The role of karst in the genesis of sulfur deposits, Pre-Carpathian region, Ukraine

 Most of exogeneous epigenetic sulfur deposits are clearly associated with intensely karstified carbonate and sulfate rocks. This paper demonstrates, using the Pre-Carpathian region as an example, that karstification is one of the most important processes controlling the formation of sulfur deposits. This is determined by a coincidence of some major prerequisites of these two processes. In the Podol'sky and Bukovinsky regions the Miocene aquifer system is well drained by erosion valleys; the giant network caves known here in gypsum formed under past artesian conditions. In the region of sulfur deposits, associated with the same karstified gypsum strata, true artesian conditions still prevail. Hydrogeologic data show that abundant cavities detected in the vicinity of sulfur deposits can be interpreted as having the same origin as the fossil caves of the Podol'sky and Bukovinsky regions. The current widespread belief that the gypsum/anhydrite stratum in the region is aquifuge separating the Miocene aguifers is inadequate. This belief caused much controversy with regard to the genetic interpretations of sulfur deposits in the region. Caves formed by the upward water flow through the gypsum/anhydrite stratum govern the water exchange between the aquifers within the aquifer system. A new karst model for the formation of sulfur deposits is suggested. It agrees well with the hydrogeological features of the Miocene sequence and with biogeochemical mechanisms of sulfur origin in low-temperature diagenetic environments. Received: 16 February 1995 · Accepted: 4 June 1996     

二氧化碳洗井中相关问题的探讨

二氧化碳洗井方法具有设备简单、用时少,效果好的特点,但随着钻孔深度和孔径加大,井管材料的更新换代,有时也会难以出现壮观的井喷场面,达不到理想的洗井效果,使用范围受到限制的问题。总结多年的洗井经验,依据二氧化碳洗井原理,运用洗井过程中起动压力和用气量的计算公式,进而对洗井深度和影响用气量的因素进行了分析,结果表明:1该方法比较适用于井深300m左右、孔径Φ325mm以内、泥浆相对密度小于1.1g/cm3的新打水井,对大于300m的深井,可采用分层洗井法或压风机引喷法进行洗井。2井喷形成时的二氧化碳气体用量,与瓶内气体的压力、钻杆的下入深度、环空体积、地面管路的长度与直径、钻杆内径、钻井液的密度等成正比,而与水温、气温等成反比;当井的含水层的水柱高度低于70m时,一般不易形成井喷。3二氧化碳洗井适用于井内下入钢管、铸铁管等抗压强度较高的井。对水泥管、塑料管等强度较低的井管则要视情况具体分析。     

The public perception of carbon dioxide capture and storage in the UK: results from focus groups and a survey

Abstract

A series of meetings of two ‘Citizen Panels’ were held to explore public perceptions of off-shore carbon dioxide (CO₂) capture and storage (CCS). In addition, a face-to-face survey of 212 randomly selected individuals was conducted. We found that, on first hearing about CCS in the absence of any information on its purpose, the majority of people either do not have an opinion at all or have a somewhat negative perspective. However, when (even limited) information is provided on the role of CO₂ storage in reducing CO₂ emissions to the atmosphere, opinion shifts towards expressing slight support for the concept.

Support depends, however, upon concern about human-caused climate change, plus recognition of the need for major reductions in CO₂ emissions. It also depends upon CCS being seen as just one part of a wider strategy for achieving significant cuts in CO₂ emissions. A portfolio including renewable energy technologies, energy efficiency, and lifestyle change to reduce demand was generally favoured. CCS can be part of such a portfolio, but wind, wave, tidal, solar and energy efficiency were preferred. It was felt that uncertainties concerning the potential risks of CCS had to be better addressed and reduced; in particular the risks of accidents and leakage (including the potential environmental, ecosystem and human health impacts which might result from leakage).     

