非等大球体的任意堆积

利用比重为1.80的分子筛材料球粒进行了等大球和不等大球的任意堆积,相当于水介质中天然颗粒的堆积。得出了不同堆积强度时等大球的堆积密度。不等大球的堆积在相当宽的范围内可视为等大球的堆积,粒径比的阈值为0.70,小球与大球直径之比小于该值时,堆积密度开始增大,通过实验得出了堆积密度随粒径比的变化曲线。实验结果对于了解沉积作用和沉积岩孔隙度等有重要意义。     

国内外河口悬沙通量研究进展

系统地介绍了国内外河口悬沙通量研究的进展,目前对于河口悬沙通量主要采用模型研究、水文学方法、机制分解、仪器直接测量等方法从理论和实际相结合的角度来进行研究。目前物理模型的研究成果比较直观,但受到模型尺度和精度等的限制,数学模型研究具有快、准的优点,可以给出令人满意的定性结果,但未能达到定量预报的程度;传统的水文学方法可以用来研究河口地区悬移质泥沙在不同动力因子作用下的输移情况;机制分解法是比较成熟和可靠的方法,但该方法与河口动力机制和泥沙输移过程结合不够;使用先进仪器进行直接测量则受到仪器精度和取样点的布设等条件的限制。因此,关于河口悬沙通量的研究还有待于深入和细化。     

三峡水库区间来沙量估算及水库排沙效果分析

三峡水库是控制和开发长江的重要工程,具有巨大的防洪、发电、航运等综合效益.水库排沙比是反映水库拦截泥沙程度的重要指标.针对目前三峡水库排沙比计算没有考虑三峡水库区间来沙,结果偏大的问题,依据三峡水库区间水文站2003-2016年实测水文资料,采用水文学法估算了三峡水库区间月、年入库输沙量,分析了三峡水库排沙效果及主要影响因素.结果表明：1）三峡水库区间年均来沙量约1775×10⁴ t,占总入库沙量的10.3%,近年来沙占比有所增大,其中2013-2016年来沙量占总入库沙量的26.9%;2）三峡水库年均排沙比为21.6%,其中围堰蓄水期为34.1%,初期蓄水期为17.0%,试验性蓄水期为15.4%;3）三峡水库采用"蓄清排浑"方式运行,主汛期7-9月的排沙比一般大于枯季,但2013年以后,出现了主汛期排沙比小于枯季的现象;4）入库细颗粒泥沙的排沙比大于粗颗粒泥沙,其中粒径d ≤ 0.062 mm的细颗粒泥沙排沙比为23.4%,0.062 mm0.125 mm的中粗沙排沙比分别为5.5%和11.1%;5）三峡水库排沙比汛期主要受V/Q影响,枯季主要受入库含沙量的影响;当V/Q约为170×10⁴ s时,水库排沙效果最差;分别建立了汛期和枯季排沙比经验计算式.本文的研究成果可为三峡水库水沙优化调度等提供参考.     

香港能见度、大气悬浮粒子浓度与气象条件的关系

利用2005年赤角能见度及东涌悬浮粒子(PM2.5)浓度的每小时数据,发现PM2.5 浓度与能见度(撇除雨雾及相对湿度≥95%的个例)呈倒数关系,相关系数约为0.8.此外,出现低能见度(能见度低于8 km,而雨雾及相对湿度≥95%的个例不计)的每月总时数与月平均PM2.5浓度都呈现相类似的季节趋势,即冬季较高,夏季较低.利用HYSPLIT作反轨迹图分析显示这现象跟影响香港的空气来源有关.来自内陆的轨迹中,出现低能见度的日平均时数及日平均PM2.5的浓度,分别远高于来自海洋的轨迹.文中还分析了一个有热带气旋接近本港的个例,论证气象条件对能见度及PM2.5浓度的重要性.     

北京风沙天气的气溶胶特征

利用常规气象观测资料、卫星云图以及1988、1990、1992、1993、1995、2000年等年北京风沙天气期间所采集的气溶胶样品的分析结果,研究了北京的风沙天气分布特征,风沙期间大气污染状况,产生风沙天气的主要原因及沙尘的来源等.初步得出北京的风沙天气主要出现在春季,是造成春季大气污染的重要原因之一;北京春季风沙天气是由沙尘暴、浮尘和扬沙造成,但以扬尘引起的频率为最高,占71.4%;风沙期间大气气溶胶与无风沙时气溶胶的物理化学特征有明显的差异;大气气溶胶的物理化学特征显示出,风沙期间的大气气溶胶主要来源于自然源,以局地尘源为主,人为排放的气溶胶作用相对减弱.     

