新显色剂四-(3-磺基-4-氯苯基)卟啉分光光度法测定微量铜

研究了新显色剂四-(3-磺基-4-氯苯基)卟啉在微酸性介质中,表面活性剂OP与CPC存在下测定微量铜的显色反应。络合物在波长420 nm处有最大吸收峰,摩尔吸光度系数为3.44×105L·mol-1cm-1,用双峰双波长光度法测定摩尔吸光系数为6.72×105L·mol-1·cm-1,铜含量在0.5~4.5μg/25 m L范围内符合比耳定律。方法应用于矿样中微量铜的测定,结果令人满意。     

漂浮通量箱法和扩散模型法测定内陆水体CH_4和N_2O排放通量的初步比较研究

采用漂浮通量箱法和扩散模型法同步地观测了模拟内陆水体在不同条件下的CH4和N2O的水-气交换通量,旨在比较两类方法取得结果的异同。结果显示:这两类方法所测得的绝大多数CH4排放通量都与水中溶解氧呈显著线性负相关(显著性系数P0.001)。同时N2O排放通量与表层水温及水中铵态氮、硝态氮、溶解碳和溶解氧的关系可用包含所有上述水环境因素的Arrhenius动力学方程来表达,这些因素可以共同解释86%~90%的N2O通量变化(P0.0001),且不同方法测定的N2O通量的表观活化能和对表层水温的敏感系数分别介于47~59 kJ mol-1和1.92~2.27之间;扩散模型法所获得的CH4和N2O通量分别是箱法测定值的13%~175%和15%~240%,差异程度因模型而异;不同模型取得通量间相差20%~1200%,平均相差2.3倍。上述结果表明:仅用一种模型方法来取得CH4或N2O排放通量易形成较大偏差;不同扩散模型法和箱法测定的通量在反映CH4和N2O排放的内在规律方面具有一致性,但它们对真实气体通量的测量是否都存在不同程度的系统误差,尚需进一步研究。     

基于SaaS的区域非职业体育赛事云服务平台的设计与实现

与传统软件架构模式相比,云计算具有综合成本较低、部署快速、规模调整灵活等优势,针对区域非职业体育赛事在信息采集、组织管理、赛果处理与发布等赛事运营、组织、管理等方面存在的不足,从平台构建的可行性、架构与功能等方面,讨论并实现了一种基于SaaS模式的非职业体育赛事云服务平台,最后从使用效益等方面总结该平台对于提升区域非职业体育赛事组织与管理所取得的促进作用。     

Trophic ecology of Pomatoschistus microps within an intertidal bay (Roscoff,France), investigated through gut content and stable isotope analyses

The diet of Pomatoschistus microps has been studied using both gut content and stable isotope analyses. In the Roscoff Aber Bay (Brittany, France), this fish is commonly found on sandy muddy intertidal flats. Gut content analyses were also interpreted using trophic indices. Owing to the large diversity of prey consumed, these indices emphasised the opportunistic feeding behaviour of P. microps. Here, this species fed mainly on endofauna with meiofauna being of high relative importance. The main biotic components of its trophic habitat, characterized by δ¹³C and δ¹⁵N, provided evidence of a major trophic pathway based on drift Enteromorpha sp. Trophic positions estimated by both diet analyses and isotopic analyses led to similar results. In this bay, P. microps is a first‐order predator with a low degree of omnivory. Despite a preferential consumption of the amphipod Corophium arenarium, we assumed that this goby behaves as a generalist feeding on a uniform variety of endofauna taxa.     

