现场海水中有机污染物光学测量方法研究

介绍了一种用光学方法对海水中的有机污染物（主要包括：叶绿素-a、黄色物质、石油）进行测量的光学系统，该系统可同时测量海水中多种有机污染物的种类和浓度。     

High-resolution measurements of chromophoric dissolved organic matter in the Mississippi and Atchafalaya River plume regions

Chromophoric dissolved organic matter (CDOM) was measured in the spring and summer in the northern Gulf of Mexico with the ECOShuttle, a towed, instrumented, undulating vehicle. A submersible pump mounted on the vehicle supplied continuously flowing, uncontaminated seawater to online instruments in the shipboard laboratory and allowed discrete samples to be taken for further analysis. CDOM in the northern Gulf of Mexico was dominated by freshwater inputs from the Mississippi River through the Birdfoot region and to the west by discharge from the Atchafalaya River. CDOM was more extensively dispersed in the high-flow period in the spring but in both time periods was limited by stratification to the upper 12 m or so. Thin, subsurface CDOM maxima were observed below the plume during the highly stratified summer period but were absent in the spring. However, there was evidence of significant in situ biological production of CDOM in both seasons.The Mississippi River freshwater end member was similar in spring and summer, while the Atchafalaya end member was significantly higher in the spring. In both time periods, the Atchafalaya was significantly higher in CDOM and dissolved organic carbon (DOC) than the Mississippi presumably due to local production and exchange within the coastal wetlands along the lower Atchafalaya which are absent along the lower Mississippi. Nearshore waters may also have higher CDOM due to outwelling from coastal wetlands. High-resolution measurements allow the differentiation of various water masses and are indicative of rapidly varying (days to weeks) source waters. Highly dynamic but conservative mixing between various freshwater and marine end members apparently dominates CDOM distributions in the area with significant in situ biological inputs (bacterial degradation of phytoplankton detritus), evidence of flocculation, and minor photobleaching effects also observed. It is clear that high-resolution measurements and adaptive sampling strategies allow a more detailed examination of the processes that control CDOM distributions in river-dominated systems.     

南极中山站大气气溶胶的化学组成及其来源的判别

从1998年3月7日至1999年11月23日历时21个月，在南极中山站连续采集89个海洋气溶胶样品，本文提供全部样品的13种化学元素Cu、Pb、Zn、Cd、Fe、Al、Mn、Cr、V、K、Na、Ca、Mg含量的实测值．研究表明中山站气溶胶化学成份的含量具有季节性变化的特征．通过相关分析、因子分析、富集因子等方法判别不同时间段中山站气溶胶化学成份的来源。     

Optical properties of low molecular weight and colloidal organic matter: Application of the ultrafiltration permeation model to DOM absorption and fluorescence

Cross-flow ultrafiltration (CFF) is often used to obtain separation and concentration of colloids from bulk natural water samples. Application of the ultrafiltration permeation model allows the quantitative determination of the low molecular weight material (LMW, < 1 kDa) and colloids in bulk dissolved organic matter (DOM) from measurements of time series permeate samples obtained from CFF. Detailed analysis of a Yukon River water sample shows that DOM absorption coefficient and fluorescence follow the permeation model and that the complex spectral optical properties of LMW DOM can be reconstructed from CFF data. A combination of measured and modeled data indicates that the LMW contribution to bulk DOM optical properties obtained from CFF can be grossly underestimated by the use of a low concentration factor (CF, the ratio of initial sample volume to retentate volume). Even at a relatively high CF of 19, optical properties of LMW DOM calculated from measurements of the retentate or integrated permeate would underestimate true values by 5–36%. In the Yukon River sample, LMW dissolved organic carbon represented 26% of the bulk concentration, but only 3–14% of the colored DOM was in the LMW fraction while 31–33% of bulk DOM florescence was due to LMW DOM. The contrasting optical properties of LMW and colloidal DOM support the concept that analysis of bulk DOM absorption and fluorescence properties reveals information about DOM molecular weight.     

福建近海主要经济渔业生物营养级和有机碳含量研究

本文研究了福建近海52种鱼类、6种虾类、4种蟹类、1种虾蛄和4种头足类的食性和营养级及其有机碳含量。结果表明：营养级以鱼类最高，为2．1～3．7级，平均2．65级；头足类为2．04～2．88级，平均2．60级；蟹类2．38～2．73级，平均2．58级；虾类最低，为1．64～2．21级，平均1．96级．干样有机碳含量百分率也以鱼类最高，为33．0％～76．2％(m／m)，平均46．25％(m／m)；头足类为27．80％～46．16％(m／m),平均40．24％(m／m)；虾类为30．60％～38．40％(m／m),平均34．90％(m/m)；蟹类最低,为25．00％～30．78％(m/m)，平均28．24％(m／m),鲜样有机碳含量百分率还是以鱼类最高,为4．80％～29．55％(m／m),平均13．75％(m／m)；蟹类为8．90％～12．68％(m／m),平均10．74％(m/m)；虾类为6．97％～11．53％(m/m)，平均9．55％(m/m)；头足类最低仅为7．38％～8．52％(m／m),平均7．95％(m/m),干样有机碳含量百分率和鲜样有机碳含量百分率与营养级均成正相关，但前者的相关性高于后者。     

The Contribution of Secondary Space to Benthic Taxon Richness of a Coral Reef: Colonisation of Dendrostrea frons (Mollusca)

Abstract. The reef‐dwelling oyster Dendrostrea frons occupied only a small proportion of space in coral reefs of the Quirimba Archipelago, Mozambique, but supported a disproportionately high variety of taxa. Assemblages on primary (substratum), secondary (dead coral heads) and ephemeral secondary space (D. frons shells) of similar area were compared across 5 depths (5, 10, 15, 20 and 25 m) and at four taxonomic levels (species, genus, class and phylum). Differences between the taxonomic richness of each type of space differed with both taxonomic level considered and depth. Of the three categories of space considered, ephemeral secondary space had the most taxa at all levels with the maximum at 10 – 15 m. Despite being small in space and time, animal externa, such as shells of D. frons, may provide important niches for particular organisms at many taxonomic levels.     

胶州湾海水中颗粒有机碳含量的分布与变化

本文报道了胶州湾表层海水及C_3和D_3站中层和底层水中的颗粒有机碳(POC)的分布与变化规律。结果表明,胶州湾POC年平均浓度为155～410μg/L;平面分布有明显的规律性,近岸和河口一带的含量较高,湾中部较低,湾口诸站为最低;垂直分布有个别数值偏高或偏低现象,但没有明显的规律;季节变化较明显,初春较高,秋季较低。     

珠江口水域化学耗氧量、溶解氧、无机磷与有机磷的三维水质数学模拟

珠江沿岸城市排污量大,对污染源治理能力十分有限,大量污染物通过河流或直接排放到珠江口,河口区半封闭的地形及潮水顶托使得污染物不易输送出外海,致使珠江口水质恶化,原有海洋生态环境遭到破坏,反过来制约了经济的发展.