会泽铅锌矿床的成矿流体来源:来自水-岩反应的证据

系统地研究了脉石矿物方解石中流体包裹体特征及矿床的水-岩反应条件.研究结果表明,该矿床的形成与中低温热液与中高温热液的混合有关;成矿流体的H、O同位素组成在不同矿体中没有明显的差别,流体形成前曾存在流体的均一化作用;成矿流体的形成是地层循环水与变质水、岩浆水在流体储库中充分混合的结果.因此,成矿流体具有多源性.     

汶川8．0级地震前兆异常对比研究

The contrast research results show that the number of items and stations with imminent, short and medium term precursor anomalies for the Wenchuan M_S 8. 0 earthquake is less than that of the Menglian earthquake. The number of anomalies and stations associated with the Wenchuan earthquake increased in the early stage of the short-term range,as opposed to the later period for the Menglian and Lijiang earthquakes. Most of the medium term anomalies occurred two to three years before the Wenchuan earthquake,when the number of anomaly stations and items was eleven,and a great change appeared in the observation values in about half of the stations ( items ) . However,for the Menglian earthquake,medium term anomalies happened one to two years before the earthquake, the number of abnormal stations and items reached 20,and a sharp change appeared in the observation values six months to one year before the earthquake in about 30 percent of the stations or items. In the epicenter and the nearby area,the macroscopic abnormalities started 3 years before the Wenchuan earthquake and lasted intermittently until 1 month before the earthquake. Within 2 percent of the total area of the province,the macroscopic abnormalities accounted for 30 to 50 percent of the total number of anomalies of the Province. For the Xingtai,Tangshan,Haicheng,Songpan earthquakes,the macroscopic anomalies started two to three months before,or on the very day of the earthquakes. The common feature of the precursors between the Wenchuan and other strong earthquakes is the appearance of tremendous changes in a certain number of observation values of anomalies in the mid and short terms before all these earthquakes.     

利用地震复发周期考察汶川8．0级地震前兆异常

通过对汶川Ms8．0地震复发周期的时间和空间进行扫描,发现地震发生前,在时间上和空间上,地震复发周期均出现低值异常。因此,对地震发生的时间和地区进行异常判断,地震复发周期是一个可以参考利用的指标。     

Last interglacial-glacial cycle and an attempt to reconstruct Würmian paleohumidity of the European Alps

A lot of paleoenvironmental surveys have been carried out in the Alpine region to elucidate glacier extension during the Last Glacial or the Würmian (115 - 12 ka BP). However, the evidence of past glaciations differs greatly between Western and Eastern Alps, while contrast between Southern and Northern Alps is not evident. The main purpose of this paper is to interpret variability of humidity during the last interglacial-glacial cycle in the Alpine region, based on results of various surveys performed in the Alpine region. Results show that distribution of moisture throughout the Alps was most even during the Late Würmian, while precipitation was mainly concentrated in the (North)Western Alps during the Early Würmian and in the (North)Western and along all the Southern Alps during the Middle Würmian. The Eastern Alps were rather dry during both episodes. Such moisture distribution can be explained by paths of prevailing winds. Moisture distribution is directly linked with atmospheric and oceanic circulation.     

岩溶洞穴次生碳酸盐沉积铀及其同位素组成古气候环境研究进展

洞穴沉积铀含量及其同位素初始234U/238U[（234U/238U)0]变化均与过去气候环境变化关系密切。文章分别对石笋中U含量和(234U/238U)0的气候意义进行统计分析发现,多数研究认为洞穴沉积U含量和(234U/238U)0可能指示土壤湿度和有效降水变化。然而,不管是对洞穴沉积的U含量还是(234U/238U)0,其气候环境意义解读还存在两种观点。但无论如何,这些研究成果都显示了洞穴沉积的U含量和(234U/238U)0是研究过去气候环境变化的重要替代指标。在未来的研究中,除了土壤环境和过程,还应关注U来源的相对贡献变化和其他微量元素与U元素的关系。这一指标可能在对东亚地区的大气粉尘活动和冬季风演化、地表生物量的变化研究等方面发挥重要作用。      

