Product study of the reaction of OH radicals with isoprene in the atmosphere simulation chamber SAPHIR

Atmospheric oxidation of isoprene and its oxidation products methacrolein (MACR) and methyl vinyl ketone (MVK) have an important impact on the photochemical activity in the boundary layer, in particular in forested areas. The oxidation of isoprene by OH radicals was investigated in chamber experiments conducted under tropospheric conditions in the atmosphere simulation chamber SAPHIR at the Research Center Jülich. The aim was to determine the product yield of MVK and MACR in the OH-induced isoprene oxidation and the rate constant of their reaction with OH under real atmospheric conditions. The recently published updated degradation scheme for isoprene from Geiger et al. (2003) was used to determine rate constants and product yields. The fractional yields in the isoprene peroxy radical reaction with NO were found to be 0.41±0.03 for MVK and 0.27±0.03 for MACR. The rate coefficient for MACR with OH was found to be in very good agreement with the recommended value of IUPAC Atkinson (Atkinson et al., 2005). while the rate coefficient for MVK with OH was 27% lower.     

北京市砂石坑对环境的影响

本文主要从砂石坑对北京地区大气质量、地下水和土地三方面,阐述了砂石坑对环境的影响,并提出了治理建议。     

Theorem of turbulent intensity and macroscopic mechanism of the turbulence development

Turbulence is one of the most common nature phenomena in everyday experience, but that is not adequately understood yet. This article reviews the history and present state of development of the turbulence theory and indicates the necessity to probe into the turbulent features and mechanism with the different methods at different levels. Therefore this article proves a theorem of turbulent transpor- tation and a theorem of turbulent intensity by using the theory of the nonequilibrium thermodynamics, and that the Reynolds turbulence and the Rayleigh-Bénard turbulence are united in the theorems of the turbulent intensity and the turbulent transportation. The macroscopic cause of the development of fluid turbulence is a result from shearing effect of the velocity together with the temperature, which is also the macroscopic cause of the stretch and fold of trajectory in the phase space of turbulent field. And it is proved by the observed data of atmosphere that the phenomenological coefficient of turbulent in- tensity is not only a function of the velocity shear but also a function of temperature shear, viz the sta- bility of temperature stratification, in the atmosphere. Accordingly, authenticity of the theorem, which is proved by the theory of nonequilibrium thermodynamics, of turbulent intensity is testified by the facts of observational experiment.     

一种快速地球大气效果3维绘制方法

介绍了地球大气模型,并回顾了国内外大气的3维绘制算法。在此基础上提出了一种基于简化模型的快速大气效果绘制算法。该算法综合利用Billboard与图形学雾化效果,逼真模拟出了地球大气的可视化效果。实验结果表明,该算法简单有效,避免了复杂的物理计算,大大提高了绘制效率。     

Three-dimensional mapping of salt stores in the Murray-Darling Basin,Australia: 2. Calculating landscape salt loads from airborne electromagnetic and laboratory data

Salt is widespread in the Australian landscape – in soil, regolith and groundwater – leading to concerns that land management practices may be putting much agricultural land and important water resources at risk of salinisation. Defining the location and nature of salt stores is an important first step in understanding the processes leading to salinity of soils, streams and groundwater resources, and predicting areas that may be at risk. Airborne geophysics can define subsurface salt stores and mobilisation pathways. Airborne electromagnetics (AEM) can map the three-dimensional conductivity structure of the landscape but does not, intrinsically, quantify the amount of salt. Salinity, moisture content, porosity and mineralogy all contribute to the electromagnetic signal, and each can vary significantly throughout the landscape.In the Lower Balonne catchment, Queensland, the relationship between AEM and the amount of salt in the landscape was quantified using laboratory analyses of pore fluids from core samples. A general statistical relationship was established between AEM conductivity and salt load (defined as the product of pore fluid salinity, porosity and moisture content)—with a significant positive correlation although data were generally widely dispersed. Comparison of calculated salt load with borehole electromagnetic logs gives insight into the factors contributing to dispersion in the AEM data.The relationship transforms bulk conductivity to salt load in 5 m layers, allowing the generation of a three-dimensional map of the salt load. This is a powerful tool for identifying areas that may require monitoring and management interventions to reduce salinity risk. An example is given of salt loads beneath an established irrigation area in the Lower Balonne catchment, Queensland.     

