Formation of radical species in photolyzed CH4:N2 ices

We report photochemical studies of thin cryogenic ice films composed of N₂, CH₄ and CO in ratios analogous to those on the surfaces of Neptune’s largest satellite, Triton, and on Pluto. Experiments were performed using a hydrogen discharge lamp, which provides an intense source of ultraviolet light to simulate the sunlight-induced photochemistry on these icy bodies. Characterization via infrared spectroscopy showed that C₂H₆ and C₂H₂, and HCO are formed by the dissociation of CH₄ into H, CH₂ and CH₃ and the subsequent reaction of these radicals within the ice. Other radical species, such as C₂, , CN, and CNN, are observed in the visible and ultraviolet regions of the spectrum. These species imply a rich chemistry based on formation of radicals from methane and their subsequent reaction with the N₂ matrix. We discuss the implications of the formation of these radicals for the chemical evolution of Triton and Pluto. Ultimately, this work suggests that , CN, HCO, and CNN may be found in significant quantities on the surfaces of Triton and Pluto and that new observations of these objects in the appropriate wavelength regions are warranted.     

CSAMT勘探中场区、记录规则、阴影及场源复印效应的解析研究

由矢量位导出均匀大地表面上水平接地谐变电偶极子地下电磁场的闭合表达式, 将地层波和地面波显式地区分开来, 据此定义了与远区场和近区场对应的地面波区和地层波区. 对长期困扰CSAMT勘探工作者的记录点问题、阴影和场源复印效应问题给出了物理解释. 由地层波与地面波之比给出了定量划分场区的方法, 每一场分量最佳记录规则下的条件和判断是产生阴影和场源复印效应的前提. 山西沁水盆地CSAMT勘探覆盖点的推断结果表明, 阴影和场源复印效应是由地层波所携带的源与观测点之间、源下方真实地质情况的信息决定, 是可以利用的.     

几种滤波器对地面飑线场的中尺度滤波试验

本文用Ｂａｒｎｅｓ带通滤波法，二十五点格式滤波法，对含有地面幅合线和飑线的地面加密观测资料和客观分析资料进行了中尺度滤波试验，结果表明，三种滤波器的作用结果都胡有效突出地面辐合线和飑线的中尺度特征，其中Ｂａｒｎｅｓ法的性能和结果较理想，二十五点法和高阶高通法各有特点。     

青藏高原雷暴云降水与地面电场的观测和数值模拟

在2003年青藏高原那曲地区夏季雷暴云的观测试验中,三次伴有降水的过程中都出现了地面电场(Egnd)随降水的漂移现象,而且固态和液态降水对Egnd的极性改变并不相同。为了模拟再现高原雷暴云降水和Egnd之间的关系,选取了8月13日这次具有高原雷暴代表性特征的过程,模拟了雷暴云移经观测点上空期间,测站固、液态降水与Egnd的变化以及雷暴云下部正电荷区的空间分布。模拟的Egnd及固、液态降水与其的对应关系与观测事实较一致。分析结果表明,固态降水主要携带正电荷,液态降水主要携带负电荷,各类带不同极性和数量电荷的降水粒子常共存在雷暴云中,Egnd主要受携带电荷量占主导地位的降水粒子的影响,地面出现强正电场时正好是云在当顶并且地面出现强固态降水的时间。     

遥感影像时—空融合的“点”—“线”—“面”质量评价

遥感影像时—空融合可集成多源数据高空间分辨率和高时间分辨率互补优势,生成时间连续的高空间分辨率影像,在遥感影像的动态监测与时序分析等方面具有重要应用价值.然而,现有多数研究往往基于单一数据产品对时—空融合算法进行评价,而在实际生产应用中,需要验证算法在多种遥感产品数据的融合表现;此外,目前研究大多基于“单点时刻”进行评...     

浅议基于像素工厂的ADS 80影像处理技术

摄影测量进入数字时代以来,ADS80因其独特的优势逐步成为航摄影像获取的主流平台,对ADS80数据后续快速处理也成为目前数据处理软件研究的重点。本文介绍了基于像素工厂系统快速处理ADS80数据的技术流程和数据处理的主要技术环节,总结了像素工厂系统数据处理的优劣势。通过实际项目实践,验证了基于像素工厂系统处理ADS80数据的可靠性与高效性。     

Optimum size and density of surface grid arrays for retrieving accurate shear-tensile fracturing of microearthquakes

