二维的大气CO2——大西洋碳循环模式

本文描述了一个二维（纬度×深度）的大西洋碳循环模式，模拟了大气和海洋间CO2的交换以及碳在海洋中的输送过程。模式在运行时使用了一个12层的三维动力学模拟的海洋环流的结果。大西洋被划分成397个网格箱，每个箱子中各种形式的碳的含量、总碱度、溶解的无机营养物和溶解氧的浓度以及几种14C(碳14)同位素的值分别得到求解。模式稳定状态的计算采用解大型稀疏线性方程组的直接解法。计算结果与“地球化学的海洋研究（GEOSECS）”的实际观测数据对比，表明模式较好地再现了实际大西洋中几种化学量的分布。     

Eruptive activity at Mount St Helens,Washington, USA, 1984–1988: a gas geochemistry perspective

The results from two different types of gas measurement, telemetered in situ monitoring of reducing gases on the dome and airborne measurements of sulfur dioxide emission rates in the plume by correlation spectrometry, suggest that the combination of these two methods is particularly effective in detecting periods of enhanced degassing that intermittently punctuate the normal background leakage of gaseous effluent from Mount St Helens to the atmosphere. Gas events were recorded before lava extrusion for each of the four dome-building episodes at Mount St Helens since mid-1984. For two of the episodes, precursory reducing gas peaks were detected, whereas during three of the episodes, COSPEC measurements recorded precursory degassing of sulfur dioxide. During one episode (October 1986), both reducing gas monitoring and SO₂ emission rate measurements simultaneously detected a large gas release several hours before lava extrusion. Had both types of gas measurements been operational during each of the dome-building episodes, it is thought that both would have recorded precursory signals for all four episodes. Evidence from the data presented herein suggests that increased degassing at Mount St Helens becomes detectable when fresh upward-moving magma is between 2 km and a few hundred meters below the base of the dome and between about 60 and 12 hours before the surface extrusion of lava.     

A Modeling Study of Climate Change and Its Implication for Agriculture in China Part II: The Implication of Climate Change for Agriculture in China

The potential CO2-induced impacts on the geographical shifts of wheat growth zones in China were studied from seven GCMs outputs. The wheat growth regions may move northward and westward under the condition of a doubling CO2 climate. The wheat cultivation features and variety types may also assume significant changes. Climatic warming would have a positive influence in Northeast China, but high temperature stress may be produced in some regions of central and southern China. Higher mean air temperatures during wheat growth, particularly during the reproductive stages, may increase the need for earlier-maturing and more heat-tolerant cultivars.     

A Modeling Study of Climatic Change and Its Implication for Agriculture in C

The trends and features of China’s climatic change in the past and future are analysed by applying station obser-vations and GCM simulation results. Nationally, the country has warmed by 0.3oC in annual mean air temperature and decreased by 5% in annual precipitation over 1951-1990. Regionally, temperature change has varied from a cooling of 0.3oC in Southwest China to a warming of 1.0oC in Northeast China. With the exception of South China, all regions of China have shown a declination in precipitation. Climatic change has the features of increasing remark-ably in winter temperature and decreasing obviously in summer precipitation. Under doubled CO2 concentration, climatic change in China will tend to be warmer and moister, with increases of 4.5oC in annual mean air temperature and 11% in annual precipitation on the national scale. Future climatic change will reduce the temporal and spatial differences of climatic factors.     

A sensitive method for measuring atmospheric concentrations of sulfur dioxide

A new sensitive method for measuring atmospheric concentrations of sulfur dioxide is presented. Samples are obtained using the mist chamber, which collects highly water-soluble gases with high efficiency, and concentrates them in a small volume of water. Particles are removed from the sampled air stream with a teflon filter, before it enters the mist chamber. After collection, the pH of the water is raised above pH 10 using sodium carbonate, then hydrogen peroxide (H₂O₂) is added to oxidize sulfur that may be present in the sulfur (IV) oxidation state, to sulfate. After a reaction time of at least 16 hours, the sulfate concentration is measured by ion chromatography. From the sulfate concentration, the water volume used in the mist chamber, and the volume of air sampled, the atmospheric concentration of SO₂ is computed. The method is not sensitive to other atmospheric sulfur gases such as DMS, SC₂, H₂S, COS, or MSH. The estimated overall precision of the method is 10%. The detection limit at the present stage of technique development is approximately 20 ppt (parts per trillion, or 10^-12 mol · mol^-1) for a 45 minute sampling time, with lower concentrations being detectable with lower precision.     