南疆开都河流域夏季径流量的变化及其特征分析

利用RegCM3模式对开都河流域2000-2006年夏季气候进行模拟,结果表明:模式对于流域夏季月降水总量和月平均气温的空间分布有较好的模拟能力。结合站点海拔高度值、实测值以及模拟量分别对降水、气温进行修正,并由此计算流域的面雨量和平均温度;结果表明开都河流域夏季面雨量与开都河同期实测径流量有较好的一致性,R~2达到0.97。对开都河流域夏季平均气温、面雨量以及径流量的分析表明,降水是影响流域夏季径流量的主要影响因子;而气温对于径流呈现负贡献的原因可能由于对温度敏感的小冰川大大减少,致使径流量随着温度增加而增加的关系减弱。此外,气温升高导致流域蒸散量的提高,可能是气温呈现负贡献的又一原因。     

LA‐ICP‐MS Analysis of Small Samples: Carbonate Reference Materials and Larval Fish Otoliths

This article proposes a methodology to analyse the composition of very small carbonate samples such as larval fish otoliths. The chemical composition of otoliths, which are carbonate structures in the inner ear, is often used to explore population dynamics in fishes. Recent advances in laser ablation‐inductively coupled plasma‐mass spectrometry have suggested its potential application to this field. In this study, analyses were performed using a 193 nm ArF Resonetics LA system, coupled to an Agilent 7700X‐ICP‐MS, with the following ablation parameters: a beam diameter of 5 μm, energy of 3 mJ, 2.7 J cm^?2, laser repetition rate of 10 Hz and translation speed of 2.5 μm s^?1. NIST SRM 610 glass was used as the primary calibration material. Performing this protocol, characterisation of a USGS GP‐4 reference material was achieved with suitable precision and accuracy, but the USGS MACS‐3 reference material appeared more heterogeneous under the ablation conditions tested. Calibration was performed using two different beam diameters (5 and 11 μm). Capelin (Mallotus villosus) otoliths measuring between 10 and 20 μm in diameter were tested. Even though a smaller beam diameter and lower energy were used compared with those normally employed to analyse larger otoliths, the method was successful.     

综合物化探方法在地质找矿“攻深找盲”中的应用

物化探找矿方法面临着新形势下复杂地质条件中找矿的新挑战,单一物化探分析方法很难具有说服力,综合各种地质信息和勘探方法显得尤为重要。笔者结合河南省某矿床的找矿实践,介绍了高精度磁测、X荧光土壤分析和EH4测深等物化探综合分析方法,在工作区内发现了与成矿有关的物化探异常,经查证与地表地质现象吻合较好,说明该综合物化探评价技术方法在该矿床的应用是成功的,显示了其快速、高效和精准的特点。     

NH4Cl水溶液的微观结构和宏观物性研究

通过拉曼光谱、同步辐射X射线散射和密度泛函理论(DFT)模拟,研究了质量分数为1.0 %-28.0 %的NH₄Cl水溶液的微观结构变化。同时在室温下测量了粘度、接触角和电导率。由拉曼光谱和密度泛函理论模拟结果可知,当溶质浓度升高至10.0 %时,在2900 cm_-1^和3100 cm_-1^{附近出现了明显的}N-H作用峰,且随着质量分数的升高,NH₄Cl水溶液中的氢键类型发生了转变。X射线散射结果表明,当NH₄Cl水溶液质量分数升高至10.0 %时,差值对分布函数G(r)在2.98 ?附近出现明显双峰,表明在该浓度下溶液中NH₄₊^-Cl_-^{接触离子对开始成为主要微观作用形式。对}NH₄Cl水溶液的宏观物性研究表明,粘度、接触角和电导率均随着NH₄Cl水溶液质量分数的增加而增大。作者推断,NH₄Cl水溶液中氢键类型的转变、O-H...N键占比增多以及逐渐增加的NH₄₊^-Cl_-^{接触离子对},是粘度和接触角随溶质浓度增加而增加的微观本质因素;电导率的增加与溶液中有效导电离子数量增加有关。     

SWDC－4数字航空摄影的质量检查内容及实现手段

针对SWDC－4（ Si wei Digital Camera ）框幅式数字航空摄影的成果质量检查内容,设计了相应的航摄质量、影像质量、文档资料等成果质量检查方法。此方法在日常生产中可快速检查航摄成果质量,对外业航摄进度和内业后期数据处理具有指导意义。