Surface arrays became an important tool for monitoring the induced seismicity in hydraulic fracturing experiments and for assessing the impact of fluid injection on the fracturing process of microearthquakes. The layout of sensors plays a key role in this task because it controls the accuracy of event locations and retrieved seismic moment tensors. We simulate various configurations of grid sensor arrays characterized by a different number of sensors, array span, sensor spacing, depth of sources and various shear/tensile source mechanisms of events. The moment tensor inversion is carried out using synthetically calculated P-wave amplitudes with added random noise. A bias in the solutions is evaluated by errors in the double-couple percentage of inverted moment tensors because the double-couple errors inform us about the sensitivity of the network to detect the shear/tensile fracturing mode of induced microearthquakes. The results show that the accuracy of the double-couple percentage is mostly controlled by the offset-to-depth ratio R defined as the ratio of half of the network size to the event depth. The optimum value of R is in the range of 0.75–1.5 irrespective of the type of the focal mechanism. If 121 (11 × 11) sensors are distributed in a regular grid and recorded data are characterized by a 10% random noise, the double-couple error is less than 6%. This error increases, if R is not optimum or if the number of sensors is reduced. However, even sparse arrays with 49 (7 × 7) or 16 (4 × 4) sensors can yield a reasonable accuracy, provided the surface grid arrays are designed to have an optimum size.     

Understanding the surface hydrology of the Lake Eyre Basin: Part 1—Rainfall

This is the first of two papers that describe the surface hydrology of the Lake Eyre Basin (LEB) (1,140,000 km²) in central Australia and compares some key characteristics with those observed from arid regions globally. This paper concentrates on annual rainfall, whereas the second paper is devoted to streamflow. The first part describes the LEB's climate (arid to semi-arid), which is dominated by a subtropical high pressure ridge stretching latitudinally across central Australia. Then follow major analyses that include the characteristics of rainfall, wet and dry spell lengths and cumulative surpluses and deficiencies, rainfall trends and intra- and inter-decadal fluctuations, and the relationship between rainfall and El Niño-Southern Oscillation (ENSO). The paper concludes with six conclusions, the key ones being: the variability of the annual rainfall (based on the coefficient of variation) in the LEB is approximately 60% greater than that found for stations located in arid regions in the rest of the world; there is a bias towards longer lengths of dry years than observed in the rest of Australia; and, there is a significant lag correlation between rainfall and ENSO, particularly in the east and in the latter part of a year.     

The Parameterisation of Scalar Transfer over Rough Ice

We test a surface renewal model that is widely used over snow and ice surfaces to calculate the scalar roughness length (z _s ), one of the key parameters in the bulk aerodynamic method. For the first time, the model is tested against observations that cover a wide range of aerodynamic roughness lengths (z ₀). During the experiments, performed in the ablation areas of the Greenland ice sheet and the Vatnajökull ice cap in Iceland, the surface varied from smooth snow to very rough hummocky ice. Over relatively smooth snow and ice with z ₀ below a threshold value of approximately 10^?3 m, the model performs well and in accord with earlier studies. However, with growing hummock size, z ₀ increases well above the threshold and the bulk aerodynamic flux becomes significantly smaller than the eddy-correlation flux (e.g. for z ₀ = 0.01 m, the bulk aerodynamic flux is about 50% smaller). Apparently, the model severely underpredicts z _s over hummocky ice. We argue that the surface renewal model does not account for the deep inhomogeneous roughness sublayer (RSL) that is generated by the hummocks. As a consequence, the homogeneous substrate ice grain cover becomes more efficiently ‘ventilated’. Calculations with an alternative model that includes the RSL and was adapted for use over hummocky ice, qualitatively confirms our observations. We suggest that, whenever exceedance of the threshold occurs (z ₀  >  10^?3 m, i.e., an ice surface covered with at least 0.3-m high hummocks), the following relation should be used to calculate scalar roughness lengths, ln (z _s /z ₀)  =  1.5  ? 0.2 ln (Re _*)  ? 0.11(ln (Re _*))².     

A Case Study of Satellite Synthetic Aperture Radar Signatures of Spatially Evolving Atmospheric Convection over the Western Atlantic Ocean

A case study of a particularly intense cold air outbreak over the northAtlantic Ocean extending from the northeast coast of the UnitedStates to the Gulf Stream is described. A RADARSAT satellite synthetic apertureradar (SAR) image of this outbreak dramatically illustrates the spatialevolution of convection. Nearly coincident images from the National Oceanic and Atmospheric Administration's Advanced Very HighResolution Radiometer are used to compare many interesting features.In addition, National Weather Service rawinsonde data, National Data Buoy Center buoy data, and Woods Hole Oceanographic Institute Coastal Mixing and Optics mooring data arepresented. We use these data to help describe the spatial evolution of the atmospheric boundary-layer processes involved in this outbreak.Rows of cellular convective clouds begin to appear some distance offshore and then slowly increase in horizontal diameter and wavelength in the downwind direction, with a subsequent jump in cloud diameter downwind of the Gulf Stream North Wall (GSNW). The SAR image shows a similar evolution of sea-surface footprints of these boundary-layer features. This change in boundary-layer structure is attributed to corresponding changes in static stability. About 300 km south of the GSNW in the SAR image, an even larger jump in cell diameter appears and the cells becomenon-uniform with bright crescents and filled semi-circles on thedownwind sides of the cells. These are believed to be surface effectsof gust fronts induced by the mesoscale cellular convection and enhanced by the overall northwesterly flow.