有机溶剂法结晶分离富钾卤水中钾盐的研究

选用3种有机溶剂甲醇、乙醇和丙酮作为沉析剂,以淡水浸取的东台吉乃尔盐田钾盐矿所得的富钾卤水为试验原料,进行了有机溶剂沉析结晶分离富钾卤水中钾盐的研究。研究表明3种溶剂均能分离出富钾卤水中的钾盐,其中甲醇的分离效果优于乙醇和丙酮,当甲醇与富钾卤水体积比为1.5∶1时,甲醇分离提取富钾卤水中钾离子的析出率最大为87.38%,同时结晶分离所得钾盐中钾离子的收率高达81.79%。     

Liberation-limited grade/recovery curves from X-ray micro CT analysis of feed material for the evaluation of separation efficiency

Procedures for 3D mineral liberation analysis by X-ray micro CT (XMT) are presented and discussed including the construction of liberation-limited grade/recovery curves for specific feed materials. In this way, actual separation efficiencies can be compared to what might be expected for a perfect separation limited only by the extent of liberation. It is shown that 3D mineral liberation analysis based on XMT is preferred to 2D section analysis which overestimates the extent of liberation. By way of example, procedures and experimental results are presented and discussed for feed material in the case of phosphate rock flotation.     

Air Flow Structure Over Short-gravity Breaking Water Waves

Despite its importance for momentum and mass transfer across the air–sea interface, the dynamics of airflow over breaking waves is largely unknown. To fill this gap, velocity and vorticity distributions above short-gravity breaking waves have been measured in a wind-wave tank. A Digital Particle Image velocimetry technique (DPIV) was developed to accomplish these measurements above single breaking waves, propagating in mechanically-generated wave groups and forced by the wind. By varying the wind speed and initial characteristics of the groups, the airflow structure was captured over waves at different stages of the breaking process, and breaking with various intensities. The instantaneous airflow that separates from a sharp breaking crest is very similar to that occurring over a backward facing step. The separation bubble is however strongly unsteady: the steeper the wave crest and the larger the Reynolds number based on the crest-height, the higher the separated layer and the farther downwind the reattachment point. Instantaneous flow topology displays specific features of three-dimensional separation patterns. The tangential stress above the wave profile does not exhibit spikes at reattachment but grows progressively downwind from zero at reattachment to a value at the next crest approximately that found at the upwind breaking crest. Static pressure measurements revealed that large pressure falls are generated by vortices in the separated layer, as found in separated flows over solids. This study may provide useful data for theoretical and numerical modelling of the flow and associated phenomena.     

Selective Separation and Preconcentration of Fe(III) and Zn(II) Ions by Solvent Extraction Using a New Triketone Reagent

A simple, rapid, and accurate method was developed for separation and preconcentration of trace levels of iron(III) and zinc(II) ions in environmental samples. Methyl‐2‐(4‐methoxy‐benzoyl)‐3‐(4‐methoxyphenyl)‐3‐oxopropanoylcarbamate (MMPC) has been proposed as a new complexing agent for Fe(III) and Zn(II) ions using solvent extraction prior to their determination by flame atomic absorption spectrometry (FAAS). Fe(III) and Zn(II) ions can be selectively separated from Fe(II), Pb(II), Co(II), Cu(II), Mn(II), Cr(III), Ni(II), Cd(II), Ag(I), Au(III), Pd(II), Cr(VI), and Al(III) ions in the solution by using the MMPC reagent. The analytical parameters such as pH, sample volume, shaking time, amount of MMPC reagent, volume of methyl isobutyl ketone (MIBK), effect of ionic strength, and type of back extractant were investigated. The recovery values for Fe(III) and Zn(II) ions were greater than 95% and the detection limits for Fe(III) and Zn(II) ions were 0.26 and 0.32 µg L^?1, respectively. The precision of the method as the relative standard deviation changed between 1.8 and 2.1%. Calibration curves have a determination coefficient (r²) of at least 0.997 or higher. The preconcentration factor was found to be 100. Accuracy of the method was checked by analyzing of a certified reference material and spiked samples. The developed method was applied to several matrices such as water, hair, and food samples.     