Spatial and temporal variations in temperate forest soil carbon dioxide during the non-growing season

In the Whitehall Forest of Georgia during the 1985-86 non-growing season soil CO₂ varied with soil depth, varied spatially at constant depth, and varied temporally with changing environmental conditions. Variations with depth in the upper 1.4 m of the soil were of greater magnitude than temporal variations and spatial differences at 30 cm depth were of lesser magnitude. Mean soil CO₂ in evergreen forest was higher (0.207 per cent) than in deciduous and mixed forest (0.157 per cent). There were no trends in soil CO₂ along hillslopes or with changes in soil texture, bulk density, moisture content, or temperature. Soil CO₂ did increase near trees possibly due to increased root densities and/or more numerous pockets of microbial activity. For CO₂ at 30 cm depth, two variables–the mean daily temperature range in the month before measurement and actual evapotranspiration in the week before measurement (AET7)–explained 76 per cent of the variation in mean soil CO₂. At the profile site, where soil CO₂ was measured at five depths, 66 per cent of the variability in CO₂ was explained by soil depth, AET7, and the average daily temperature range in the two months before measurement.     

Vertical distribution of dimethylsulfide,sulfur dioxide,aerosol ions,and radon over the Northeast Pacific Ocean

Dimethylsulfide (DMS), sulfur dioxide (SO₂), methanesulfonate (MSA), nonsea-salt sulfate (nss-SO₄ ^2–), sodium (Na⁺), ammonium (NH₄ ⁺), and nitrate (NO₃ ^–) were determined in samples collected by aircraft over the open ocean in postfrontal maritime air masses off the northwest coast of the United States (3–12 May 1985). Measurements of radon daughter concentrations and isentropic trajectory calculations suggested that these air masses had been over the Pacific for 4–8 days since leaving the Asian continent. The DMS and MSA profiles showed very similar structures, with typical concentrations of 0.3–1.2 and 0.25–0.31 nmol m^–3 (STP) respectively in the mixed layer, decreasing to 0.01–0.12 and 0.03–0.13 nmol m^–3 (STP) at 3.6 km. These low atmospheric DMS concentrations are consistent with low levels of DMS measured in the surface waters of the northeastern Pacific during the study period.The atmospheric SO₂ concentrations always increased with altitude from <0.16–0.25 to 0.44–1.31 nmol m^–3 (STP). The nonsea-salt sulfate (ns-SO₄ ^2–) concentrations decreased with altitude in the boundary layer and increased again in the free troposphere. These data suggest that, at least under the conditions prevailing during our flights, the production of SO₂ and nss-SO₄ ^2– from DMS oxidation was significant only within the boundary layer and that transport from Asia dominated the sulfur cycle in the free troposphere. The existence of a sea-salt inversion layer was reflected in the profiles of those aerosol components, e.g., Na⁺ and NO₃ ^–, which were predominantly present as coarse particles. Our results show that long-range transport at mid-tropospheric levels plays an important role in determining the chemical composition of the atmosphere even in apparently remote northern hemispheric regions.     

