Origin and source regions of PM10 in the Eastern Mediterranean atmosphere

A set of daily PM₁₀ (n = 281) samples collected from April 2001 to April 2002 at a rural site (Erdemli), located on the coast of the Eastern Mediterranean, were analyzed applying Mass Closure (MC), absolute principal factor analysis (APFA) and Positive Matrix Factorization (PMF) to determine source contributions. The results from the three techniques were compared to identify the similarities and differences in the sources and source contributions. Source apportionment analysis indicated that PM₁₀ were mainly originated from natural sources (sea salt + crustal ≈ 60%) whilst secondary aerosols and residual oil burning accounted for approximately 20% and 10% of the total PM₁₀ mass, respectively. Calculations for sulfate showed that on average 8% and 12% of its total concentration were originated from sea salt and biogenic emissions, respectively. However, the contribution by biogenic emissions may reach up to a maximum of ~ 40% in the summer. Potential Source Contribution Function (PSCF) analysis for identification of source regions showed that the Saharan desert was the main source area for crustal components. For secondary aerosol components the analysis revealed one source region, (i.e. the south-Eastern Black Sea), whereas for residual oil, Western Europe and the western Balkans areas were found to be the main source regions.     

黄海海雾WRF数值模拟中垂直分辨率的敏感性研究

基于WRF模式探究不同垂直分辨率下模式对黄海海雾的模拟表现。将3种垂直分层方案（35η、44η与63η）和2种边界层方案（YSU、MYNN）组合,对10次海雾做模拟研究。统计分析了水平雾区与雾顶高度对垂直分辨率的敏感性,并利用1次典型个例剖析了雾顶长波辐射与雾体湍流的作用。统计结果显示,提高垂直分辨率能显著改进水平雾区的模拟效果,改善明显的个例在不同垂直分辨率试验下的雾顶高度差异也较大;YSU方案相比于MYNN方案更敏感,从35η层增至44η层其试验个例的击中率（POD）和公正预兆得分（ETS）的平均改进率分别提高了13.29%和10.22%。典型个例研究结果揭示,模式对雾顶长波辐射和雾体湍流作用的模拟程度强烈依赖垂直分辨率：粗垂直分辨率给出的湍流强度很弱,导致模拟失败;雾顶存在“云水含量增多→长波辐射增强→降温加大→云水含量增多”的正反馈过程,细垂直分辨率比粗垂直分辨率更容易维持与增强此反馈;只有细垂直分辨率才能模拟出雾顶长波辐射冷却产生的贯穿雾体直抵海面、强度不弱于近海面机械湍流的浮力湍流,它导致雾体降温而出现符合观测事实的海温高于气温的现象。     

An Improved Mellor–Yamada Level-3 Model: Its Numerical Stability and Application to a Regional Prediction of Advection Fog

This note describes a numerically stable version of the improved Mellor–Yamada (M–Y) Level-3 model proposed by Nakanishi and Niino [Nakanishi, M. and Niino, H.: 2004, Boundary-Layer Meteorol. 112, 1–31] and demonstrates its application to a regional prediction of advection fog. In order to ensure the realizability for the improved M–Y Level-3 model and its numerical stability, restrictions are imposed on computing stability functions, on L/q, the temperature and water-content variances, and their covariance, where L is the master length scale and q ²/2 the turbulent kinetic energy per unit mass. The model with these restrictions predicts vertical profiles of mean quantities such as temperature that are in good agreement with those obtained from large-eddy simulation of a radiation fog. In a regional prediction, it also reasonably reproduces the satellite-observed horizontal distribution of an advection fog.     