The Atmospheric Oxidation of the HS Radical: Reaction with NO2

The atmospheric reaction between HS and NO₂ was theoretically investigated at 298 K and 1 atm of pressure. Our results show that the first reaction step will lead to the formation of HSNO₂ or HSONO, spontaneously and exothermically. HSONO easily decomposes into HSO + NO. On the other hand, HSNO₂ can hardly dissociate in the reactants, and its isomerization to other adducts is much hindered. Production of HNO + SO and SNO + OH was found to be unfavorable. Thus, the main products would be HSO + NO and HSNO₂, and new investigations focusing on the atmospheric fate of HSNO₂ are suggested. A general discussion of the fate of HS under atmospheric conditions is presented. Recent investigations indicate that NO₂, O₂ and N₂O should be the most important oxidants of HS, while the O₃ influence will not be significant.     

On the solar cycle dependence of winds and planetary waves as seen from mid-latitude D1 LF mesopause region wind measurements

At the Collm Observatory of the University of Leipzig LF D1 low-frequency total reflection nighttime wind measurements have been carried out continuously for more than two decades. Using a multiple regression analysis to derive prevailing winds, tides and the quasi-2-day wave from the half-hourly mean values of the horizontal wind components, monthly mean values of mesopause wind parameters are obtained that can be analysed with respect to long-term trends and influences of solar variability. The response of the prevailing wind to the 11-year solar cycle differs throughout the year. While in winter no significant correlation between the zonal prevailing wind and solar activity is found, in spring and summer a negative correlation between the TWC can be seen from the measurements. This is connected with stronger vertical gradients of the zonal prevailing wind during solar maximum than during solar minimum. Since the amplitude of the quasi-2-day wave is dependent on the zonal mean wind vertical gradient, this is connected with a positive correlation between solar activity and quasi-two-day wave activity.Paper Presented at the Second IAGA/ICMA (IAMAS) Workshop on Solar Activity Forcing of the Middle Atmosphere, Prague, August 1997     

Cooling of the mesosphere and lower thermosphere due to doubling of CO2

A new parameterization of infrared radiative transfer in the 15-m CO₂ band has been incorporated into the Spectral mesosphere/lower thermosphere model (SMLTM). The parameterization is applicable to calculations of heating rates above approximately 15 km for arbitrary vertical profiles of the CO₂ concentration corresponding to the surface mixing ratio in the range 150–720 ppm. The sensitivity of the mesosphere and lower thermosphere (MLT) to doubling of CO₂ has been studied. The thermal response in the MLT is mostly negative (cooling) and much stronger than in the lower atmosphere. An average cooling at the stratopause is about 14 K. It gradually decreases to approximately 8 K in the upper mesosphere and again increases to about 40–50 K in the thermosphere. The cooling and associated thermal shrinking result in a substantial density reduction in the MLT that reaches 40–45% in the thermosphere. Various radiative, chemical, and dynamical feedbacks potentially important for the thermal response in the MLT are discussed. It is noted that the results of simulations are strikingly similar to observations of long-term trends in the MLT. This suggests that during the last 3–4 decades the thermal structure in the real upper atmosphere has undergone substantial changes driven by forcing comparable with that due to doubling of CO₂.     

Thermoelastic stress due to a rectangular heat source in a semi-infinite medium. Presentation of an analytical solution

The thermoelastic response due to a time-dependent rectangular heat source in a semi-infinite medium is analyzed. The problem originates from studies of nuclear waste repositories in rock. Canisters containing heat-emitting nuclear waste are deposited over a large rectangular area deep below the ground surface. The solution for a time-dependent heat source is obtained from the corresponding instantaneous heat source by superposition. The thermoelastic problem for the instantaneous rectangular heat source in a infinite surrounding is solved exactly. An important step is the introduction of so-called quadrantal heat sources. The solution for the rectangle is obtained from four quadrantal solutions. The solution for the quadrantal heat source depends on the three dimelasionless coordinates only. Time occurs in the scale factors only. The condition of zero normal and shear stresses at the ground surface is fulfilled by using a mirror heat source and a boundary solution. The boundary solution accounts for the residual normal stress at the ground surface. Using a Hertzian potential, a surprisingly simple solution is obtained. The final analytical solution is quite tractable considering the complexity of the initial problem. The solution may be used to test numerical models for coupled thermoelastic processes. It may also be used in more detailed numerical simulations of the process near the heat sources as boundary conditions to account for the three-dimensional global process.     

Joint analysis of seismological data by the USSO and DSS stations in the Caucasus region

This paper deals with a procedure of a joint analysis of seismic data from earthquakes and those obtained by DSS. The DSS data are used as a first approximation to construct a two-dimensional model of the medium made up of individual blocks. These models serve as a basis when constructing specific three-dimensional travel-time curves. These travel-time curves are further used for the calculation of hypocenter parameters in a laterally inhomogeneous block medium.The hypocenter field and the travel times obtained are input data for the computation of three-dimensional fields of velocities in earthquake focal zones. Results of applying the proposed procedure to the Caucasus region are presented.