Environmental significance of C/C and O/O ratios of modern land-snail shells from the southern great plains of North America

¹³C/¹²C and ¹⁸O/¹⁶O ratios of aragonite shells of modern land snails from the southern Great Plains of North America were measured for samples from twelve localities in a narrow east-west corridor that extended from the Flint Hills in North Central Oklahoma to the foothills of the Sangre de Cristo Mountains in Northern New Mexico, USA. Across the study area, shell δ¹⁸O values (PDB scale) ranged from −4.1‰ to 1.2‰, while δ¹³C values ranged from −13.2‰ to 0.0‰. δ¹⁸O values of the shell aragonite were predicted with a published, steady state, evaporative flux balance model. The predicted values differed (with one exception) by less than 1‰ from locality averages of measured δ¹⁸O values. This similarity suggests that relative humidity at the time of snail activity is an important control on the δ¹⁸O values of the aragonite and emphasizes the seasonal nature of the climatic information preserved in the shells. Correlated δ¹³C values of coexisting Vallonia and Gastrocopta suggest similar feeding habits and imply that these genera can provide information on variations in southern Great Plains plant ecology. Although there is considerable scatter, multispecies, transect average δ¹³C values of the modern aragonite shells are related to variations in the type of photosynthesis (i.e., C₃, C₄) in the local plant communities. The results of this study emphasize the desirability of obtaining isotope ratios representing averages of many shells in a locale to reduce possible biases associated with local variations among individuals, species, etc., and thus better represent the “neighborhood” scale temporal and/or spatial environmental variations of interest in studies of modern and ancient systems.     

273.15K下LiCl-Li2B4O7-H2O体系热力学性质的等压研究

用等压法研究了273 15K下LiCl-Li2B4O7-H2O体系中纯盐水溶液(离子强度范围为LiCl0 2046～2 5055mol·kg-1,Li2B4O70 1295～0 3700mol·kg-1)以及混合盐水溶液(离子强度范围为0 0931～2 4911mol·kg-1)渗透系数和水活度;计算了LiCl-Li2B4O7-H2O体系的饱和蒸汽压,获得饱和蒸汽压、渗透系数随离子强度的变化规律。用实验数据以最小二乘法求取了LiCl和Li2B4O7纯盐参数及体系的混合盐参数,拟合的标准偏差分别为0 0077和0 026。用该模型计算的渗透系数值与实验结果取得合理的一致。同时研究结果与273 15K下LiCl-Li2SO4-H2O体系的渗透系数随离子强度变化的规律作了比较。本研究对完善低温下含锂、硼盐湖卤水体系的热力学模型和盐湖资源的综合开发利用具有重要意义。     

浓硫酸钠水溶液中的离子对

不同浓度的Na2SO4水溶液的拉曼光谱显示了SO42-的四个拉曼活性带:980 cm-1处的SO42-的对称伸缩振动模式v1带,1 106 cm-1处的反对称伸缩振动模式v3带,448 cm-1处的变形振动模式v2带和617 cm-1处的变形振动模式v4带。482 cm-1处的肩膀峰是由于NaSO4-离子对的形成对448 cm-1的v2带的影响而形成的SO42-的一个新的振动峰。浓Na2SO4水溶液中,水共享离子对[Na+.H2O.SO42-]-是主要的离子对物种。随着Na2SO4水溶液浓度的增加,Na+和SO42-的相互作用增强,NaSO4-离子对所占的摩尔分数增加。     

Assessing the effects of land cover and future climate conditions on the provision of hydrological services in a medium‐sized watershed of Portugal

The separated and combined effects of land‐cover scenarios and future climate on the provision of hydrological services were evaluated in Vez watershed, northern Portugal. Soil and Water Assessment Tool was calibrated against daily discharge, sediments and nitrates, with good agreements between model predictions and field observations. Four hypothetical land‐cover scenarios were applied under current climate conditions (eucalyptus/pine, oak, agriculture/vine and low vegetation). A statistical downscaling of four General Circulation Models, bias‐corrected with ground observations, was carried out for 2021–2040 and 2041–2060, using representative concentration pathway 4.5 scenario. Also, the combined effects of future climate conditions were evaluated under eucalyptus/pine and agriculture/vine scenario. Results for land cover revealed that eucalyptus/pine scenario reduced by 7% the annual water quantity and up to 17% in the summer period. Although climate change has only a modest effect on the reduction of the total annual discharge (?7%), the effect on the water levels during summer was more pronounced, between ?15% and ?38%. This study shows that climate change can affect the provision of hydrological services by reducing dry season flows and by increasing flood risks during the wet months. Regarding the combined effects, future climate may reduce the low flows, which can be aggravated with eucalyptus/pine scenario. In turn, peak flows and soil erosion can be offset. Future climate may increase soil erosion and nitrate concentration, which can be aggravated with agriculture scenario. Results moreover emphasize the need to consider both climate and land‐cover impacts in adaptation and land management options at the watershed scale. Copyright © 2015 John Wiley & Sons, Ltd.     