Effect of germanium dioxide on growth of Spirulina platensis

This study on the effect of different concentrations of germanium dioxide (GeO₂) on the specific growth rate (SGR), pigment contents, protein content and amino acid composition ofSpirulina platensis showed that Ge was not the essential element of this alga; that GeO₂ could speed up growth and raise protein content ofS. platensis, and could possibly influence the photosynthesis system. The concentration range of GeO₂ beneficial to growth ofS. platensis is from 5–100mg/l. GeO₂ is proposed to be utilized to remove contamination byChlorella spp. usually occurring in the cultivation ofSpirulina.     

Numerical Simulation Study on the Impacts of Tropospheric O3 and CO2 Concentration Changes on Winter Wheat.Part I: Model Description

Ozone is well documented as the air pollutant most damaging to agricultural crops and other plants.It is reported that tropospheric O3 concentration increases rapidly in recent 20 years. Evaluating and predicting impacts of ozone concentration changes on crops are drawing great attention in the scientific community. In China, main study method about this filed is controlled experiments, for example, Open Top Chambers. But numerical simulation study about impacts of ozone on crops with crop model was developed slowly, what is more, the study about combined impacts of ozone and carbon dioxide has not been reported.The improved agroecosystem model is presented to evaluate simultaneously impacts of tropospheric O3 and CO2 concentration changes on crops in the paper by integrating algorithms about impacts of ozone on photosynthesis with an existing agroecosystem biogeochemical model (named as DNDC). The main physiological processes of crop growth (phenology, leaf area index, photosynthesis, respiration, assimilated allocation and so on) in the former DNDC are kept. The algorithms about impacts of ozone on photosynthesis and winter wheat leaf are added in the modified DNDC model in order to reveal impacts of ozone and carbon dioxide on growth, development, and yield formation of winter wheat by coupling the simulation about impacts of carbon dioxide on photosynthesis of winter wheat which exists in the former DNDC. In the paper, firstly assimilate allocation algorithms and some genetic parameters (such as daily thermal time of every development stage) were modified in order that DNDC can be applicable in North China. Secondly impacts of ozone on crops were simulated with two different methods-one was impacts of ozone on light use efficiency , and the other was direct effects of ozone on leaves photosynthesis. The latter simulated results are closer to experiment measurements through comparing their simulating results. At last the method of direct impacts of ozone on leaf growth is adopted and the coe cients about impacts of ozone on leaf growth and death are ascertained. Effects of climate changes, increasing ozone, and carbon dioxide concentration on agroecosystem are tried to be simulated numerically in the study which is considered to be advanced and credible.     

CO2 output and δ13C(CO2) from Mount Etna as indicators of degassing of shallow asthenosphere

 An estimated average CO₂ output from Etna's summit craters in the range of 13±3 Mt/a has recently been determined from the measured SO₂ output and measured CO₂/SO₂ molar ratios. To this amount the CO₂ output emitted diffusely from the soil (≈ 1 Mt/a) and the amount of CO₂ dissolved in Etna's aquifers (≈ 0.25 Mt/a) must be added. Data on the solubility of CO₂ in Etnean magmas at high temperature and pressure allow the volume of magma involved in the release of such an amount of this gas to be estimated. This volume of magma (≈ 0.7 km³/a) is approximately 20 times greater than the volume of magma erupted annually during the period 1971–1995. On the basis of C-isotopic data of CO₂ collected in the Etna area and of new hypotheses on the source of Mediterranean magmas, significant contributions of CO₂ from non-magmatic sources to the total output from Etna are unlikely. Such large outputs of CO₂ and also of SO₂ from Etna could be due to an anomalously shallow asthenosphere beneath the volcano that allows a continuous escape of gases toward the surface, even without migration of magma. Received: 7 August 1996 / Accepted: 9 November 1996     

