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71.
龙固井田为全隐蔽的华北型煤田,位于巨野煤田中部,其首采扩大区主采煤层为3号煤层。考虑3煤层顶板稳定性主要受其顶板的构造信息和岩性信息影响,因此首先依据三维地震勘探综合解释成果及波阻抗反演解释成果对二者进行定量化,然后对波阻抗数据进行归一化处理,使得波阻抗数据和量化后的构造数据具有相同的变化范围及等量贡献。在此距离范围内构造和岩性的权值各为0.5,依此生成综合因素煤层顶板稳定性隶属度。分析3煤层顶板以上10m、20m处的综合因素煤层顶板稳定性隶属度图可以发现,该区3煤层顶板稳定性比较好。且其稳定性主要是受构造因素控制,岩性因素相对影响较小。 相似文献
72.
The kinetics of the aqueous phase reactions of NO3 radicals with HCOOH/HCOO– and CH3COOH/CH3COO– have been investigated using a laser photolysis/long-path laser absorption technique. NO3 was produced via excimer laser photolysis of peroxodisulfate anions (S2O
8
2–
) at 351 nm followed by the reactions of sulfate radicals (SO
4
–
) with excess nitrate. The time-resolved detection of NO3 was achieved by long-path laser absorption at 632.8 nm. For the reactions of NO3 with formic acid (1) and formate (2) rate coefficients ofk
1=(3.3±1.0)×105 l mol–1 s–1 andk
2=(5.0±0.4)×107 l mol–1 s–1 were found atT=298 K andI=0.19 mol/l. The following Arrhenius expressions were derived:k
1(T)=(3.4±0.3)×1010 exp[–(3400±600)/T] l mol–1 s–1 andk
2(T)=(8.2±0.8)×1010 exp[–(2200±700)/T] l mol–1 s–1. The rate coefficients for the reactions of NO3 with acetic acid (3) and acetate (4) atT=298 K andI=0.19 mol/l were determined as:k
3=(1.3±0.3)×104 l mol–1 s–1 andk
4=(2.3±0.4)×106 l mol–1 s–1. The temperature dependences for these reactions are described by:k
3(T)=(4.9±0.5)×109 exp[–(3800±700)/T] l mol–1 s–1 andk
4(T)=(1.0±0.2)×1012 exp[–(3800±1200)/T] l mol–1 s–1. The differences in reactivity of the anions HCOO– and CH3COO– compared to their corresponding acids HCOOH and CH3COOH are explained by the higher reactivity of NO3 in charge transfer processes compared to H atom abstraction. From a comparison of NO3 reactions with various droplets constituents it is concluded that the reaction of NO3 with HCOO– may present a dominant loss reaction of NO3 in atmospheric droplets. 相似文献
73.
Results from numerical investigations regarding the exchange of HNO3, NH3, and NH4NO3 between the atmosphere and the biosphere are presented. The investigations were performed with a modified inferential method which is based on the generally accepted micrometeorological ideas of the transfer of momentum, sensible heat and matter near the Earth's surface and the chemical reactions among these nitrogen compounds. This modified inferential method calculates the micrometeorological quantities (such as the friction velocity and the fluxes of sensible and latent heat), the height-invariant fluxes of the composed chemically conservative trace species with group concentrationsc
1=[HNO3]+[NH4NO3] (total nitrate),c
2=[NH3]+[NH4NO3] (total ammonia), andc
3=[HNO3]-[NH3] as well as the fluxes of the individual nitrogen compounds. The parameterization of the fluxes is based on the flux-gradient relationships in the turbulent region of the atmospheric surface layer. The modified inferential method requires only the data of wind velocity, temperature, humidity and concentrations (HNO3, NH3, and NH4NO3) measured at a reference height by stations of a monitoring network. 相似文献
74.
We present a new cooled grating near infra-red spectrometer designed to acquire spectra at the TIRGO telescope in the 0.9÷2.5m region with a resolving power of 300÷4000, equipped with a Rockwell NICMOS 3 detector. 相似文献
75.
A. Hofzumahaus T. Brauers U. Platt J. Callies 《Journal of Atmospheric Chemistry》1992,15(3-4):283-298
The latitudinal variation of the photolysis frequency of ozone to O(1D) atoms, J(O1D), was measured using a filter radiometer during the cruise ANT VII/1 of the research vessel Polarstern in September/October 1988. The J(O1D) noon values exhibited a maximum of 3.6×10-5 s-1 (2 sr) at the equator and decreased strongly towards higher latitudes. J(O1D) reached highest values for clean marine background air with low aerosol load and almost cloudless sky. The J(O1D) data, measured under these conditions and a temperature of 295 K, can be expressed by: % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaamOsaiaacI% cacaqGpbWaaWbaaSqabeaaiiaacqWF8baFaaGccaqGebGaaeykaiaa% bccacqWF9aqpcaqGGaGaaeyzaiaabIhacaqGWbGaaeiiaiaabUhacq% GHsislcaaI4aGaaiOlaiaaicdacaaIYaGaeyOeI0IaaGioaiaac6ca% caaI4aGaaiiEaiaaigdacaaIWaWaaWbaaSqabeaacqGHsislcaaIZa% aaaOGaaeiiaiaabIhacaqGGaGaam4uaiabgUcaRiaaiodacaGGUaGa% aGinaiaacIhacaaIXaGaaGimamaaCaaaleqabaGaeyOeI0IaaGOnaa% aakiaadofadaahaaWcbeqaaiaaikdaaaGccaGG9bGaaeikaiaaboha% daahaaWcbeqaaiabgkHiTiaaigdaaaGccaGGPaaaaa!5EE9!\[J({\text{O}}^| {\text{D) }} = {\text{ exp \{ }} - 8.02 - 8.8x10^{ - 3} {\text{ x }}S + 3.4x10^{ - 6} S^2 \} {\text{(s}}^{ - 1} )\] where S represents the product of the overhead ozone column (DU) and the secant of the solar zenith angle. The meridional profile of the primary OH radical production rate P(OH) was calculated from the J(O1D) measurements and simultaneously recorded O3 and H2O mixing ratios. While the latitudinal distribution of J(O1D) and water vapour was nearly symmetric to the equator, high tropospheric ozone levels up to 40 ppb were observed in the Southern Hemisphere, SH, resulting in higher P(OH) in the SH. 相似文献
76.