Countergradient Fluxes of Conserved Variables in the Clear convective and Stratocumulus-topped Boundary Layer: The role of the Entrainment Flux

Large-eddy simulations of a clear convective boundary layer (CBL)and a stratocumulus-topped boundary layer are studied. Bottom-upand a top-down scalars were included in the simulations, and theprinciple of linear superposition of variables was applied toreconstruct the fields of any arbitrary conserved variable.This approach allows a systematic analysis of countergradient fluxesas a function of the flux ratio, which is defined as the ratio betweenthe entrainment flux and the surface flux of the conserved quantity.In general, the turbulent flux of an arbitrary conserved quantityis counter to the mean vertical gradient if the heights where thevertical flux and the mean vertical gradient change sign do notcoincide. The regime where the flux is countergradient is thereforebounded by the so-called zero-flux and zero-gradient heights. Becausethe vertical flux changes sign only if the entrainment flux has anopposite sign to the surface flux, countergradient fluxes arepredominantly found for negative flux ratios. In the CBL the fluxratio for the virtual potential temperature is, to a good approximation,constant, and equal to -0.2. Only if the moisture contribution to thevirtual potential temperature is negligibly small will the flux ratio forthe potential temperature be equal to this value. Otherwise, theflux ratio for the potential temperature can have any arbitrary(negative) value, and, as a consequence, the fluxes for thepotential temperature and the virtual potential temperature willbe countergradient at different heights. As a practical application ofthe results, vertical profiles of the countergradient correction termfor different entrainment-to-surface-flux ratios are discussed.     

北京密云地区辐射与能量平衡特征分析

利用北京密云站2007年1,4,8和10月辐射及湍流通量观测资料,分析了农林混合非均匀下垫面晴天、阴天条件下的辐射平衡、反照率及能量平衡特征。结果表明：（1）1,4,8和10月能量平衡闭合度（OLS方法）分别为82%,97%,72%和83%,总体闭合度为76%,数据质量较好;（2）晴天向上长波辐射1,4,8和10月平均...     

旋转扰动流体中壁面湍流不稳定及其拟序结构研究Ⅱ：数值模式

对第一部分的实验结果进行了讨论,指出局地最大、最小涡度的存在与所谓的正压不稳定和大气中经常观测到的滚动涡有关。速度廓线中的拐点和涡度极大值点对应不稳定发展的位置。另外,为了改进湍流的模拟,根据“准正则”近似,发展了一个三阶闭合模式。这个模型已被证明可以描述与湍流过程有关的流体动力学变量的趋势。     

A New Tethered Balloon-Borne Payload for Fine-Scale Observations in the Cloudy Boundary Layer

A new scientific payload is introduced for fine-scale measurements of meteorological (wind vector, static air temperature, humidity, and air pressure) and microphysical (aerosol particles and cloud droplets) properties, suspended below a tethered balloon. The high resolution sensors and the tethered balloon are described. Measurements in a lifted fog layer from a first field campaign are presented.The detailed investigation of the fog/haze and the temperature inversion layer demonstrates the damping influence of the fog on temperature fluctuations, while thewind fluctuations are significantly decreased by theevolving temperature inversion, whichwas about 30 m above the fog layer.From spectral analysis the noise floors of the high-resolution sensors are determined to10^-6 kg m^-3 for the LWC (liquid water content) and 4 mK for the fast temperature sensor (UFT-B). The correlation betweentemperature and LWC structures in shallow haze layers is investigated. The release of latent heat and the corresponding warming in the haze of about 0.1 K could be quantified.     

The Control Of Coherent Eddies In Vegetation Canopies: Streamwise Structure Spacing, Canopy Shear Scale And Atmospheric Stability

An analogy has been established between a plane mixing layer and the atmospheric flow near the top of a vegetation canopy. It is based on a common feature, a strong inflection in the mean velocity profile, responsible for hydrodynamical instabilities that set the pattern for the coherent eddies and determine the turbulence length scales. In an earlier study, this analogy was tested using a small data set from thirteen experiments, all in near-neutral conditions. It provided a good prediction of the streamwise spacing _w of the dominant canopy eddies (evaluated from time series of vertical velocity) that appears to depend on a shear length scale L_s = U(h)/U'(h), where h is canopy height, U is mean velocity and U' the vertical gradient dU/dz. The present analysis utilizes an extensive data set of approximately 700 thirty-minute runs, from six experiments on two forest sites and a maize crop, with a large range of stability conditions. _w was estimated for each run using the wavelet transform as an objective, automated detection method. First, the variations of _w and L_s with atmospheric stability are discussed. Neutral and unstable values exhibit a large scatter whereas in stable conditions both variables decrease with increasing stability. It is subsequently found that _w is directly related to L_s, in a way close to the neutral prediction _w /h = 8.1L_s/h.The Strouhal number S_tr = L_s /_w is then shown to vary with atmospheric stability, weakly in unstable conditions, more significantly in stable conditions. Altogether these results suggest that, to some extent, the plane mixing-layer analogy can be extended to non-neutral conditions. It is argued that the primary effect of atmospheric stability, at least in stable conditions, is to modify the shear length scale L_s through changes in U(h) and U'(h), which in turn determines the streamwise spacing of the active, coherent motions.     

