Speciation of trace metals in sediments of a tropical estuary

Axial surveys were performed in the two river tributaries of the Cochin estuary, SW India during November 1988. Surficial sediments were subjected to sequential chemical extractions to delineate five metal fractions, namely, exchangeable, carbonate bound, easily reducible, organic/sulfide bound, and residual. The results indicated selective accumulation of Mn and Ni in carbonate bound and organic/sulfide forms, along with marginal amounts of Co in the exchangeable fraction. Large portions of Fe and Cr occurred in the residual fraction, whereas composite fractionation of Zn species was noticed. The exchangeable fractions of Fe and Cr as well as of easily reducible cobalt were below detection limits. The levels of Cr and Zn indicate anthropogenic inputs in this estuary, whereas Co and Ni show regional contamination exceeding natural levels. The analytical speciation procedure helps to deduce the sedimental diagenetic processes in the estuarine environment.     

Infiltration at the Tai rain forest (Ivory Coast): Measurements and modelling

Infiltration experiments have been performed at three sites along a well-known catena under virgin tropical rain forest using a portable sprinkling infiltrometer. Experimentally determined infiltration curves are presented. Infiltration curves are also simulated on the basis of the Mein-Larson equation. The parameters for this model have been obtained from the infiltration curves (saturated conductivity) and simple soil moisture determinations (fillable porosity). The agreement between experimentally determined and modelled infiltration is reasonable, provided (a) saturated conductivity as derived from the experimental data is corrected, (b) a storage parameter, also derived from the experimental data, is added to the Mein-Larson model, and (c) the decline in soil porosity with depth is either small or occurs abruptly at shallow depth. Comparison of observed infiltration rates with rainfall intensity shows that Horton Overland Flow has to occur naturally at least on the middle and lower section of the catena. Despite the fact that most parameters can be estimated in principle from basic soil data, it remains advisable to obtain sprinkling infiltrometer field measurements, because of soil variability due to dynamic surface conditions, macroporosity, air entrapment, and irregularity of the wetting front.     

Spectra of quasiperiodic oscillations of galactic X-ray sources–dynamical regimes from a simple model

We suggest that the dynamical regime(s) underlying quasi-periodic oscillations observed in the spectra of bright galactic-bulge X-ray sources are nonlinear with a mixed phase space. The important feature of such regimes is that they are generic among nonlinear Hamiltonian and nearly Hamiltonian systems of more than two degrees of freedom. We give a simple example of such chaotic (deterministic) systems whose spectra share a number of features with those observed for quasiperiodic oscillations of such sources.     

A numerical study of the r-mode instability of rapidly rotating nascent neutron stars

The first results of numerical analysis of classical r-modes of rapidly rotating compressible stellar models are reported. The full set of linear perturbation equations of rotating stars in Newtonian gravity is solved numerically without the slow rotation approximation. A critical curve of gravitational wave emission induced instability, which restricts the rotational frequencies of hot young neutron stars, is obtained. Taking the standard cooling mechanisms of neutron stars into account, we also show the 'evolutionary curves' along which neutron stars are supposed to evolve as cooling and spinning down proceed. Rotational frequencies of 1.4-M_⊙ stars suffering from this instability decrease to around 100 Hz when the standard cooling mechanism of neutron stars is employed. This result confirms the results of other authors, who adopted the slow rotation approximation.