Dating the giant Zhuxi W–Cu deposit (Taqian–Fuchun Ore Belt) in South China using molybdenite Re–Os and muscovite Ar–Ar system

The recently discovered Zhuxi W–Cu ore deposit is located within the Taqian–Fuchun Ore Belt in the southeastern edge of the Yangtze Block, South China. Its inferred tungsten resources, based on new exploration data, are more than 280 Mt by 2016. At least three paragenetic stages of skarn formation and ore deposition have been recognized: prograde skarn stage; retrograde stage; and hydrothermal sulfide stage. Secondly, greisenization, marmorization and hornfels formation are also observed. Scheelite and chalcopyrite are the dominant metal minerals in the Zhuxi deposit and their formation was associated with the emplacement of granite stocks and porphyry dykes intruded into the surrounding Carboniferous carbonate sediments (Huanglong and Chuanshan formations) and the Neoproterozoic slate and phyllites. The scheelite was mostly precipitated during the retrograde stage, whereas the chalcopyrite was widely precipitated during the hydrothermal sulfide stage. A muscovite ⁴⁰Ar/³⁹Ar plateau age of about 150 Ma is interpreted as the time of tungsten mineralization and molybdenite Re–Os model ages ranging from 145.9 ± 2.0 Ma to 148.7 ± 2.2 Ma (for the subsequent hydrothermal sulfide stage of activity) as the time of the copper mineralization. Our new molybdenite Re–Os and muscovite ⁴⁰Ar/³⁹Ar dating results, along with previous zircon U–Pb age data, indicate that the hydrothermal activity from the retrograde stage to the last hydrothermal sulfide stage lasted up to 5 Myr, from 150.6 ± 1.5 to 145.9 ± 1 Ma, and is approximately coeval or slightly later than the emplacement of the associated granite porphyry and biotite granite. The new ages reported here confirm that the Zhuxi tungsten deposit represents one of the Mesozoic magmatic–hydrothermal mineralization events that took place in South China in a setting of lithospheric extension during the Late Jurassic (160–150 Ma). It is suggested that mantle material played a role in producing the Zhuxi W–Cu mineralization and associated magmatism.     

Combined zircon and cassiterite U–Pb dating of the Piaotang granite-related tungsten–tin deposit,southern Jiangxi tungsten district,China

The large low-grade Piaotang W–Sn deposit in the southern Jiangxi tungsten district of the eastern Nanling Range, South China, is related to a hidden granite pluton of Jurassic age. The magmatic-hydrothermal system displays a zonation from an inner greisen zone to quartz veins and to peripheral veinlets/stringers (Five-floor zonation model). Most mineralization is in quartz veins with wolframite > cassiterite. The hidden granite pluton in underground exposures comprises three intrusive units, i.e. biotite granite, two-mica granite and muscovite granite. The latter unit is spatially associated with the W–Sn deposit.Combined LA-MC-ICP-MS U–Pb dating of igneous zircon and LA-ICP-MS U–Pb dating of hydrothermal cassiterite are used to constrain the timing of granitic magmatism and hydrothermal mineralization. Zircon from the three granite units has a weighted average ²⁰⁶Pb/²³⁸U age of 159.8 ± 0.3 Ma (2 σ, MSWD = 0.3). The cathodoluminescence (CL) textures indicate that some of the cassiterite crystals from the wolframite-cassiterite quartz vein system have growth zonations, i.e. zone I in the core and zone II in the rim. Dating on cassiterite (zone II) yields a weighted average ²⁰⁶Pb/²³⁸U age of 159.5 ± 1.5 Ma (2 σ, MSWD = 0.4), i.e. the magmatic and hydrothermal systems are synchronous. This confirms the classical model of granite-related tin–tungsten mineralization, and is against the view of a broader time gap of >6 Myr between granite magmatism and W–Sn mineralization which has been previously proposed for the southern Jiangxi tungsten district. The elevated trace element concentrations of Zr, U, Nb, Ta, W and Ti suggest that cassiterite (zone II) formed in a high-temperature quartz vein system related to the Piaotang granite pluton.     