基于观测资料的云系分裂现象分析

根据中尺度地面站网、多普勒雷达和卫星云图资料,对一次云系分裂现象的成因进行了分析,结果表明:两条雨带之间的弱降水是由于云系分裂所导致的;组合反射率因子反映出北支云系以层状云为主,南支云系以对流云为主;北支云系移向是ENE,南支云系移向是E,使得两支云系逐渐分离;通过低层气压梯度力的估算,北侧为西北风,南侧为东偏南风,大体代表云系底部的移向,结合雷达得到的高低层明显的移向差异,故引起南支云系和北支云系的逐步分开;受气压梯度力和地形阻挡的作用,使得南北云系分开,成为分别独立的云系。     

N523-TBP-磺化煤油萃取体系从饱和氯化镁卤水中萃取锂的工艺研究

进行了以20%N523-30%TBP-50%磺化煤油萃取体系从青海高镁锂比盐湖卤水中萃取锂的工艺研究。根据相比实验求得萃取平衡等温线,通过阶梯图解法确定萃取理论级数为三级,并完成了三级逆流萃取串级实验。通过对洗涤、反萃、转相工艺进行的研究,确定了全流程八级萃取工艺。经此流程,锂的萃取率达96%,反萃液中杂质含量低,萃取剂经过多次循环无溶损,萃取性能良好,萃取过程分相快,未见三相及乳化现象。     

Separation of up-going and down-going wave fields of vertical cable data

The vertical cable method for acquiring and processing pre-stack 3-D marine seismic data is based on the technology developed by the US Navy for antisubmarine warfare. In order to achieve the maximum utilization of vertical cable field data, a new separation method of the up-going and down-going wave fields of the vertical cable data processing was developed in this paper, which is different from the separation of the down-going and up-going wave fields of normal VSP data processing. In tests with synthetic modeling data andactual field data, this newly developed method performs well and is also computationally simpler without pre-assumption conditions.     

时空阵列混场源电磁法理论及模拟研究

针对电磁勘探中的混场源输入条件,提出了一种时空阵列混场源电磁勘探方法.假设输入端同时包含天然电磁场源和可控人工场源,输出端进行多站同步观测;基于多输入-多输出系统的分析方法,推导了混场源条件下的时空阵列方程组.提出了系统响应的求解策略,一次性获得所有同步测道对各个场源独立激励时的响应,并分别求取了大地电磁法及可控源电磁法的各种解释参数.在此理论基础上,设计了针对性的施工方案;可控人工场源的选择形式多样,其类型、数量、激励方式及布设位置等不受限制,所有场源的激励可同时进行,无需分步;测区内各测站的布设方式灵活,可根据需要布设单分量测道或多分量测道;同时在测区外布设张量远参考站.利用数值模拟方法,论证了方法的有效性,并与常规方法进行了对比.结果表明,本方法不仅可提高人工场响应的处理精度,还具有一次野外数据采集,可同时获得天然场及人工场电磁响应结果的突出特点,进而提高采集效率,压制噪声影响;本方法集合了天然场源电磁法和人工场源电磁法的优点,为实现不同类型频率域电磁测深方法数据的统一处理提供了思路.     

一次大磁暴主相期间ENA氧与氢的分离及分布特征——TWINS卫星观测

本文采用基于ENA(Energetic Neutral Atoms)次生电子起始脉冲高度分布,统计拟合分离中能段ENA两种主要成分氢和氧的方法,研发了实现ENA氢与氧分离的TWINS卫星原始数据处理软件;其中所需要的脉高分布模型,参照已有理论公式,利用TWINS(Two Wide-angle Imaging Neutral-atom Spectrometers)卫星标定数据进行拟合确定未知参数,再加以计算得到.将上述方法用于TWINS卫星实测数据,分离得到一次大磁暴主相期间ENA-H和ENA-O微分通量随观测视线的分布及其随主相增长的变化.分析发现:(1)ENA-H与ENA-O微分通量的强度和随观测视线的分布特征都有明显差别,从某种角度反映出ENA之源的O~+与H~+离子强度和分布之间的差异;(2)接近主相极大时,ENA-H有很强的低高度发射(LAE,Low Altitude Emission),出现在磁地方时午夜前极光和亚极光纬度区,意味着该区域较强的等离子片和环电流质子沉降,进入到外层基底以下较低高度大气层;而ENA-O则未有明显LAE产生;ENA-O强通量观测视线主要穿过广大环电流区,磁地方时主要在午夜之后以及黄昏前和黎明前后;(3)在磁暴主相快速增长期,ENA-O平均总通量持续增大,而ENA-H同步减小,ENA-O与ENA-H平均总通量的比率随环电流指数Dst绝对值的增大而大致成正比增长.     

反演磁性地层界面的逐步剥离磁场法

在对前人研究方法总结对比的基础上,本文提出了一种逐步剥离位场反演磁性地层界面的方法,该方法假定位场是由一个等效单位厚度层的等效磁化强度变化引起,通过逐步剥离位场,得到等效单位厚度层的等效磁化强度,进而求取磁性地层的起伏.本文进行了理论模型计算和野外实例处理,取得了良好效果.