Pix4Dmapper在无人机航摄应急救灾项目中的应用研究

无人机由于其独特的航摄优势,在灾害应急处理等特殊事件中,发挥着越来越重要的作用。本文结合一次山体滑坡救灾项目,阐述了使用Pix4Dmapper软件对无人机航摄数据进行快速处理,并获取正射影像图和数字表面模型的方法,通过数据分析和评估,证明了此方法的可行性和有效性。     

内蒙古老国营子金铜矿床地质-地球物理勘查与研究

内蒙古老国营子金铜矿床是近年来利用地质与地球物理相互结合手段新发现的一个矿床。本次研究利用基于电磁原理的地球物理手段进行了找矿测试,结果表明:甚低频(VLF)地球物理扫面发现了近EW向和NW向的高阻带,分别对应了两条相应的矿化蚀变带。音频大地电磁法(EH4)测深影像显示矿化蚀变带表现为高阻异常带,与VLF的测量结果相一致。激电(IP)中梯测量显示矿化蚀变带具有高阻、高充电率和高金属因子异常特征。结合具体的地质特征,在老国营子金铜矿区综合运用这三种地球物理方法,取得了较好的找矿效果。     

基于有理多项式模型的GF4卫星区域影像平差处理方法及精度验证

分析了我国首颗静止轨道光学遥感卫星高分四号(GF4)特有的区域成像模式的几何特性,基于静止轨道成像基高比较小的几何特性提出一种利用平均高程面的区域网平差方法。该方法针对GF4卫星影像构建了基于有理多项式模型RFM的区域网平差模型,并在无控制条件下,对GF4卫星区域影像进行区域网平差处理,解决了GF4号区域影像由于定轨误差、定姿误差、大气折光以及镜头畸变等因素导致的拼接精度较低的问题。最后,通过两组真实数据试验对本文方法的精度及有效性进行了验证,同时分析了采用不同的误差补偿模型对于平差结果精度的影响。     

皖南晚中生代花岗闪长岩地球化学:成岩成矿制约

皖南地区是铜、钼、金多金属成矿区,成矿与晚中生代花岗闪长岩类关系密切。近十年来,皖南花岗闪长岩的成因仍然存在分歧。本次报道了皖南花岗闪长岩全岩主、微量元素和锆石原位元素数据。皖南花岗闪长岩(Si O2=64.3%~70.8%)为高钾钙碱性、过铝质岩石,具有相似的埃达克岩特征:高Si O2、Sr/Y(17.1)和(La/Yb)N(14.9)比值,低Yb(1.72×10-6)和Y(18.4×10-6)含量。它们也具有较低Al2O3和Cr(3.40×10-6~10.0×10-6)含量、低Mg#(0.34~0.42)和Nb/Ta(9.6~13.3)值,高K2O和Ba(404×10-6)含量,高K2O/Na2O(0.89~1.55)、Th/La(0.27~0.51)和Th/U(2.79~7.49)比值。锆石原位地球化学特征显示其岩浆源区为低温(锆石Ti-in-zircon温度均值674℃)和高氧逸度(lgfO2集中在-21.4~-9.18,均值-16.4;锆石Ce4+/Ce3+平均值276)的陆壳。这些特征说明皖南花岗闪长岩可能起源于较年轻的加厚下地壳的部分熔融,并经历了斜长石、钾长石和铁镁矿物等结晶分异作用。它们可能形成于与古太平洋板块俯冲密切相关的大陆活动边缘弧至弧后拉张构造转换背景。本区大规模Cu、Mo、Au成矿作用与岩浆的高氧逸度密切相关,而锆石Ce4+/Ce3+可作为矿床勘探一个有效的指标。     

乌兰哈达变质岩地层地热勘探井钻头选择与取心工艺

内蒙古自治区察右后旗乌兰哈达苏木地热勘探井井深2006.87 m。采用石油30型钻机施工,钻遇地层大部分为变质岩,达1500 m以上,对牙轮钻头损坏严重,同时施工要求进行18次岩心采取。经过对钻头的试用、选择,最后选用HJ637G型牙轮钻头,钻进时效可达0.8～1.2 m,使用寿命可达到80～100 h。取心段采用川7-4型双管单动取心筒配合金刚石钻头,岩心采取率可达70%～95%。     

Estimation of mean and extreme waves in the East China Seas

Accurately estimating the mean and extreme wave statistics and better understanding their directional and seasonal variations are of great importance in the planning and designing of ocean and coastal engineering works. Due to the lack of long-term wave measurement data, the analysis of extreme waves is often based on the numerical wave hind-casting results. In this study, the wave climate in the East China Seas (including the Bohai Sea, the Yellow Sea and the East China Sea) for the past 35 years (1979–2013) is hind-casted using a third generation wave model – WAMC4 (Cycle 4 version of WAM model). Two sets of reanalysis wind data from NCEP (National Centers for Environmental Prediction, USA) and ECMWF (European Centre for Medium-range Weather Forecasts) are used to drive the wave model to generate the long-term wave climate. The hind-casted waves are then analysed to study the mean and extreme wave statistics in the study area. The results show that the mean wave heights decrease from south to north and from sea to land in general. The extreme wave heights with return periods of 50 and 100 years in the summer and autumn seasons are significantly higher than those in the other two seasons, mainly due to the effect of typhoon events. The mean wave heights in the winter season have the highest values, mainly due to the effect of winter monsoon winds. The comparison of extreme wave statistics from both wind fields with the field measurements at several nearshore wave observation stations shows that the extreme waves generated by the ECMWF winds are better than those generated by the NCEP winds. The comparison also shows the extreme waves in deep waters are better reproduced than those in shallow waters, which is partly attributed to the limitations of the wave model used. The results presented in this paper provide useful insight into the wave climate in the area of the East China Seas, as well as the effect of wind data resolution on the simulation of long-term waves.