BOOK REVIEWS

Books reviewed in this article: Aerial Photography and Remote Sensing. Terrain Analysis and Remote Sensing . JOHN R. G. TOWNSHEND , ed. Environmental Data Use in Computer-assisted Data Handling Systems: The Results of a Survey of Applications in the Pacific Northwest States . KENNETH E. GORDON . Applied Land Use: A Spatial Approach . JOHN F. LOUNSBURY , LAWRENCE M. SOMMERS , AND EDWARD A. FERNALD , eds. The Second Battle of New Orleans: A History of the Vieux Carre Riverfront-Expressway Controversy . RICHARD O. BAUMBACH , JR. AND WILLIAM E. BORAH . Cultural Environmental Archaeology . MYRA SHACKLEY . The Immoral landscape: Female Prostitution in Western Societies . RICHARD SYMANSKI . life Among the Poor in Cairo . UNNI WIKAN , translated by Ann Henning. Women, Work and Property in Northwest India . URSULA SHARMA . The Domestication of Women: Discrimination in Developing Societies . BARBARA ROGERS Economic Optimization in Locational and Transport Analysis . A. G. WILSON , J. D. COELHO , S. M. MACGILL , H. C. W. L. WILLIAMS . New Tools for Economic Development: The Enterprise Zone, Development Bank, and RFC . GEORGE STERNLIEB AND DAVID LISTOKIN , eds. Regional Wage Inflation . R. L. MARTIN , ed. Finding A Place For Energy-Siting Coal Conversion Facilities . FRANK J. CALZONETTI WITH MARK S. ECKERT . Environmental Management, Resources, and Systems Environmentalism. Second Edition . T. O'RIORDAN . Countryside Conservation . BRYN GREEN . Medical Spatial Diffusion: An Historical Geography of Epidemics in an Island Community . A. D. CLIFF , P. HAGGETT , J. K. ORD , AND G. R. VERSEY . Philosophy and Geographic Thought Order and Skepticism: Human Geography and the Dialectic of Science . RICHARD SZYMANSKI AND JOHN A. AGNEW . Measurement of Subjective Phenomena . D. F. JOHNSTON , ed. Conceptions of Space in Social Thought: A Geographic Perspective . ROBERT DAVID SACK . The Association of American Geographers: The First Seventy-five Years: 1904-1979 . PRESTON E. JAMES AND GEOFFREY J. MARTIN . The Life and Thought of Isaiah Bowman . GEOFFREY J. MARTIN . Physical River Basin Planning: Theory and Practice . SURANJIT K. SAHA AND CHRISTOPHER J. BARROW , eds. Soils and landforms: An Integration of Ceomorphology and Pedology . A. I. GERRARD Climatic Change and Society. Consequences of Increasing Atmospheric Carbon Dioxide . WILLIAM W. KELLOGG AND ROBERT SCHWARE . Political Political Redistrictings and Geographic Theory . RICHARD L. MORRILL . Population Studies in Spanish American Population History: Dell Plain Latin American Studies NO. 8 . DAVID J. ROBINSON , ed. Population Redistribution in the Midwest . CURTIS C. ROSEMAN , ANDREW J. SOFRANKO , AND JAMES D. WILLIAMS , eds. Geographical Perspectives on the Elderly . A. M. WARNES , ed. Regional Perspective On the American South . MERLE BLACK AND JOHN SHELTON REED , eds. The Prairies and Plains: Prospects for the 80s . JOHN R. ROGGE , ed. Rural Rural Settlement in an Urban World . MICHAEL BUNCE . Social Accident at Three Mile Island: The Human Dimensions . DAVID L. SILLS , C. P. WOLF , AND VIVIEN B. SHELANSKI , eds. The American Small Town: Twentieth-Century Place Images . JOHN JAKLE . Urban A House of My Own . SUSAN LOBO . The City: Patterns and Processes in the Urban Ecosystem . CHRISTOPHER H. EXLINE , GARY L. PETERS , AND ROBERT P. LARKIN . Movement in Cities . P. W. DANIELS AND A. M. WARNES . Urbanization and Urban Planning in Capitalist Society . MICHAEL DEAR AND ALLEN J. SCOT , eds.     

