夏季亚洲对流层中上层温度年际变率的预测水平评估及其在我国东部降水预测中的应用

夏季亚洲对流层温度异常与中国东部夏季降水紧密相关并可能作为降水的有效预报因子。基于欧盟ENSEMBLES计划的季节预测试验耦合模式每年5月1日开始的回报试验，分析了其对1960～2005年夏季亚洲对流层中上层温度（以200～500 hPa厚度替代，简称对流层温度）年际变率的预测结果，发现模式集合平均对夏季亚洲对流层温度年际变率具有较高的预报技巧，可以合理回报其前两个EOF（Empirical Orthogonal Function）主导模态（EOF1、EOF2），只是未能回报出EOF2高纬度的温度异常，模式集合平均预测的第一模态主成分（PC1）和第二模态主成分（PC2）与再分析资料的时间相关系数分别达到0.63和0.77。再分析资料中前两个EOF模态分别由ENSO（El Ni?o–Southern Oscillation）发展年印度夏季降水异常所激发的丝绸之路遥相关波列和ENSO衰减年西北太平洋夏季降水异常对应的太平洋—日本遥相关波列导致。ENSEMBLES计划可以合理预测出相应的海温异常及遥相关波列，进而合理预测出前两个EOF模态。对流层温度PC1和PC2分别表征了欧亚大陆与周围海洋之间的纬向和经向热力对比异常，模式对由PC1的预报技巧远高于前人定义的纬向热力对比的东亚夏季风指数，对前人定义的经向热力对比指数的预测技巧与PC2相当。将PC1和前人定义的经向热力对比指数作为预报因子，建立了中国夏季降水的动力—统计降尺度预测模型，交叉检验的结果表明该预报模型显著提高了东北和长江流域上游夏季降水的预报技巧。本文提出的亚洲对流层温度年际变率的EOF1及PC1，既能较好表征纬向热力对比与中国东部夏季降水显著相关，又能被模式合理预测，可以作为我国中高纬度地区，特别是东北地区降水的重要预测因子之一。     

On the transfer of stratospheric ozone into the troposphere near the north pole

A series of nearly daily ozone vertical profiles obtained at station T-3 on Fletcher's Ice Island (85°N, 90°W) during the period January-March 1971 shows several significant ozone intrusions into the troposphere. These intrusions are not only associated with enhanced ozone amounts in the stratosphere but also require tropopause folding events to transport ozone into the troposphere. These folds in the Arctic tropopause appear to be capable of contributing significantly to the ozone budget of the Arctic troposphere during the late winter and spring seasons. The importance of tropopause folding for bringing ozone into the troposphere seen in the daily ozone profiles confirms the results found in the Arctic Gas and Aerosol Sampling Program aircraft flights.     

A study of ozone in the Colorado mountains

The seasonal and diurnal variations of ozone mixing ratios have been observed at Niwot Ridge. Colorado. The ozone mixing ratios have been correlated with the NO _x (NO+NO₂) mixing ratios measured concurrently at the site. The seasonal and diurnal variations in O₃ can be reasonably well understood by considering photochemistry and transport. In the winter there is no apparent systematic diurnal variation in the O₃ mixing ratio because there is little diurnal change of transport and a slow photochemistry. In the summer, the O₃ levels at the site are suppressed at night due to the presence of a nocturnal inversion layer that isolated ozone near the surface, where it is destroyed. Ozone is observed to increase in the summer during the day. The increases in ozone correlate with increasing NO _x levels, as well as with the levels of other compounds of anthropogenic origin. We interpret this correlation as in-situ or in-transit photochemical production of ozone from these precursors that are transported to our site. The levels of ozone recorded approach 100 ppbv at NO _x mixing ratios of approximately 3 ppbv. Calculations made using a simple clean tropospheric chemical model are consistent with the NO _x -related trend observed for the daytime ozone mixing ratio. However, the chemistry, which does not include nonmethane hydrocarbon photochemistry, underestimates the observed O₃ production.     

Amino acid nitrogen in atmospheric aerosols: Occurrence,sources and photochemical modification

The presence of amino acids in atmospheric precipitation and aerosols has been noted for many years, yet relatively little is known about these or other nitrogen containing organic compounds in the atmosphere. Marine and continental rainwater analyses indicate that atmospheric aerosols, and subsequently atmospheric precipitation, may contain substantial levels of free and combined amino acids. The most likely source of amino N in the remote marine atmosphere appears to be the injection of proteinaceous material through the action of bursting bubbles at the sea-air interface or the long range transport from terrestrial sources. The capacity of these substrates to undergo photooxidation and photodegradation in the atmosphere to simpler species, such as ammonium ions, carboxylic acids, and for the S containing amino acids, oxidized forms of sulfur, has received little attention from atmospheric chemists. The photochemistry of covalently bound amino groups, particularly as found in peptides and amino acids, is discussed here with the purpose of summarizing what is known of their occurrence and their possible importance to atmospheric chemistry.     

Diurnal variability in turbidity and coral fluorescence on a fringing reef flat: Southern Molokai,Hawaii

Terrigenous sediment in the nearshore environment can pose both acute and chronic stresses to coral reefs. The reef flat off southern Molokai, Hawaii, typically experiences daily turbidity events, in which trade winds and tides combine to resuspend terrigenous sediment and transport it alongshore. These chronic turbidity events could play a role in restricting coral distribution on the reef flat by reducing the light available for photosynthesis. This study describes the effects of these turbidity events on the Hawaiian reef coral Montipora capitata using in situ diurnal measurements of turbidity, light levels, and chlorophyll fluorescence yield via pulse-amplitude-modulated (PAM) fluorometry. Average surface irradiance was similar in the morning and the afternoon, while increased afternoon turbidity resulted in lower subsurface irradiance, higher fluorescence yield (ΔF/F_m^′), and lower relative electron transport rates (rETR). Model calculations based on observed light extinction coeffecients suggest that in the absence of turbidity events, afternoon subsurface irradiances would be 1.43 times higher than observed, resulting in rETR for M. capitata that are 1.40 times higher.     

The effect of the Mt St Helens eruption on tropospheric and stratospheric ions

Balloon-borne observations of electrical conductivity in the troposphere and stratosphere were performed using conductivity sondes at Garmisch-Partenkirchen, West Germany, from June to November, 1980, after the Mt St Helens eruption. A significant decrease of atmospheric ions in the altitudes from the troposphere to lower stratosphere has been detected until several months after the eruption in comparison with the observational results obtained before the eruption. Simulteneous ruby lidar observation a month after the eruption indicates an increased amount of aerosol at nearly the same altitude as that of conductivity decrease. Several months after the eruption it appears that aerosols detected by lidar and those effective in reducing ion concentration have different profiles.     

GPS定位中对流层折射估计研究

本文首先讨论了ＧＰＳ相对定位中的对流层折射２估计的单参数方法，多参数方法，分估线性方法和随机过程方法。论证了其它方法都是随机过程方法的近似。为了用随机过程模拟对流折射，建立了一种最小二乘递推算法。在此基础上，在ＧＡＭＩＴ软件中统一实现了以各种对流层折射估计方法。最后给出并分析了不同方法所获得的结果。     

The action of chlorine on the ozone layer as given by a zonally averaged two-dimensional model

In order to study the behavior of stratospheric minor constituents related to aeronomic processes and atmospheric transport in the meridional plane, a numerical two-dimensional model is established.This model is applied to the study of chlorine compounds in the stratosphere. A special attention is devoted to the effect in the ozonosphere of an increase of CIX due to anthropogenic activities.