Insights into the extreme PGE enrichment of the W Horizon,Marathon Cu-Pd deposit,Coldwell Alkaline Complex,Canada: Platinum-group mineralogy,compositions and genetic implications

The W Horizon, Marathon Cu-Pd deposit in the Mesoproterozoic Midcontinent rift is one of the highest grade PGE repositories in magmatic ore deposits world-wide. The textural relationships and compositions of diverse platinum-group mineral (PGM) and sulfide assemblages in the extremely enriched ores (>100 ppm Pd-Pt-Au over 2 m) of the W Horizon have been investigated in mineral concentrates with ∼10,000 PGM grains and in situ using scanning electron microprobe and microprobe analyses.Here we show, from ore samples with concentrations up to 23.1 Pd ppm, 8.9 Pt ppm, 1.4 Au ppm and 0.73 Rh ppm, the diversity of minerals (n = 52) including several significant unknown minerals and three new mineral species marathonite (Pd₂₅Ge₉; McDonald et al., 2016), palladogermanide (Pd₂Ge; IMA 2016-086, McDonald et al., 2017), kravtsovite (PdAg₂S, IMA No 2016-092, Vymazalová et al., 2017). The PGM are distributed as PG-, sulfides (52 vol%), -arsenides (34 vol%), -intermetallics of Au-Ag-Pd-Cu and Pd-Ge(10 vol%) and -bismuthides and tellurides (4 vol%). The discovery of abundant (>330 grains) large unknown sulfide minerals with Rh allows us to present analyses three significant potentially new minerals (WUK-1, WUK-2, WUK-3) that are all clearly enriched in Rh (averaging 4.2, 8.5 and 28.21 wt% Rh respectively). Several examples of paragenetic sequences and mineral chemical changes for enrichment of Cu, Pd and Rh with time are revealed in the PGM and base-metal sulfides. We suggest this enhanced metal enrichment formed in response to increasing fO₂ causing the oxidation of Fe²⁺ to Fe³⁺ and to a lesser extent, S.Phase relations in the Ag-Pd-S, Rh-Ni-Fe-S, Pd-Ge, Au-Pd-Cu-Ag, Pd-Ag-Te systems help constrain the crystallization temperatures of the majority of ore minerals in the W Horizon at ∼500 °C or moderate to high subsolidus temperatures (400–600 °C). Local transport by aqueous fluids becomes evident as minerals recrystallize down to <300 °C. The PGE-enriched W Horizon ores exhibit a complex post-magmatic history dominated by the effects of oxidation during cooling of a Cu-PGE enriched magma source from a deep reservoir.     

新疆河流年径流量对夏季0C层高度变化的响应

According to climate features and river runoff conditions, Xinjiang could be divided into three research areas: The Altay-Tacheng region, the Tianshan Mountain region and the northern slope of the Kunlun Mountains. Utilizing daily observations from 12 sounding stations and the annual runoff dataset from 34 hydrographical stations in Xinjiang for the period 1960-2002, the variance of the summertime 0℃ level height and the changing trends of river runoff are analyzed both qualitatively and quantitatively, through trend contrast of curves processed by a 5-point smoothing procedure and linear correlation. The variance of the summertime 0℃ level height in Xinjiang correlates well with that of the annual river runoff,especially since the early 1990s, but it differs from region to region, with both the average height of the 0℃ level and runoff quantity significantly increasing over time in the Altay-Tacheng and Tianshan Mountain regions but decreasing on the northern slope of the Kunlun Mountains. The correlation holds for the whole of Xinjiang as well as the three individual regions, with a 0.01 significance level. This indicates that in recent years, climate change in Xinjiang has affected not only the surface layer but also the upper levels of the atmosphere, and this raising and lowering of the summertime 0℃ level has a direct impact on the warming and wetting process in Xinjiang and the amount of river runoff. Warming due to climate change increases the height of the 0℃ level, but also speeds up, ice-snow melting in mountain regions, which in turn increases river runoff, leading to a season of plentiful water instead of the more normal low flow period.