δ34S isotope values of dissolved sulfate (SO4 2−) as a tracer for battery acid (H2SO4) contamination in groundwater

The application of sulfur isotope (³⁴S) values of sulfate in groundwater provided the information necessary to evaluate the source, transport and fate of battery acid and associated contaminants at the Gulf Coast Recycling (GCR) facility. The chemical and isotopic composition of groundwater beneath the (GCR) property, a battery recycling facility in east Tampa, Florida, varies more than expected for an area of comparable size. Sulfate (SO₄^2–) values, for example, range from 1.2 to 11,500 mg/L and oxygen and hydrogen isotopes do not attenuate towards the weighted annual mean. Those samples that are high in sulfate generally have a low pH, which immediately indicates battery acid (H₂SO₄) contamination as a potential source for the sulfate. The low pH and high reactivity of the sulfuric acid groundwater cause the formation of hydrogeological microenvironments due to preferential dissolution of carbonate minerals, which in turn causes enhanced recharge and groundwater flow in certain areas; thus, the extreme scatter in the data set. Because of the difficult hydrogeology it is not straightforward to delineate the point-sources of contamination and up to five potential scenarios have to be evaluated: (1) seawater intrusion, (2) upwelling of high-sulfate groundwater, (3) local dissolution of gypsum, (4) an up-gradient contaminant source to the northeast of the GCR property and (5) battery acid contamination.     

On the Retrieval of Volcanic Sulfur Dioxide Emissions from GOME Backscatter Measurements

We focus on the retrieval of volcanic sulfur dioxide (SO₂) emissions from an analysis of atmospheric UV backscatter spectra obtained by the Global Ozone Monitoring Experiment (GOME) spectrometer on board the ESA European Remote Sensing Satellite (ERS-2). Here, the last major eruptions of Mt. Etna on Sicily (Italy) in July/August 2001 and October/November 2002 provided an excellent opportunity to study the retrieval of SO₂ columnar amounts from ground-based, LIDAR and satellite measurements. Our study shows that the bulk of emitted SO₂ was confined in the troposphere, mainly between 700 hPa and 400 hPa which is confirmed by trajectory analysis, by LIDAR observations and AVHRR observations. The area of influence of Mt. Etna eruptions ranges from the Western Saharan Desert to Greece and the near east states and even down to the basin of Tschad, Africa. Our analysis revealed that information about the plume height of volcanic eruptions and aerosol parameters is necessary for a reliable quantitative retrieval of SO₂ from space-borne sensor data at periods perturbed by volcanic eruptions.     

Diffuse CO<Subscript>2</Subscript> degassing at Vesuvio,Italy

At Vesuvio, a significant fraction of the rising hydrothermal–volcanic fluids is subjected to a condensation and separation process producing a CO₂–rich gas phase, mainly expulsed through soil diffuse degassing from well defined areas called diffuse degassing structures (DDS), and a liquid phase that flows towards the outer part of the volcanic cone. A large amount of thermal energy is associated with the steam condensation process and subsequent cooling of the liquid phase. The total amount of volcanic–hydrothermal CO₂ discharged through diffuse degassing has been computed through a sequential Gaussian simulation (sGs) approach based on several hundred accumulation chamber measurements and, at the time of the survey, amounted to 151 t d^–1. The steam associated with the CO₂ output, computed assuming that the original H₂O/CO₂ ratio of hydrothermal fluids is preserved in fumarolic effluents, is 553 t d^–1, and the energy produced by the steam condensation and cooling of the liquid phase is 1.47×10¹² J d^–1 (17 MW). The location of the CO₂ and temperature anomalies show that most of the gas is discharged from the inner part of the crater and suggests that crater morphology and local stratigraphy exert strong control on CO₂ degassing and subsurface steam condensation. The amounts of gas and energy released by Vesuvio are comparable to those released by other volcanic degassing areas of the world and their estimates, through periodic surveys of soil CO₂ flux, can constitute a useful tool to monitor volcanic activity.Editorial responsibility: H. Shinohara