Assessing the Comparability of Ammonium,Nitrate and Sulfate Concentrations Measured by Three Air Quality Monitoring Networks

Airborne fine particulate matter across the United States is monitored by different networks, the three prevalent ones presently being the Clean Air Status and Trend Network (CASTNet), the Interagency Monitoring of PROtected Visual Environment Network (IMPROVE) and the Speciation and Trend Network (STN). If combined, these three networks provide speciated fine particulate data at several hundred locations throughout the United States. Yet, differences in sampling protocols and samples handling may not allow their joint use. With these concerns in mind, the objective of this study is to assess the spatial and temporal comparability of the sulfate, nitrate and ammonium concentrations reported by each of these networks. One of the major differences between networks is the sampling frequency they adopted. While CASTNet measures pollution levels on seven-day integrated samples, STN and IMPROVE data pertain to 24-hour samples collected every three days. STN and IMPROVE data therefore exhibit considerably more short-term variability than their CASTNet counterpart. We show that, despite their apparent incongruity, averaging the data with a window size of four to six weeks is sufficient to remove the effects of differences in sampling frequency and duration and allow meaningful comparison of the signals reported by the three networks of concern. After averaging, all the sulfate and, to a lesser degree, ammonium concentrations reported are fairly similar. Nitrate concentrations, on the other hand, are still divergent. We speculate that this divergence originates from the different types of filters used to collect particulate nitrate. Finally, using a rotated principal component technique (RPCA), we determined the number and the geographical organization of the significant temporal modes of variation (clusters) detected by each network for the three pollutants of interest. For sulfate and ammonium, the clusters’ geographical boundaries established for each network and the modes of variations within each cluster seem to correspond. RPCA erformed on nitrate concentrations revealed that, for the CASTNet and IMPROVE networks, the modes of variation do not correspond to unified geographical regions but are found more sporadically. For STN, the clustered areas are unified and easily delineable. We conclude that the possibility of jointly using the data collected by CASTNet, IMPROVE and STN has to be weighed pollutant by pollutant. While sulfate and ammonium data show some potential for joint use, at this point, combining the nitrate data from these monitoring networks may not be a judicious choice.     

岩土钻掘设备的液压步履机构

因液压步履移位最方便，辅助时间短，换向灵活，移位对孔准确，大型岩土钻掘设备施工的群孔现场实现近距离的自行迁移多采用液压步履机构。详细叙述了双向移动和单向移动加转向步履机构的结构和特点。     

空间运动对象与时空数据类型研究

当前时空数据模型多以描述空间实体的离散变化为主。该文中对空间运动对象在抽象层次的无限连续空间、离散层次的有限离散空间上的数据类型进行分析和定义，将其分别划分为时间类型、空间类型和时态类型来研究，并提出支持空间运动对象的表示方法和操作方式。该方法既能表示空间实体的连续运动，也能表示其离散变化，为空间运动对象时空数据模型的建立奠定了基础。     

Three‐dimensional shakedown solutions for anisotropic cohesive‐frictional materials under moving surface loads

Previous work on three‐dimensional shakedown analysis of cohesive‐frictional materials under moving surface loads has been entirely for isotropic materials. As a result, the effects of anisotropy, both elastic and plastic, of soil and pavement materials are ignored. This paper will, for the first time, develop three‐dimensional shakedown solutions to allow for the variation of elastic and plastic material properties with direction. Melan's lower‐bound shakedown theorem is used to derive shakedown solutions. In particular, a generalised, anisotropic Mohr–Coulomb yield criterion and cross‐anisotropic elastic stress fields are utilised to develop anisotropic shakedown solutions. It is found that shakedown solutions for anisotropic materials are dominated by Young's modulus ratio for the cases of subsurface failure and by shear modulus ratio for the cases of surface failure. Plastic anisotropy is mainly controlled by material cohesion ratio, the rise of which increases the shakedown limit until a maximum value is reached. The anisotropic shakedown limit varies with frictional coefficient, and the peak value may not occur for the case of normal loading only. Copyright © 2013 John Wiley & Sons, Ltd.     

Calibration of paired watersheds: Utility of moving sums in presence of externalities

Historically, paired watershed studies have been used to quantify the hydrological effects of land use and management practices by concurrently monitoring 2 similar watersheds during calibration (pretreatment) and post‐treatment periods. This study characterizes seasonal water table and flow response to rainfall during the calibration period and tests a change detection technique of moving sums of recursive residuals (MOSUM) to select calibration periods for each control–treatment watershed pair when the regression coefficients for daily water table elevation were most stable to minimize regression model uncertainty. The control and treatment watersheds were 1 watershed of 3–4‐year‐old intensely managed loblolly pine (Pinus taeda L.) with natural understory, 1 watershed of 3–4‐year‐old loblolly pine intercropped with switchgrass (Panicum virgatum), 1 watershed of 14–15‐year‐old thinned loblolly pine with natural understory (control), and 1 watershed of switchgrass only. The study period spanned from 2009 to 2012. Silvicultural operational practices during this period acted as external factors, potentially shifting hydrologic calibration relationships between control and treatment watersheds. MOSUM results indicated significant changes in regression parameters due to silvicultural operations and were used to identify stable relationships for water table elevation. None of the calibration relationships developed using this method were significantly different from the classical calibration relationship based on published historical data. We attribute that to the similarity of historical and 2010–2012 leaf area index on control and treatment watersheds as moderated by the emergent vegetation. Although the MOSUM approach does not eliminate the need for true calibration data or replace the classic paired watershed approach, our results show that it may be an effective alternative approach when true data are unavailable, as it minimizes the impacts of external disturbances other than the treatment of interest.     

