Comparative studies of the kinetic parameters of various algaenans and kerogens via open-system pyrolyses

Kinetic parameters were determined for the first time, via open-system pyrolyses, on algaenans (highly resistant biomacromolecules that are selectively preserved during kerogen formation) isolated from extant microalgae. Parallel studies were also carried out on 10 kerogens exhibiting, with one exception, a low level of maturity. These kerogens included samples chiefly derived from the selective preservation of the above algaenans and samples mainly, or almost exclusively, derived from the “natural vulcanization” pathway. Important differences in activation energy (E_a) distributions were observed between the four algaenans investigated and correlated with their chemical structures. The kerogens predominantly derived from algaenan-selective preservation (Pula alginite, NE 70 and BJ 248 Torbanites, Rundle Oil Shale) also exhibited pronounced differences in E_a distributions. These distributions provided: (i) information on the diversity of the source materials; and (ii) reflected the occurrence of important differences in chemical structures and thermal behaviour between three of the tested kerogens, even though they are all classified as low maturity type I. The Kimmeridge Clay samples and the Lorca Oil Shale showed broad E_a distributions shifted to low energies when compared with the above algaenans and kerogens. Such shifts reflect an important (or even almost exclusive for some of these kerogens) contribution of materials originating from sulphur incorporation into various lipids during early diagenesis. Finally, the kinetic data derived for the nine low maturity fossil samples were extrapolated to a very low, geological heating rate of 3°C Ma⁻¹ and the generation rate curves and cumulative yield curves thus obtained were compared.     

CuInSe2太阳电池薄膜的制备技术及研究进展

着重介绍了CuInSe2的结构和光、电学特性；讨论了多各上薄膜沉积技术；评价了主要的合成装置及其作途；综述了制备CuInSe2太阳电池器件的工艺和材料，提出了一种能成功地生产大面积太阳电池薄膜的经济有铲的沉积技术。     

刃具斜切入破岩的试验与研究

介绍了刃具斜切入破岩的试验装置及试验结果，推导出了跃进载荷的计算公式，并对试验结果进行了理论分析，探讨了影响刃具侵入岩石难易的因素和影响破岩比功大小的因素。     

大冲击功液动锤的研究及其应用

从液动锤基础理论出发，依据理论计算公，科学建立数学模型，开发计算机软件，对液动锤内部动力过程及工作参数进行计算机模拟仿真电算，寻求大幅度提高冲击功的途径和方法。     

热幔柱的启动动力

科氏力是地球各圈层差异旋转的原因。在重力分异过程中，随着地球质量不断向地心集中，地球自转动能也不断向地核集中，从而产生圈层分化和差异旋转。     

Comparative study of activation energies of conductance and desiccation rates of some marine algae

Measurements of the activation energy of electrical conductance and desiccation rates on subtidal marine algae from Florida were compared to similar data from the Bay of Fundy, Nova Scotia, on intertidal marine algae frequently subjected to long periods of exposure to air. We have developed a method for calculating the reaction rate constant of desiccation of fully hydrated marine algae. Values of activation energies and desiccation rate constants are consistent with the requirements for survival of these algae under widely different environmental conditions.     

煤层倾角与覆岩变形破裂分带

地下采煤中三带(冒落带、裂隙带、弯曲带)高度的判断是预测采空引起地表变形破坏程度的依据。在诸多的影响因素中, 煤层倾角是控制三带高度的最主要因素。建立在实测统计基础上的经验范围值用于三带高度的判断带有一定的人为性。急倾斜煤层中冒落带和裂隙带高度随煤层倾角变化的规律已被褐示[7].通过弹塑性岩石材料的非线性有限元模拟, 本文提出了利用应力重分布图判断中、缓倾角煤层采空区覆岩三带高度的方法, 并应用于实际工程。     

