cycles (avg. 13 and 19 per season, respectively). Floods in winter were more common, more severe and affected a greater number of neighbourhoods than during summer. High runoff volumes together with debris remobilized with high winds challenged the capacity of wastewater systems regardless of their age or type (combined vs. separate). The two key determinants for the number of insurance claims were antecedent frost depth and total precipitation volume per event. Two pluvial regimes were particularly problematic: long duration (13–25 h), late peaking rain on snow (RoS), where snowmelt enhanced the runoff intensity, elongated and connected independent rainfall into a singular, more voluminous (20–76 mm) event; shorter duration (7–9 h), more intensive precipitation that evolved from snow to rain. Closely timed RoS and cooling were believed to trigger frost formation. A positive trend was detected in the average seasonal snow depth and volume of rain and snowmelt during RoS events. More emphasis, therefore, needs to be placed on designing and operating urban drainage infrastructure with regard to RoS co-acting with frozen ground. Furthermore, more detailed, routine monitoring of snow and soil conditions is important to predict RoS flood events.     

Development of a rain‐on‐snow detection algorithm using passive microwave radiometry

Currently observed climate warming in the Arctic has numerous consequences. Of particular relevance, the precipitation regime is modified where mixed and liquid precipitation can occur during the winter season leading to rain‐on‐snow (ROS) events. This phenomenon is responsible for ice crust formation, which has a significant impact on ecosystems (such as biological, hydrological, ecological and physical processes). The spatially and temporally sporadic nature of ROS events makes the phenomenon difficult to monitor using meteorological observations. This paper focuses on the detection of ROS events using passive microwave (PMW) data from a modified brightness temperature (T_B) gradient approach at 19 and 37 GHz. The approach presented here was developed empirically for observed ROS events with coincident ground‐based PMW measurements in Sherbrooke, Quebec, Canada. It was then tested in Nunavik, Quebec, with the Advanced Microwave Scanning Radiometer for the Earth Observing System (AMSR‐E). We obtained a detection accuracy of 57, 71 and 89% for ROS detection for three AMSR‐E grid cells with a maximum error of 7% when considering all omissions and commissions with regard to the total number of AMSR‐E passes throughout the winter period. Copyright © 2016 John Wiley & Sons, Ltd.     

东北地区春季首场透雨的变化特征及与青藏高原地面加热场强度的关系

利用1958—2012年4—5月东北地区(39°~55°N、118°~135°E)101个站点逐日降水资料、青藏高原地区(25°~40°N、73.75°~103.75°E)JRA-55的地面感热和潜热通量月平均再分析资料以及NCEP/NCAR-I大气环流场的月平均再分析资料,分析了春播期首场透雨出现日期的时空变化特征及其与透雨量和播种期降水量间的关系,以及对青藏高原地面加热场强度异常的响应及其可能机制。结果表明:透雨日期自1958年以来在东北地区的西北和东南大部分区域呈现略微偏晚的趋势;中部有略微偏早的趋势。春播期首场透雨出现时间偏早(晚)的地方,首场透雨量小(大),春播期总降水量多(少)。同时,4月青藏高原地面加热场强度增强(减弱),有利于(不利于)来自北方的冷空气和南方的暖湿气流在东北上空交汇,且上升气流增强(减弱),水汽输送充沛(减少),导致该地区春季首场透雨出现的时间偏早(晚)。     

Logistic判别模型在强降水预报中的应用

利用Logistiv判别模型进行强降水预报,并设计3种方案进行对比分析。方案1直接使用14个影响因子进行判别预报,受因子共线性作用及噪音信号影响,虽然拟合效果较好,但预报效果明显下降。方案2对14个影响因子进行主成分分析,利用前6个主成分建模,虽然拟合效果较方案1降低,但由于消除了因子共线性作用以及噪音信号影响,预报效果较方案1提高。方案3运用Bootstrap抽样技术得到符干样本并建模计算模型参数,打乱了原有时间序列中的波动,仪保留平稳信息,拟合自由度进一步降低,导致拟合效果较方案案2下降,但预报效果却是3种方案中最好且最稳定的。在上述研究基础上,利用欧洲中心数值预报模式的预报场资料,建立基于Logistic判别模型的强降水客观预报系统,并在中央气象台业务运行。2013和2014年连续两年汛期预报检验结果表明,概模型对强降水预报的TS评分高于数值模式本身,具有一定的业务参考价值。     

中国东部7类暴雨异常环流型

近年来的研究发现,瞬变扰动天气图上的扰动场天气系统对区域暴雨的落区指示能力强于传统天气图上的总场天气系统。为供预报员在业务预报中参考,本文划分1998年发生在中国东部地区的41日次区域暴雨为7类扰动场天气系统。与区域暴雨相联系的7类异常环流型分别是:华南切变线、华南涡旋、华南倒槽、长江切变线与槽、沿江涡旋、华北涡旋和东北涡旋。无论是在对流层的垂直剖面上,还是在850 hPa水平分布上,扰动天气图上位势高度低值和风扰动辐合处并配合大的水汽扰动对应有区域暴雨,而传统天气图上的低值系统和高水汽区与暴雨之间存在位置上的偏移。由此建议,用实况大气变量和中期数值模式产品绘制扰动天气图有助于预报员确定区域暴雨落区。