Spontaneous Emission of Gravity Waves by Interacting Vortex Dipoles in a Stratified Fluid: Laboratory Experiments

Results from a new series of experiments on the geophysically important issue of spontaneous emission of internal gravity waves during unsteady interactions of vortical structures are presented. Vortex dipoles are a common element of a quasi-two-dimensional turbulent flow. Vortex dipoles perform translational motion and can collide with other vortices. During collision events the flow is unsteady and unbalanced and a further adjustment process associated with these events can therefore result in the spontaneous emission of gravity waves. Our laboratory experiments demonstrate that gravity waves are emitted when two translating vortex dipoles interact (collide) in a layered fluid, in accord with the current theoretical results. The emission was evident both in a two-layer system and in a fluid with a linear distribution of density with depth. The waves were generated during the period of deceleration of the secondary dipoles which constitute a vortex quadrupole emerging immediately after the collision of the primary dipoles.     

Experimental and theoretical study of a cylindrical oscillating water column device with a quadratic power take-off model

The wave power extraction by a cylindrical oscillating water column (OWC) device with a quadratic power take-off (PTO) model was studied experimentally and theoretically. In the experiment, a scaled model OWC was tested in a wave flume, with an orifice being used to simulate a quadratic PTO mechanism. In the theoretical analysis, the quadratic PTO model was linearized based on Lorenz's principle of equivalent work, which allows us to perform a frequency domain analysis using an eigen-function matching method. The effects of higher harmonic components and the spatial non-uniformity of the surface velocity inside the chamber were discussed. A semi-analytical model was proposed to understand the viscous loss affecting the measured capture length. Our treatment of the quadratic PTO model was validated by comparing quasi-linear theoretical capture length and the laboratory measurement. Our results also showed that the effects of spatial non-uniformity and viscous loss could be noticeable for shorter waves.     

Effects of linear and exponential heterogeneity on the dynamic response of a moving load in an irregular isotropic half-space: a comparative study

Heterogeneity, being a trivial feature inside the earth or in a geostructure, makes a strong basis for its consideration in the study of geomechanics. Inclusion of the concept of heterogeneity along with irregularity in the medium brings a novelty to the existing literature related to the study of the moving load. The present study investigates the effects of linear and exponential heterogeneity on the dynamic response due to a normal load moving with constant velocity on a rough irregular heterogeneous isotropic half-space in a comparative approach. Expressions for both normal and shear stresses for either case of heterogeneity have been established in closed form. Substantial effects of the affecting parameters such as depth, irregularity factor, maximum depth of irregularity, frictional coefficient, linear heterogeneity parameter and exponential heterogeneity parameter on normal and shear stresses for both the cases of heterogeneity have been observed. Numerical computation has been carried out and the effects of said parameters have been meticulously examined by means of graphs. Moreover, different cases of heterogeneity and homogeneity along with various types of irregularity namely rectangular, parabolic and no irregularity are compared which serve as a focal theme of the study.     

普朗斑岩型铜矿床成矿元素多重分形特征及其矿化强度指示

成矿元素品位的变化受控于长期地质作用过程,具有较强的非线性特征,定量刻画其变化特征有助于深入理解成矿过程,并为找矿预测提供理论依据。运用多重分形去趋势移动均值（MFDMA） 法,分析云南普朗斑岩型铜矿床4号勘探线钻孔Cu元素品位的多重分形特征及其对矿化强度的指示意义。结果显示：所有钻孔Cu元素品位具有多重分形特征,且不同矿化等级的元素分布存在局部奇异性差异,多重分形强度随矿化强度等级减弱而增加;这些特征指示在钾硅化带—带内侧强矿化钻孔的高品位相对聚集,而带外侧角岩化—青磐岩化带的高品位相对分散;通过数据随机重排技术推测Cu品位多重分形结构奇异性差异是由其分布概率密度和长相关性共同作用引起,后者的作用贡献大于前者。     

青藏高原云团东传过程及其中中尺度对流系统的统计特征

利用逐小时风云卫星TBB资料、逐小时中国自动站与CMORPH降水产品融合数据以及国家级地面观测站24小时累积降水量,统计分析2010～2016年夏季,伴随下游地区（104°E以东）降水的青藏高原云团东传过程以及东传过程中镶嵌于云团中的中尺度对流系统（Mesoscale Convective System,简称MCS）特征。结果表明,共出现120次伴随下游降水的高原云团东传过程,6月出现最频繁,但持续时间较长的过程多出现在7月。云团向东传播的主要三条路径是平直东传、沿长江折向东传和复合东传。其中路径二——沿长江折向东传中的过程是高影响过程,因为过程次数较多（46次）,过程平均持续时间较长（62小时）,在下游地区引发的降水日数和暴雨日数最多。属于东传过程的MCS在7月形成最多,集中分布在青藏高原东坡、云贵高原东部、长江沿岸及其以南地区。高原MCS影响长江中下游地区降水主要是通过向东传播的形式实现,因为即使生命史更长的中α尺度对流系统（Meso-α Convective System,简称MαCS）也鲜少直接移动至110°E以东地区。不同区域的中α尺度持续性拉长形对流系统（Permanent Elongated Convective System,简称PECS）的日变化特征显示,东传过程MCS更容易在夜间从高原东坡向东传播至下游地区。在三条路径中,路径二中的东传过程MCS数量最多、在下游地区发展最旺盛并与降水日数和覆盖范围存在更好的对应关系。