南沙珊瑚礁对大气CO2含量上升的响应

本文利用南沙海域的碳酸盐化学以及相关调查资料，分析了表层CaCO3饱和度的分布特征，通过碳酸盐的热力学计算模式，定量评估了未来大气CO2增加对表层CaCO3饱和度的潜在影响，利用CaCO3饱和度与珊瑚钙化速率的经验关系式，进一步预测了珊瑚礁对大气CO2上升可能产生的生物地球化学响应．初步结果显示，工业革命前至2100年，南沙海域的CaCO3饱和度将下降43％左右，从而将引起珊瑚礁的平均钙化速率减少33％．如果未来大气CO2浓度继续保持目前的上升趋势，南沙海域珊瑚礁可能会停止生长，甚至某些造礁生物面，临灭绝的危险．     

大亚湾核电站运前和运转后大鹏澳海区的二氧化碳体系

根据大亚湾核电站运输运转后对大鹏澳海区春，夏，秋，冬4季的现场调查，通过测定pH和碱度计算了大鹏澳海区二氧化碳体系各组分浓度，并比较了核电站运转前和运转后的差别，对核电站运转前和运转后的∑CO2，HCO3^-,CO^2-3和CO2与水温，盐度以及与DO和Chla的相互关系作了讨论和比较。     

The sensitivity of ECHAM4/ML to a double CO2 scenario for the Late Miocene and the comparison to terrestrial proxy data

For the Tortonian, Steppuhn et al. [Steppuhn, A., Micheels, A., Geiger, G., Mosbrugger, V., 2006. Reconstructing the Late Miocene climate and oceanic heat flux using the AGCM ECHAM4 coupled to a mixed-layer ocean model with adjusted flux correction. Palaeogeography, Palaeoclimatology, Palaeoecology, 238, 399–423] perform a model simulation which considers a generally lower palaeorography, a weaker ocean heat transport and an atmospheric CO₂ concentration of 353 ppm. The Tortonian simulation of Steppuhn et al. [Steppuhn, A., Micheels, A., Geiger, G., Mosbrugger, V., 2006. Reconstructing the Late Miocene climate and oceanic heat flux using the AGCM ECHAM4 coupled to a mixed-layer ocean model with adjusted flux correction. Palaeogeography, Palaeoclimatology, Palaeoecology, 238, 399–423] demonstrates some realistic trends: the high latitudes are warmer than today and the meridional temperature gradient is reduced. However, the Tortonian run also indicates some insufficiencies such as too cool mid-latitudes which can be due to an underestimated pCO₂ in the atmosphere. As a sensitivity study, we perform a further model experiment for which we additionally increase the atmospheric carbon dioxide (700 ppm). According to this CO₂ sensitivity experiment, we find a global warming and a globally more intense water cycle as compared to the previous Tortonian run. Particularly the high latitudes are warmer in the Tortonian CO₂ sensitivity run which leads to a lower amount of Arctic sea ice and a reduced equator-to-pole temperature difference. Our Tortonian CO₂ sensitivity study basically agrees with results from recent climate model experiments which consider an increase of CO₂ during the next century (e.g. [Cubasch, U., Meehl, G.A., Boer, G.J., Stouffer, R.J., Dix, M., Noda, A., Senior, C.A., Raper, S., Yap, K.S., 2001. Projections of Future Climate Change. In: Houghton, J.T., Y. Ding, D.J. Griggs, M. Noguer, P.J. van der Linden, X. Dai, K. Maskell, C.A. Johnson (eds.), Climate Change 2001: The Scientific Basis. Contribution of Working Group I to the Third Assessment Report of the Intergovernmental Panel on Climate Change. Cambridge University Press, Cambridge, 525–582]) suggesting that the climatic response on a higher atmospheric CO₂ concentration is almost independent from the different settings of boundary conditions (Tortonian versus today). To validate the Tortonian model simulations, we perform a quantitative comparison with terrestrial proxy data. This comparison demonstrates that the Tortonian CO₂ sensitivity experiment tends to be more realistic than the previous Tortonian simulation by Steppuhn et al. [Steppuhn, A., Micheels, A., Geiger, G., Mosbrugger, V., 2006. Reconstructing the Late Miocene climate and oceanic heat flux using the AGCM ECHAM4 coupled to a mixed-layer ocean model with adjusted flux correction. Palaeogeography, Palaeoclimatology, Palaeoecology, 238, 399–423]. However, a high carbon dioxide concentration of 700 ppm is questionable for the Late Miocene, and it cannot explain shortcomings of our Tortonian run with ‘normal’ CO₂. In order to fully understand the Late Miocene climate, further model experiments should also consider the palaeovegetation.