哈尔滨市冬末逆温、大气稳定度与大气污染概率关系

利用2006～2008年2月逐日地面常规观测资料和高空探测资料以及逐日的污染监测资料,统计分析了哈尔滨市2月风速、逆温和大气稳定度与大气污染的概率关系。分析结果表明：哈尔滨市2月的大气污染主要发生在风速〈3 m/s,污染物浓度随着风速的增大而减小,在一定程度上反映了哈尔滨市2月的污染主要是局地污染物的累积;发生大气污染时一定有逆温出现,但有逆温时不一定就发生大气污染;大气稳定度增加,大气污染概率增大。     

Pyrite–anhydrite–magnetite–pyroxene-type deposits and coexisting hydrothermal fluids in Mesozoic volcanic basins, Yangtze River Valley, China

Anhydrite–pyrite–magnetite–pyroxene–type deposits occur in the Mesozoic volcanic areas of the Middle–Lower Yangtze Valley in China. These deposits are hosted in alkaline basaltic rocks, and are generally accompanied by melanocratic and leucocratic alteration zones, both of which are characterized by a distinct vertical zonation pattern. Investigation of these zones indicates that the chemical compositions of solid solutions and polymorphs of various minerals vary spatially in the alteration profile, upwards from the lowest level, and outwards from the center.Here we report a case study on the Luohe deposit. In the melanocratic-alteration zone, the composition of magnetite (including trace elements Ti, V, Mg, Mn), pyroxene (Mg, Fe²⁺, Fe³⁺, Al₂O₃), plagioclase (An_xAb_{1 − x}), pyrite (Co, Ni) and apatite (F, CeO₂ + Y₂O₃ + La₂O₃) changes with depth. The isotherms of hydrothermal fluids determined from fluid inclusion data, including homogenization temperature and salinity, also vary with depth.Activity diagrams were constructed from mineral and isotherm analysis to estimate the chemical constraints on the alteration-mineral assemblages and the coexisting hydrothermal solutions for the Na₂O–K₂O–CaO–MgO–FeO–Fe₂O₃–A1₂O₃–SiO₂–H₂SO₄–H₂S–HCI–H₂O system at 350 to 600 °C and 500 bars (50 MPa), assuming that the major alteration mineral assemblages along the profile reflect the nature of the coexisting hydrothermal solutions. The activity diagrams adopted the major minerals as buffers to fix the activities of the aqueous species in the system, simulating the physicochemical conditions of the magnetite–anhydrite–pyroxene equilibrium and of solid solutions of diopside–hedenbergite, grossular–andradite and anorthite–albite found in the profile.This study provides an approach to modeling the chemical constraints of coexisting fluids in ore-alteration zones based on field observations.     

西藏尼木变质岩特征及变质温压条件

出露于雅鲁藏布江缝合带北侧尼木县的变质岩主要由石榴黑云片麻岩和黑云斜长角闪角岩组成.研究表明岩石变质程度达到角闪角岩相-辉石角岩相;石榴子石变斑晶具有生长环带,角闪石均为钙质角闪石,黑云母大多为铁质黑云母和铁叶云母,长石多为更长石和中长石,少量为正长石.利用石榴子石-黑云母温度计、石榴子石-黑云母-斜长石-石英压力计和角闪石-斜长石温度及压力计计算获得石榴黑云片麻岩和黑云斜长角闪角岩的变质温度分别为619 ～661℃,695 ～ 702℃,压力范围分别为1.86～1.94kbar和3.69～4.56kbar.野外和室内研究认为岩石原岩为冈底斯带南缘叶巴组火山岩及其上部沉积岩,岩石经历了高温低压的接触变质作用.结合已有冈底斯带陆缘岩浆活动特征,对变质岩的形成环境和过程进行了反演.     

Diurnal variation in relative photosynthetic performance of marestail (Hippuris vulgaris Linn.) Across a water temperature gradient using PAM fluorometry in Jiuzhaigou National Nature Reserve, Sichuan Province, China

This paper reports the first photosynthetic study of marestail in Jiuzhaigou. In this work, we used PAM fluorometry to examine photosynthetic rates of submerged and emerged marestail in three lakes. Three lakes were studied across a gradient of water temperature, with low water temperature conditions in Grass Lake and Arrow Bamboo Lake, and higher water temperature in Five Colored Lake. In the field, electron transport rates (ETR_max) were measured as rapid light curves (RLCs) by in situ yield measurements. Submerged and emerged marestail showed higher photosynthetic activity in Five Colored Lake compared to the other lakes, a response consistent with the adaptation of marestail in Five Colored Lake to high water temperature. The optimal temperature for photosynthesis of submerged marestail in Jiuzhaigou was about 12 °C. Nonphotochemical quenching (NPQ) of submerged and emerged marestail increased with increasing water temperature. Maximum quantum yield (F _v/F _m) of submerged marestail in Five Colored Lake showed full recovery at 1700 h due to higher NPQ. Further, the chlorophyll a for submerged marestail was the highest in Grass Lake and the lowest in Five Colored Lake. These results indicate that in different lakes the function of these aquatic plants is associated with a diversity of place-dependent environmental conditions, especially water temperature that leads to pronounced differences in the plant’s ecophysiological reactions.     

