全文获取类型
收费全文 | 226篇 |
免费 | 37篇 |
国内免费 | 38篇 |
专业分类
测绘学 | 7篇 |
大气科学 | 9篇 |
地球物理 | 59篇 |
地质学 | 72篇 |
海洋学 | 136篇 |
天文学 | 2篇 |
综合类 | 4篇 |
自然地理 | 12篇 |
出版年
2024年 | 1篇 |
2023年 | 3篇 |
2022年 | 4篇 |
2021年 | 4篇 |
2020年 | 9篇 |
2019年 | 5篇 |
2018年 | 7篇 |
2017年 | 10篇 |
2016年 | 5篇 |
2015年 | 7篇 |
2014年 | 14篇 |
2013年 | 11篇 |
2012年 | 10篇 |
2011年 | 9篇 |
2010年 | 12篇 |
2009年 | 16篇 |
2008年 | 21篇 |
2007年 | 23篇 |
2006年 | 27篇 |
2005年 | 12篇 |
2004年 | 10篇 |
2003年 | 9篇 |
2002年 | 9篇 |
2001年 | 3篇 |
2000年 | 5篇 |
1999年 | 10篇 |
1998年 | 6篇 |
1997年 | 5篇 |
1996年 | 5篇 |
1995年 | 8篇 |
1994年 | 2篇 |
1993年 | 7篇 |
1992年 | 8篇 |
1991年 | 2篇 |
1990年 | 2篇 |
排序方式: 共有301条查询结果,搜索用时 375 毫秒
11.
I. Brandariz P. Castro M. Montes F. Penedo M.E. Sastre de Vicente 《Marine Chemistry》2006,102(3-4):291-299
Acid–base equilibrium constants of triethanolamine (TEA) have been determined by potentiometric titrations with a glass electrode, at 25 °C. Ionic strength was kept constant with only one electrolyte (using one of these salts: NaCl, KCl, MgCl2 or CaCl2), with binary mixtures of MgCl2 and CaCl2, and finally, in a solution with a composition approximately similar to that of natural seawater without sulfate. Equilibrium constants have been expressed in function of ionic strength by means of Pitzer equations and interaction parameters proposed in this theory have been obtained. It has been found that acid–base behaviour of TEA depends greatly on the salt used: basicity of TEA is decreased by CaCl2, while it is increased by the other electrolytes used in this work. 相似文献
12.
13.
14.
15.
用国家海洋局1975—1982年间在黄东海调查的海水透明度数据换算为悬浮体含量,用NOAA卫星高分辨率辐射计数据计算悬浮体含量,以绘制悬浮体含量分布图。分布图显示,研究区有三个悬浮体含量高值区,位于苏北浅滩、长江口、成山角沿岸水域。研究表明,风浪是影响悬浮体含量的海洋外部的主要因素。层化参量是影响悬浮体含量海洋内部的主要因素。 相似文献
16.
Christine S McCulloch 《Area》2006,38(1):24-33
Public participation in transparent decisionmaking has been proposed as a panacea for environmental protection. Bargaining theory suggests drawbacks to transparency such as hardening of attitudes and intransigence. Yet achievement of consensus on environmental values for integrated water resource management demands public involvement. Historical study of attempts to prevent reservoir construction in upland valleys designated for protection of nature suggests that 'closed-door' bargaining proved more effective for environmentalists than open, public debate. Records now open for analysis of disputes over Teesdale and Farndale, 1950–1970, allow comparisons to be made between behind-the-scenes deliberations and 'open-door' public discussion. The ambition of progressing from public participation to devolution of environmental decisionmaking and responsibility to the local scale demands more conceptualization of the process of decisionmaking on water resource development. 相似文献
17.
