Interlaboratory comparison of cosmogenic 21Ne in quartz

We performed an interlaboratory comparison study with the aim to determine the accuracy of cosmogenic ²¹Ne measurements in quartz. CREU-1 is a natural quartz standard prepared from amalgamated vein clasts which were crushed, thoroughly mixed, and sieved into 125–250 μm and 250–500 μm size fractions. 50 aliquots of CREU-1 were analyzed by five laboratories employing six different noble gas mass spectrometers. The released gas contained a mixture of 16–30% atmospheric and 70–84% non-atmospheric (predominantly cosmogenic) ²¹Ne, defining a linear array on the ²²Ne/²⁰Ne-²¹Ne/²⁰Ne three isotope diagram with a slope of 1.108 ± 0.014. The internal reproducibility of the measurements is in good agreement with the formal analytical precision for all participating labs. The external reproducibility of the ²¹Ne concentrations between labs, however, is significantly overdispersed with respect to the reported analytical precision. We report an average reference concentration for CREU-1 of 348 ± 10 × 10⁶ at [²¹Ne]/g[SiO₂], and suggest that the 7.1% (2σ) overdispersion of our measurements may be representative of the current accuracy of cosmogenic ²¹Ne in quartz. CREU-1 was tied to CRONUS-A, which is a second reference material prepared from a sample of Antarctic sandstone. We propose a reference value of 320 ± 11 × 10⁶ at/g for CRONUS-A. The CREU-1 and CRONUS-A intercalibration materials may be used to improve the consistency of cosmogenic ²¹Ne to the level of the analytical precision.     

An inter-laboratory comparison of cosmogenic 3He and radiogenic 4He in the CRONUS-P pyroxene standard

This study reports an inter-laboratory comparison of the ³He and ⁴He concentrations measured in the pyroxene material CRONUS-P. This forms part of the CRONUS-Earth and CRONUS-EU programs, which also produced a series of natural reference materials for in situ produced ²⁶Al, ¹⁰Be, ¹⁴C, ²¹Ne and ³⁶Cl.Six laboratories (GFZ Potsdam, Caltech Pasadena, CRPG Nancy, SUERC Glasgow, BGC Berkeley, Lamont New York) participated in this intercomparison experiment, analyzing between 5 and 22 aliquots each. Intra-laboratory results yield ³He concentrations that are consistent with the reported analytical uncertainties, which suggests that ³He is homogeneous within CRONUS-P. The inter-laboratory dataset (66 determinations from the 6 different labs) is characterized by a global weighted mean of (5.02 ± 0.12) × 10⁹ at g⁻¹ with an overdispersion of 5.6% (2σ). ⁴He is characterized by a larger variability than ³He, and by an inter-lab global weighted mean of (3.60 ± 0.18) × 10¹³ at g⁻¹ (2σ) with an overdispersion of 10.4% (2σ).There are, however, some systematic differences between the six laboratories. More precisely, 2 laboratories obtained mean ³He concentrations that are about 6% higher than the clustered other 4 laboratories. This systematic bias is larger than the analytical uncertainty and not related to the CRONUS-P material (see Schaefer et al., 2015). Reasons for these inter-laboratory offsets are difficult to identify but are discussed below. To improve the precision of cosmogenic ³He dating, we suggest that future studies presenting cosmogenic ³He results also report the ³He concentration measured in the CRONUS-P material in the lab(s) used in a given study.     

《国际汉语能力标准》中值得商榷的地方——兼与《欧洲语言共同参考框架:学习、教学、评估》比较

通过对《国际汉语能力标准》的考察,同时与《欧洲语言共同参考框架:学习、教学、评估》比较,发现《国际汉语能力标准》存在三个方面的问题:结构不合理、内容有缺失以及评级等级标准不科学,以此研究结果为《国际汉语能力标准》的修订提供参考。     

OpenGIS网络地图分块服务实现标准(WMTS)分析

在充分理解OpenGIS网络地图分块服务实现标准(WMTS)1.0的基础上,通过与目前开源社区和商业应用中具有相同定位的几个规范的对比,分析了WMTS所具有的技术特点.分析表明,该规范除支持常规的分块地图服务,还在多图式、多维度、坐标系统适应性以及URL个性化等方面为一些特殊应用提供了有力支持,相应其实现的难度也相对较...     

OGC WCS系统若干关键实现技术研究

由于栅格数据种类繁多,处理过程复杂,目前还没有一种软件能为他们提供完善的WCS。研究表明,针对具体的数据源设计和实现WCS是比较好的解决方案。研究针对MODIS数据,参照OGC WCS实现规范,在充分分析WCS数据处理与服务流程的基础上,总结了WCS系统实现的技术要点,研究和探讨了系统实现中的若干关键技术问题,包括元数...     

国标图纸的分片输出

本文阐述了国标图纸分片输出的意义与方法；通过举例，ＡｕｔｏＣＡＤ用户能够容易地掌握使用本文中所述的分片输出方法，用小幅面图形输出设备绘制大幅面的工程技术图纸。     

OSL测年中CGC法求D_e均值的计算方法之比较分析

光释光测年中等效剂量是计算样品埋藏年龄的一个重要参数,一般通过求多个实验测量值的均值得出。标准生长曲线法是求等效剂量的一种常用且有效的方法,分析讨论了此法计算的等效剂量存在小幅度的系统性的偏大及其原因,提出了改进的方法;展望了CGC法求De均值更优的估计——极大似然估计。     

HJ-1A星HSI数据2级产品处理流程研究

研究了HJ-1A星HSI数据2级产品的数据预处理流程及相关算法,包括绝对辐亮度值转换、条纹去除、大气校正及几何纠正,得到了具有精确地理位置信息的地表光谱反射率图像; 基于相同位置同期的一景Hyperion数据标准化处理流程得到的地表反射率,进行了HSI数据的光谱模拟,并将模拟的地表反射率与真实HSI数据的地表反射率进行...     

锂离子选择电极的研究 Ⅲ.：开链聚醚三（二环己酰胺）锂电极的制备和应用

以合成的开链聚醚三(二环己酰胺)等中性载体制成了PVC膜Li~+电极,研究了载体结构、膜成分与电极性能的关系,在聚醚三酰胺的胺基中,以环己基取代直链的烷基,显著地改善了Li~+—载体的性能,以邻苯二甲酸二癸酯或其和二苄醚混合增塑的1,1,1—三[1′—(2′—氧杂—3′—二环己胺基羰基)丙基]丙烷Li~+—电极的线性响应范围为2×10~(-5)～10~(-1)mol/L LiCl,K_(Li+Na)~(pot)～8×10~(-3),以Mg(Ac)_2为离子强度调节缓冲剂,用标准比较法或样品加入法测定了LiCl—HCl—H_2O或LiCl—MgCl_2—HCl—H_2O体系中的Li~+,LiCl含量≥2％的样品,测定误差≤5％。