新显色剂四-（3-磺基-4-氯苯基）卟啉分光光度法测定微量铜

研究了新显色剂四-（3-磺基-4-氯苯基）卟啉在微酸性介质中,表面活性剂OP与CPC存在下测定微量铜的显色反应。络合物在波长420 nm处有最大吸收峰,摩尔吸光度系数为3．44×10^5 L·mol^-1 cm^-1,用双峰双波长光度法测定摩尔吸光系数为6．72×10^5 L·mol^-1·cm^-1,铜含量在0．5～4．5μg/25 mL范围内符合比耳定律。方法应用于矿样中微量铜的测定,结果令人满意。     

低阻油层成因分析及识别方法—以鄂尔多斯盆地盐池地区延长组长4+5段为例

近年来,低阻油层在鄂尔多斯盆地三叠系延长组不断被发现,逐渐成为主要产油层。针对鄂尔多斯盆地盐池地区长4+5低阻油层,通过岩芯观察、铸体薄片鉴定、扫描电镜观察、黏土矿物X射线衍射及高压压汞等分析测试,研究该地区长4+5低阻油层成因,认为构造圈闭幅度低、束缚水饱和度与地层水矿化均较高等是造成油层电阻率低的主要因素。利用交会图版法、电阻率差异法及计算自然电位差法3种方法,结合试油资料,对低阻油层进行定性识别。     

Organically Bound Nutrients in Dissolved Organic Matter Fractions in Seepage and Pore Water of Weakly Developed Forest Soils

Previous field and laboratory studies showed that organically bound nutrients can contribute largely to the export of N, P, and S from soil into aquatic systems. One possible determinant for the losses of dissolved organic nutrients leaving the soil environment could be their distribution between dissolved organic matter (DOM) fractions of different mobility in soil. To elucidate the potential influence of DOM fractions under varying flow conditions on the vertical translocation of organically bound nutrients, we determined the concentrations and fluxes of dissolved organic C (DOC) and nutrients (DON, DOP, DOS) in soil water under a Scots pine (Pinus sylvestris L.) and a European beech (Fagus sylvatica L.) forest. We sampled seepage water from the organic forest floor layer and the mineral subsoil using zero‐tension lysimeters and soil pore water using tension lysimeters and suction cups. DOM in soil water was fractionated into hydrophilic and hydrophobic compounds by XAD‐8 at pH 2. We found that the organic forest floor layers were large sources for DOC, DON, DOP, and DOS. The dissolved organic nutrients were mainly concentrated in the hydrophilic DOM fraction which proved to be more mobile in mineral soil pore water than the hydrophobic one. Consequently, the concentrations and fluxes of dissolved organic nutrients decreased less with depth than those of DOC. Concentrations as well as fluxes in subsoil pore water of DOC and dissolved organic nutrients in the studied weakly developed soils were high as compared with literature data on deeply developed forest soils. Under conditions of rapid water flow through the strongly structured mineral soil at the beech site, almost no retention of DOM took place and thus the influence of the distribution of organically bound nutrients between the DOM fractions on the export of DON, DOP, and DOS was negligible.     

FY-4A卫星云导风观测误差优化及同化效果影响研究

为了推进FY-4A卫星资料在数值模式中的实际应用,本研究选择云导风产品作为研究对象,首先统计了FY-4A高层水汽通道和红外通道云导风的观测误差,进一步基于WRFDA(Weather Research and Forecasting model Data Assimilation system)系统,利用默认观测误差和新...     

4D产品质量的模糊综合评价

4D产品正逐步替代传统的模拟地图,在国民经济的众多领域中得到广泛应用.相应的,其质量问题也越来越受到重视.本文讨论了4D产品质量的模糊综合评价方法,分析了模糊综合评价方法的实施过程及其特点.并以DEM产品质量的综合评价为例,建立了DEM产品质量的模糊综合评价模型.     

WEP的安全技术分析及AES的解决方案

在深入分析IEEE 802.11标准的有线等价私密（WEP）安全漏洞的基础上,提出了用高级加密算法AES代替RC4,AES提供了比RC4更高的加密性能和更加强大的安全保护,因此AES方案必将成为新一代的加密标准.     

EH4 电磁测深在江西城门山矿区深部及 外围找矿中的应用

城门山铜矿床位处九瑞铜多金属矿集区南东端,是典型的层控块状硫化物型铜矿床.利用EH4电磁测深清晰的反映地层和低阻体的展布状态,在城门山矿区取得了明显效果,并将这一成果运用到城门山矿区的深部和外围,发现了与成矿相关的电性异常,达到了评价勘探区成矿潜力的目的,也证明了EH4电磁测深对层控硫化物铜矿床是一套高效实用的勘探手段.     

皋兰山红黏土-黄土记录的上新世-更新世转型期C3/C4植被演化

上新世-更新世转型是上新世温暖气候向更新世冰期-间冰期旋回过渡的重要时段,与此同时,青藏高原的强烈隆升也深刻改变了高原及周边地区的地貌格局和生态环境面貌.因此,开展青藏高原东北缘地区上新世-更新世转型期的古气候变化是理解地球各圈层相互作用的重要切入点.而兰州盆地地处中国三大自然区的衔接位置,对气候变化和构造活动响应较为...     

青藏高原五道梁冻土活动层表面二氧化碳和甲烷的排放

通过静态箱取样方法，首次获得青藏高原冻土活动层排放气体。分析测定结果表明，ＣＨ４含量为０．６３～１．５４μｇ／ｇ，平均为１．１９μｇ／ｇ，大多数样品ＣＨ４含量低于当地大气ＣＨ４含量（１．３２μｇ／ｇ）；ＣＯ２含量为０．１５％～０．２７％，平均为０．２１％，明显高于大气ＣＯ２的浓度（０．０６９％）。ＣＨ４、ＣＯ２含量具有一定的日变化特征。ＣＨ４排放率为－０．０３２～０．０４８ｍｇｍ－２ｈ－１，平均为０．００１ｍｇｍ－２ｈ－１；ＣＯ２排放率为－５６．５０３～６１．４２５ｍｇｍ－２ｈ－１，平均为０．０９５ｍｇｍ－２ｈ１。从所获得的冻土排放气体中ＣＨ４和ＣＯ２的浓度来看，这种干燥寒冷的高原冻土活动层表面ＣＨ４排放较少，ＣＯ２的排放较高     

应用湿Q矢量诊断梅雨锋暴雨

利用湿Q矢量，结合改进的MM4（MMM4）模式模拟输的加密资料，细致地诊断分析了1991－07－05T20－06T20一次典型的江淮梅雨锋暴雨过程，结果表明：湿Q矢量散度辐合场随高度向倾斜；在梅雨锋暴雨发展，衰亡阶段，湿Q矢量散度散，合场在垂直方向上主要呈现出了相间分布的特点；从湿Q矢量散度辐合场这个角度探讨了梅雨锋暴雨的内在机理，并给出了梅雨锋暴雨具体预后的新思路。