Distribution and sources of aliphatic and polycyclic aromatic hydrocarbons in suspended particulate matter in water from two Brazilian estuarine systems

The levels of selected organic markers, including 17 polycyclic aromatic hydrocarbons (PAHs), 16 of which are classified as priority pollutants by the US-EPA and perylene, aliphatic hydrocarbons (total and linear alkanes) and petroleum biomarkers (hopanes and steranes), were measured in suspended particulate matter (SPM) of the Mundaú-Manguaba estuarine-lagoon system (MMELS) in northeastern Brazil and the Paraíba do Sul River (PSR) estuary in southeastern Brazil, both of which are affected by sugarcane agriculture and urbanization. A total of 33 surface water samples of SPM were collected (22 from the MMELS and 11 from the PSR). The ∑16PAH ranged from 221 to 1243 ng g⁻¹ in the MMELS and from 228 to 1814 ng g⁻¹ in the PSR. Hopane and sterane concentrations in the PSR were higher than in the MMELS due to the input from petrogenic sources in PSR. The contributions of higher plants were also observed by n-alkane analyses. The PAH isomeric ratios indicated that the SPM from MMELS showed characteristics of combustion from biomass or petroleum and PSR was associated to petrogenic input, either from combustion or from unburned petroleum. Three sampling sites located near to the sugarcane plant and mouth of the rivers showed higher PAH concentrations and may largely be considered as highly contaminated. However, levels of n-alkanes and petroleum biomarkers in both study areas were relatively low.     

Distributions of polycyclic aromatic hydrocarbons in the Daliao River Estuary of Liaodong Bay, Bohai Sea (China)

The distributions of 16 polycyclic aromatic hydrocarbons (PAHs) were determined in the aqueous phase, suspended particulate matter (SPM), sediment, and pore water of the Daliao River Estuary in Liaodong Bay, Bohai Sea (China). Total PAH concentrations ranged from 139.16 to 1717.87 ng L⁻¹ in surface water, from 226.57 to 1404.85 ng L⁻¹ dry weight in SPM, from 276.26 to 1606.89 ng g⁻¹ dry weight in sediments, and from 10.20 to 47.27 μg L⁻¹ in pore water. PAH concentrations were at relatively moderate levels in water, SPM, sediment and pore water in comparison with those reported for other estuary and marine systems around the world. Sedimentary PAH concentrations decreased offshore owing to active deposition of laterally-transported river-borne particles. PCA analysis of the possible PAH source suggested petrogenic and pyrolytic PAH inputs in the studied region.     

Transport and delivery of suspended solids, nitrogen and phosphorus from various sources to freshwaters in the UK

Sources of nutrients and suspended solids (SS) are diverse in origin and dynamic with respect to their transport pathways and delivery to surface and groundwaters. Three broad source groups can be identified based on their hydrological and compositional characteristics. Consented discharges from point sources are generally continuous and highly concentrated relative to receiving waters while non-point (diffuse) sources are generally more dilute with SS and phosphorus in particular tending to have a high transport dependence upon hydrological (storm) events. A third group with properties that are intermediate include overflows from septic systems, seepages from farmyards or road/track runoff. This grouping automatically introduces a strong temporal and spatial variability in the relative contribution individual group sources make to the total quantity of nutrients and SS delivered to freshwaters. This spatial or temporal variability in either effluent volumes or composition is generally not considered when predicting impacts, which can be highly significant in headwater streams. Complete compositional data for individual sources (especially the intermediary group) are also often lacking when apportioning source contributions in catchments, being simply lumped into average export coefficients. Better definition of intermediary sources would help to more accurately define the relative contribution of different sources and enable cost-effective river basin management planning as required under the Water Framework Directive.     

不同层间堆垛密度的HDTMA^＋柱撑蒙脱石对对硝基苯酚的吸附实验研究

本文以阳离子表面活性剂(十六烷基三甲基溴化铵,HDTMAB)为柱撑剂,在不同浓度条件下(0.5～2.5CEC)制备了层间季铵盐离子呈单层平卧、双层平卧和倾斜双层排列的HDTMA 柱撑蒙脱石,并研究了具有不同层间结构的HDTMA 柱撑蒙脱石对对硝基苯酚的吸附能力以及溶液pH值、温度、对硝基苯酚初始浓度等因素对HDTMA 柱撑蒙脱石吸附性能的影响。实验结果表明,HDTMA 柱撑蒙脱石对对硝基苯酚的吸附能力随着介质溶液pH值的升高而升高,这主要受对硝基苯酚在不同pH条件下的离子化程度影响;HDTMA 柱撑蒙脱石对对硝基苯酚的吸附能力随着介质溶液温度的升高而降低,说明吸附反应是一个放热过程。同时,从单层平卧→双层平卧→倾斜双层,HDTMA 柱撑蒙脱石对对硝基苯酚的吸附能力明显提高。钠基蒙脱石和低堆垛密度(单层平卧、双层平卧)的HDTMA 柱撑蒙脱石对对硝基苯酚的吸附等温线呈S型,而高堆垛密度(倾斜双层)的HDTMA 柱撑蒙脱石对对硝基苯酚的吸附等温线呈Linear型,表明前者以表面吸附为主,后者以分配作用为主。     

Suspended basaltic glass–seawater interactions

The objective of this study was to quantify by experiments the initial seawater–suspended basaltic glass interactions following the 1996 outburst flood from the Vatnajökull glacier, Iceland. The altered basaltic glass dissolved in seawater as recorded by the Si release from the glass. The dissolved concentrations of Na, Ca, Si, Ba, Cd, Co, Cu, Hg, Mn, Ni and total dissolved inorganic N increased with time but the concentrations of Mg, K, S, Sr, Fe, Pb and Zn decreased. Calculated 1 to 10 day fluxes for Si range from 38,000 tons/day to 70,000 tons/10 days. The fluxes for other major elements are more uncertain, but the positive flux (release from suspended matter to seawater) of Ca and Na, and negative flux of Mg, K and S are greater than the Si flux.