Pall型摩擦阻尼支撑内力计算方法

从Pall摩擦阻尼器四连杆机构的几何非线性变形特征出发，分析框架位移、支撑刚度、阻尼器摩擦力、阻尼器大小、支撑倾角、支撑屈曲力等对一种改进的Pall摩擦阻尼器-T形芯板摩擦阻尼器支撑的受力特点，拟合出可供设计人员使用的实用计算公式。     

利用前兆事件对云南地区地震进行中短期预测研究

对某些类型的主震事件, 进行中短期预测也许是可能的. 利用Varnes, Bufe和Varnes提出的破裂时间法模拟前兆地震能量加速释放模型,通过实际观测资料与理论公式的拟合, 可以建立主地震事件的中短期预测技术, 用以确定表示主震的地点、时间和震级大小. 本文使用的是云南区域台网的地震目录资料，覆盖的时间段为1965~2002年. 统计分析表明，在此37年时间内，等于或大于2.5级地震资料是相当完整的. 本文对云南地区的30次主震事件进行了模拟，其中25次主震事件由前兆序列模拟得到的预测时间和震级与实际值相当接近，主震震级预测精度约0.57个震级单位，假定已知前兆序列中最后一次事件，则预测主震发生时间误差约0.64年.对另外的5次主震事件，由于没有足够的前兆事件来充分确定前兆能量加速曲线或是存在对能量加速释放曲线的干扰事件，而不能进行破裂时间法模拟.本文的研究结果还表明，由于云南是破坏性地震和中小地震活跃的地区，因此，主地震与前兆事件最佳搜索半径不存在明显的线性关系.主震矩与系数k，m之间存在强烈的相关性，利用主震地震矩与系数的关系和限制指数m的取值范围，可进一步缩小预测时间和预测震级的最佳拟合区范围，提高了模拟主震事件的预测精度. 本文采用破裂时间法对30次主震事件进行拟合，80％以上获得了较好的结果. 显示出该方法在预测已知主震事件序列的能力方面大有希望，因此，利用前兆事件对未来主震事件进行中短期预测的前景是令人鼓舞的.      

Comparison of Aircraft and Ground-Based FluxMeasurements during OASIS95

Aircraft and ground-based measurements made during the1995 Australian OASIS field campaign are compared. The aircraft data were recorded during low-level flightsat 6 m above ground level and grid flights at altitudes of between 15 and 65 m, allin unstable atmospheric conditions. The low-level flights revealed an inadequate temperaturesensor response time, a correction for which was determined from subsequent work ina wind tunnel. Aircraft and ground-based measurements of mean wind speed, wind directionand air temperature agree to within 0.2 m s^-1, 4° and 0.9 °C respectively.Comparisons between aircraft and ground-based observations of the standarddeviations of vertical velocity, horizontal wind speed, air temperature and specifichumidity have slopes of 0.96, 0.97, 0.92 and 0.99 respectively but the observed scatter isroughly twice the random error expected due to the averaging length of the aircraft data andthe averaging period of the ground-based data. For the low-level flights, the ground-basedand aircraft measurements of sensible and latent heat flux show mean differences of 27 and-25 W m^-2 respectively, which reduce to 11 and -4 W m^-2 respectivelywhen analysis of aircraft data is limited to areas immediately adjacent to the fluxtowers. For the flights at 15 to 65 m above ground level, the mean differences between theground-based and aircraft measurements of sensible and latent heat flux are -22 and-1 W m^-2 respectively and these change to -1 and -7 W m^-2 respectively oncethe effect of surface heterogeneity is included. Aircraft and ground-based measurementsof net radiation agree to within 6% at one ground-based site but differ by 20% at a second.Aircraft measurements of friction velocity at 6 m above the ground agree well withground-based data, but those from flights between 15 and 65 m above ground level do not.This is because at these heights the aircraft measurements provide the local shear stress,not the surface shear stress. Overall, the level of agreement allows confidence in the aircraftdata provided due care is taken of instrument response times and differences in thesurfaces sampled by aircraft and ground-based systems.