A sequence of computer experiments is used to study questions concerning the tsunami problem as a quantitative estimate of tsunami danger, detailed geographical tsunami classification, determination of the parameters of critical tsunami waves, and the conditions of their development. We call a wave critical, if its impact on the coast is most hazardous.Using the Middle Kuril Island as an example, we present the results of a computer experiment which includes determining the wavefields on the shelf and estimating the effects connected with the deep-water Bussol and Diana Straits.Numerical simulation of tsunami waves of different sources permits the assessment of the extent of tsunami danger in different areas of the coastal zone of Simushir Island, depending on the location of the focus zone and their geometry.The major singularities of the wavefield arise in the zones of the deep-water straits. The distribution of the amplification factors is determined by both the global parameters of the wavefields and the local properties of individual harbours. The results obtained for a particular harbour in the northern part of Simushir Island, formed the basis for the quantitative estimate of tsunami danger for this area. 相似文献
77.
W. Kirchner F. Welter A. Bongartz J. Kames S. Schweighoefer U. Schurath 《Journal of Atmospheric Chemistry》1990,10(4):427-449
A liquid jet of 90 m diameter and variable length has been utilized to determine absorption rates and, hence, mass accommodation coefficients , of atmospheric trace gases. The compounds investigated are HCl (0.01), HNO3 (0.01), N2O5 (0.005), peroxyacetyl nitrate (>0.001), and HONO (0.005). It is concluded that the absorption of these trace gases by liquid atmospheric water is not significantly retarded by interfacial mass transport. The strengths and limitations of the liquid jet technique for measuring mass accommodation coefficients are explored. 相似文献
78.
This paper reviews the data concerning the fracture network and the hydraulic characteristics of faults in an active zone of the Gulf of Corinth. Pressure gap measured through fault planes shows that in this area the active normal faults (Aigion, Helike) act, at least temporarily and locally, as transversal seal. The analysis of the carbonate cements in the fractures on both the hangingwall and the footwall of the faults also suggests that they have acted as local seals during the whole fault zone evolution. However, the pressure and the characteristics of the water samples measured in the wells indicate that meteoric water circulates from the highest part of the relief to the coast, which means it goes through the fault zones. Field quantitative analysis and core studies from the AIG-10 well have been performed to define both regional and fault-related fracture networks. Then laboratory thin section observations have been done to recognize the different fault rocks characterizing the fault zone components. These two kinds of approach give information on the permeability characteristics of the fault zone. To synthesize the data, a schematic conceptual 3D fluid flow modeling has been performed taking into account fault zone permeability architecture, sedimentation, fluid flow, fault vertical offset and meteoric water influx, as well as compaction water flow. This modeling allows us to fit all the data with a model where the fault segments act as a seal whereas the relays between these segments allow for the regional flow from the Peloponnese topographic highs to the coast. 相似文献
79.
Subsurface thermal structure in Tohoku district are characterized by existing data such as geothermal resources maps, drill hole thermal gradients, Curie point depths and hypocenters distribution maps. The collected data are registered in a database system, then, compared in plan view, cross-section and bird's-eye pictures. The comparison indicates that subsurface temperatures extrapolated from drill hole thermal gradients are generally concordant to the Curie point depth, assumed to be 650 °C. Tohoku district is generally divided into 5 type areas; fore arc lowland, fore arc mountain country, Quaternary volcanic terrain, back arc lowland and back arc mountain country. The surface thermal manifestations in Quaternary volcanic terrain are mainly controlled by the magma chambers as heat sources, while, surface thermal features such as hot springs in non-volcanic areas are controlled by degrees of heat flows, and hydrothermal flows in permeable Cenozoic formations and along permeable fault zones. 相似文献
80.
The NW-trending Bucaramanga fault links, at its southern termination, with the Soapaga and Boyacá faults, which by their NW trend define an ample horsetail structure. As a result of their Neogene reactivation as reverse faults, they bound fault-related anticlines that expose the sedimentary fill of two Early Jurassic rift basins. These sediments exhibit the wedge-like geometry of rift fills related to west-facing normal faults. Their structural setting was controlled further by segmentation of the bounding faults at approximately 10 km intervals, in which each segment is separated by a transverse basement high. Isopach contours and different facies associations suggest these transverse anticlines may have separated depocenters of their adjacent subbasins, which were shaped by a slightly different subsidence history and thereby decoupled. The basin fill of the relatively narrow basin associated with the Soapaga fault is dominated by fanglomeratic successions organized in two coarsening-upward cycles. In the larger basin linked to the Boyacá fault, the sedimentary fill consists of two coarsening-upward sequences that, when fully developed, vary from floodplain to alluvial fan deposits. These Early Jurassic rift fills temporally constrain the evolution of the Bucaramanga fault, which accommodated right-lateral displacement during the early Mesozoic rift event. 相似文献