Ritta Niinioja Anna-Liisa Holopainen Liisa Lepist Anita Rm Jouko Turkka 《Limnologica》2004,34(1-2):154
Lake Pyhäjärvi, on the border between Finland and Russia in Karelia, is a very valuable clear-water lake of the Lobelia type. It belongs to the European Union's Natura 2000 programme in Finland, and has been included in regional and national monitoring programmes since the 1960s. The main monitoring station is situated near the outlet of the lake. Deterioration of its water quality was suspected already in the 1980s because of decreasing Secchi depths (transparency) and increasing chlorophyll a.The occurrence of algal blooms on the lakeshores is monitored weekly during each summer at one site on Lake Pyhäjärvi (site 1). This is a part of nationwide intensive algae monitoring programme organised by the environmental authorities together with voluntary observers at some 270 lake sites in Finland since 1998. Since 1997, Secchi depth observations have been carried out by volunteers biweekly or monthly at 17 sites on the lake. In the vicinity of one of these transparency observation sites (station 100), intensive monitoring of algae has been carried out. At this lakeshore monitoring site 69 algal observations were made, ten of which recorded algal blooms during the study period 1998–2002. The observed algal blooms were caused by algae of the Anabaena species, mainly by Anabaena lemmermannii. At Lake Pyhäjärvi the number of algal bloom observations received from the public have decreased from the 1990s to the 2000s. The range of Secchi disc transparency was 5.0–8.4 m with a mean value of 6.2 m at station 100 and 4.3–7.7 m (mean 6.1 m) at the main monitoring station 2 during the open water periods in 1998–2002. During this study period, the maximum values at site 100 seem to have increased slightly, which might indicate some improvement in the water quality due to decreased point source loading.We conclude that the intensive algal monitoring results of 5 years at the lakeshore site and the transparency results — both compiled by trained volunteers — reflect an improvement in the state of Lake Pyhäjärvi in Karelia. This conclusion is in accordance with the long-term water quality and short-core studies of sedimentary diatoms in Lake Pyhäjärvi. We suggest that the intensive algal observations and transparency measurements are both suitable methods for the monitoring of lakeshores and lakes, and that both are suitable for voluntary monitoring. We found public participation a good tool for monitoring lakes and lakeshores. 相似文献
18.
19.
Rouaida Trabelsi Moncef Zaïri Habib Smida Hamed Ben Dhia 《Comptes Rendus Geoscience》2005,337(5):515-524
The intensive agricultural and economic activities induce the increase of the risk of groundwater quality degradation through high groundwater pumping rates. The salinization and contamination are the main sources of this pollution, especially in coastal aquifers. The explanation of the origin of salinity for the shallow aquifer of Northern Sahel of Sfax was analysed by a chemical study of the groundwater main compounds. The partitioning of groundwaters into homogenous groups is undertaken by graphical techniques, including a Stiff pattern diagram, an expanded Durov diagram and several binary diagrams. The study indicates the presence of various salinization processes. In the recharge area, salinization is the result of dissolution/precipitation of the aquifer formation material (group I). The irrigation water return and the intensive pumping have been identified as major sources of salinization in the south by direct cation exchange and mixing reactions (groups II and III). The anomaly of high groundwater salinity observed near the Hazeg zone was explained by the presence of a seawater intrusion in this area. This hypothesis is related to the high chloride concentration, to the presence of inverse cation exchange reactions (group IV), and to the piezometric level inferior to sea level. To cite this article: R. Trabelsi et al., C. R. Geoscience 337 (2005). 相似文献
20.
Pasquale Crea Concetta De Stefano Demetrio Milea Silvio Sammartano 《Marine Chemistry》2008,112(3-4):142-148
The results of a potentiometric investigation (by ISE-H+, glass electrode) on the speciation of phytate ion (Phy12−) in an ionic medium simulating the major components (Na+, K+, Ca2+, Mg2+, Cl− and SO42−) of natural seawater, at different salinities and t = 25 °C, are reported. The work was particularly aimed at determining the possible formation of mixed Ca2+–Mg2+–phytate ion pairs, and to establish how including the formation of these mixed species would affect the speciation modeling in seawater media. After testing various speciation models, that considering the formation of the MgCaH3Phy5−, MgCaH4Phy4−, Mg2CaH3Phy3− and Mg2CaH4Phy2− species was accepted, and corresponding stability constants were determined at two salinities (S = 5, 10). A discussion is reported both on the choice of the experimental conditions and on the possibility to extend these results to those typical of real seawater. A detailed procedure is also described to demonstrate that the stability of these species is higher than that statistically predicted. As reported in literature, a parameter, namely log X, has been determined in order to quantify this extra stability for the formation of each mixed species at various salinities. For example, at S = 10, log X113 = 2.67 and log X114 = 1.37 for MgCaH3Phy5− and MgCaH4Phy4− (statistical value is log Xstat = 0.60), and log X213 = 6.11 and log X214 = 2.15 for Mg2CaH3Phy3− and Mg2CaH4Phy2− (log Xstat = 1.43), respectively. Results obtained also showed that the formation of these species may occur even in conditions of low salinity (i.e. low concentration of alkaline earth cations) and low pH (i.e., more protonated ligand). 相似文献