Buoyancy and The Sensible Heat Flux Budget Within Dense Canopies

In contrast to atmospheric surface-layer (ASL) turbulence, a linear relationship between turbulent heat fluxes (F_T) and vertical gradients of mean air temperature within canopies is frustrated by numerous factors, including local variation in heat sources and sinks and large-scale eddy motion whose signature is often linked with the ejection-sweep cycle. Furthermore, how atmospheric stability modifies such a relationship remains poorly understood, especially in stable canopy flows. To date, no explicit model exists for relating F_T to the mean air temperature gradient, buoyancy, and the statistical properties of the ejection-sweep cycle within the canopy volume. Using third-order cumulant expansion methods (CEM) and the heat flux budget equation, a “diagnostic” analytical relationship that links ejections and sweeps and the sensible heat flux for a wide range of atmospheric stability classes is derived. Closure model assumptions that relate scalar dissipation rates with sensible heat flux, and the validity of CEM in linking ejections and sweeps with the triple scalar-velocity correlations, were tested for a mixed hardwood forest in Lavarone, Italy. We showed that when the heat sources (S_T) and F_T have the same sign (i.e. the canopy is heating and sensible heat flux is positive), sweeps dominate the sensible heat flux. Conversely, if S_T and F_T are opposite in sign, standard gradient-diffusion closure model predict that ejections must dominate the sensible heat flux.     

藏北尼玛地区白垩纪岩浆岩对班公湖-怒江缝合带演化的制约

班公湖-怒江缝合带及其两侧广泛分布白垩纪岩浆岩,这些岩浆活动记录了班公湖-怒江特提斯洋俯冲至闭合以及拉萨-羌塘板块碰撞过程。为了约束该缝合带在早-晚白垩世的演化过程,本文对缝合带中段尼玛地区花岗岩进行岩相学、地球化学、锆石年代学和Hf同位素研究。尼玛北部虾别错花岗岩侵入到中生代地层中,发育石英闪长质包体。锆石U-Pb定年结果表明寄主花岗岩和包体形成于早白垩世(122Ma和121Ma)。这些锆石均具有正的ε_Hf(t)值,分别为+2.4~+7.0和+3.0~+5.1。寄主花岗岩具有高硅和高钾钙碱性特征,属于准铝质-弱过铝质系列。包体相对低硅,属于中钾钙碱性准铝质系列。寄主花岗岩和包体具有相似的微量元素分布,如均亏损Nb、Ta和Ti,富集Th、U和Pb。综合分析,虾别错寄主花岗岩和包体是壳幔熔体混合作用的产物。尼玛南部张乃错花岗岩侵入到古生代地层里。锆石U-Pb年龄为97Ma,形成于晚白垩世。锆石ε_Hf(t)值在+2.2~+6.0之间。张乃错花岗岩具有高硅特征,属于高钾钙碱性弱过铝质系列。岩体显著亏损Ba、Sr、Ti和Eu,富集Rb、Th、U和Pb等元素。该花岗岩来源于新生地壳部分熔融,并在后期经历结晶分异。结合区域地质概况,虾别错早白垩世花岗岩(和包体)形成于班公湖-怒江特提斯洋闭合过程,而张乃错晚白垩世花岗岩形成于洋盆闭合之后拉萨-羌塘板块碰撞背景。尼玛地区早-晚白垩世岩浆活动记录了班公湖-怒江缝合带从洋盆闭合到拉萨-羌塘板块挤压碰撞的演变过程。