A 352-year record of summer temperature reconstruction in the western Tianshan Mountains,China, as deduced from tree-ring density

Three robust tree-ring density chronologies were developed for the western Tianshan Mountains of northwestern China. The chronologies were significantly correlated and form a regional chronology (GLD). The GLD had significant and positive correlations with temperature of warm seasons. Based on this relationship, the mean minimum temperatures of May to August were reconstructed using the GLD chronology for the period AD 1657 to 2008. The temperature reconstruction exhibited temperature patterns on interannual to centennial timescales, and showed that the end of the 20th century is the warmest period in the past 352 years. The reconstructed temperature variation has a teleconnection with large-scale atmospheric–oceanic variability and captures long- and broad-scale regional climatic variations.     

塔里木盆地凝析气田的地质特征及其形成机制

塔里木盆地凝析油气资源丰富,已发现了二十余个凝析气田,包括库车坳陷的陆相油气来源的凝析气田和台盆区海相烃源岩来源的凝析气田;储层有碎屑岩,也有碳酸盐岩;时代自奥陶系至新生代均有分布。这些凝析气田的气油比分布在600~19900m³/m³,凝析油含量40~750g/m³;储层温度在78~155℃;地层压力在37~111MPa。研究认为,塔里木盆地凝析气藏的成因类型可以分为原生凝析气藏和次生凝析气藏。其中,以库车坳陷迪那2凝析气田为代表的煤系烃源岩在高演化阶段(镜质体反射率Ro为1.2%~2.0%),即凝析油和湿气生成带所形成的原生腐植型凝析气藏或煤成型凝析气藏。次生凝析气藏包括两类:陆相油气来源的多期充注,晚期干气对早期油藏发生混合改造,形成了以牙哈为代表的陆相油气成因的次生凝析气藏;以海相油气来源,多期油气充注与晚期干气气侵,造成蒸发分馏,在运移、聚集和成藏过程中烃体系分异、富化,发生反凝析作用,从而导致次生凝析气藏的形成。随着塔里木盆地勘探向深层转化,地层的温度和压力逐渐增高,烃类演化程度的升高,不同生烃阶段的烃体系混合也将更为普遍,次生凝析气藏也将更为普遍,因此,以海相油气来源的次生成因型凝析气藏将成为勘探的主体。     

树轮最大密度记录的吉尔吉斯斯坦天山山区公元1650年以来的7-8月温度变化

利用吉尔吉斯斯坦天山山区3个采样点的雪岭云杉树轮最大密度数据建立区域树轮最大密度年表（RC）。气候响应分析发现,区域树轮最大密度年表与7-8月平均温度显著相关。在此基础上,利用区域树轮最大密度年表重建了吉尔吉斯斯坦天山山区自1650年以来的7-8月温度变化,重建方程的方差解释量高达45．3％（Radj^2=44．7％,N=95,F=77．029）。重建结果显示,在过去的346a中吉尔吉斯斯坦天山山区7-8月平均温度的异常高温年份为40a,异常低温年份为46a,且存在11个低温时段（16501654,1662-1678,1693-1703,1779-1794,1801-1805,1811-1819,1834-1854,1882-1910,1917-1923,1952-1975和1986-1992年）和11个高温时段（1655-1661,1679-1692,1704-1778,1795-1800,1806-1810,1820-1833,1855-1881,1911-1916,1924-1951,1976-1985和1994-至今）。突变和周期分析揭示该地区的温度变化受到了火山、太阳活动和海陆气交互作用的共同影响。此外,在过去的346a来气候以暖干／冷湿为主,近20a来出现了明显暖湿化趋势。     

单斜星叶石矿物的穆斯堡尔光谱学研究

本文对产于俄罗斯希宾地区的单斜星叶石进行了不同的温度条件下的穆斯堡尔光谱效应研究,通过在温度分别在298 K,180 K和80 K条件下的分析,发现单斜星叶石由2个Fe~(2 )和1个Fe~(3 )四极双峰组成,并进行了单斜星叶石中的畸变参数包括八面体键角(σ~2)和键长变量(Δ)的计算。但是,在两个畸变参数之间存在着明显的差异,将无法对它们的穆斯堡尔参数和四极双峰进行指派。本文对温度在同质异能位移和四极分裂中的作用进行了探讨,根据通过穆斯堡尔效应和f(Fe~(3 )(O))/f(Fe~(2 )(O))的平均值获得的三价铁对全铁的比值,改写了单斜星叶石的化学式。     

Salt water infiltration in two artificial sea inlets in the Belgian dune area

In the dune area of the Westhoek Nature Reserve, situated in the western Belgian coastal plain, two artificial tidal inlets were made aiming to enhance biodiversity. The infiltration of salt water in these tidal inlets was carefully monitored because a fresh water lens is present in the phreatic dune aquifer. This forms an important source of fresh water which is for instance exploited by a water company. The infiltration was monitored over a period of two years by means of electromagnetic borehole measurements (EM39) and by measurements of fresh water heads and temperature using a large number of observation wells. EM39 observations point to aquifer heterogeneity as a determining factor in the movement of the salt infiltration water. It is shown that part of the infiltration water moves further in the dunes instead of towards the sea. On the long term run, possibility exists that salt water enters the extraction’s capture zone. This issue needs further monitoring and study. Fresh water head and temperature data illustrate that the main period of infiltration is confined to spring tide when large amounts of salt water enter the tidal inlets.