半空间埋置动点源荷载问题的传递矩阵法

引用了流体饱和两相多孔介质的动力控制方程分析半空间埋置动点源荷载问题的位移和变形。经过Laplace Hankel变换 ,控制方程化成常微分方程组。利用数学软件mathmatic对上述方程组求解 ,可以得到单层砂土的传递矩阵。分析过程中 ,假设在两层面上 ,位移与应力相互连续 ,可以借鉴有限元的思想进行耦合计算。这样就获得了在饱和砂土中施加竖向动荷载问题的Laplace Hankel变换解 ,其最终的解还需要通过Laplace Hankel逆变换得到     

Analysis of Sediments and Soils by X-Ray Fluorescence Spectrometry Using Matrix Corrections Based on Fundamental Parameters

Wavelength dispersive X-ray fluorescence spectrometry (WD-XRF) is widely used for the analysis of soils and sediments using well characterised procedures. However, difficulties can occur with samples such as unknowns containing small amounts of ore materials and samples collected from contaminated sites where trace elemental concentrations can exceed the concentration range for routine analysis. We studied the performance of a commercially available method, based on fundamental parameters (FP) to correct matrix effects. The spectrometer was originally calibrated with elemental or simple compound calibrants. Samples were analysed as pressed powder pellets. Eighteen sediment and soil reference materials, three of them with certified values for some of their constituents, were used to evaluate accuracy, by comparing results with recommended values and their standard deviations (RV ± 2s) or certified values and their confidence intervals (CV ± Cl). When results fell systematically outside these intervals, calibrations were refined with geochemical reference materials. The best agreement of results with recommended and certified values was obtained when the contents of H₂O and C in each sample were included as matrix constituents during calculations. The detection limits of trace elements tended to be relatively high, because the measuring conditions employed were not maximised for sensitivity. The main advantage of the method tested was that it enabled the analysis of samples with high concentrations of trace elements and the determination of elements such as F, Bi, Sb and W, which are not commonly included in quantitative XRF analysis of geological samples.     

Triaxial stress state deep in orogenic belts: an example from Turkey

A rare metachert pebble containing amphibole grains with microboudin structures in a wide range of orientations provides an opportunity to perform stress analysis in two orthogonal orientations on the foliation surface. The sample was analysed by the microboudin method to infer the triaxial stress state during microboudinage. Stress parameters proportional to the far-field differential stress were determined for sodic amphibole grains in the two orientations. The ratio of the stresses in the two orthogonal orientations (σ₁−σ₂)/(σ₁−σ₃) was calculated to be 0.64, indicating that σ₂ lies closer to the midpoint between σ₁ and σ₃ than to σ₃.     

适用于大旋转角的三维基准转换的一种简便模型

基于大角度的空间直角坐标转换，提出了以方向余弦为参数、适用于任何角度旋转的空间直角坐标转换的简明计算方法。     

石墨炉原子吸收光谱法测定土壤样品中镉

采用磷酸氢二铵作基体改进剂塞曼扣背景石墨炉原子吸收光谱法测定土壤样品中镉，方法检出限DL=0．012μg／g，精密度RSD在3．55％～7．33％，满足了土壤样品中镉测定的镉质量要求。     

Direct Current Plasma Emission Spectrometric Determination of Major, Minor and Trace Elements in Microwave Oven Acid Leachates of Powdered Whole Coal Samples

Major concentrations of Al₂O₃, Fe₂O₃, MgO, CaO, Na₂O and K₂O, minor levels of TiO₂, P₂O₅ and thirty petrologically, geochemically and environmentally significant trace elements have been determined in microwave oven acid leachates of whole powdered coal samples by direct current plasma‐atomic emission spectrometry (DCP‐AES). A single sample preparation procedure was suitable for all the determinations with no additional dilution step for major elements solution. Dried samples (0.5 g) were treated in low‐pressure PFA digestion vessels with HF/HCl/HNO₃/HClO₄ acids to quantitatively extract the analytes from the bulk material, while leaving the major part of organic matrix as a residue. The major constituents of geological samples, in particular the easily ionised elements (EIEs) such as alkali and alkaline earths, may complicate the instrumental determinations in DCP‐AES because of differential enhancements of elemental emission intensities and stray light interferences. Taking account of these factors, the coal matrix is considered to have very low major oxide totals as compared to many other common geo‐environmental and related materials (rocks, sediments, soil, ashes etc.). The sample size employed here, while yielding a relatively concentrated solution to cover a wide range of elemental determinations, provided a sample matrix that significantly diminished interferences for DCP measurements. The need for closely matching the unknowns and calibrators was eliminated except for overall acidity and an excess quantity of caesium for EIE buffering. Calibration of the spectrometer was accomplished by simple aqueous single element solutions as high concentration calibrators in addition to a reagent blank as a low concentration calibrator. Two point working curves were established to allow for the maximum concentrations of each element expected in the unknowns. The precision of determinations under routine conditions as well as the reproducibility of the leaching and precision of instrumental measurements have been evaluated. Relative standard deviations (RSD) were of 1–2% for those elements whose concentrations in solid samples were well above the limits of quantification. Method detection limits in the buffered solutions were also evaluated. To evaluate the accuracy of the microwave oven‐DCP method a suite of eight certified coal reference materials of differing rank, were analysed with good agreement with the certified and/or available published data. Results are presented for the uncertified major oxides in the AR series reference materials.     

关于薄壁金刚石钻头胎体性能的探讨

对薄壁金刚石钻头胎体进行了性能分析和配方设计探讨，尤其根据被钻切介质对钻头胎体性能的要求作了较详细的分析，从理论分析结合实践经验筛选出了钻切建筑石材和各种钢筋砼的钻头胎体配方，在生产中满足了钻头工作条件的要求。     

Transient seepage analysis in zoned anisotropic soils based on the scaled boundary finite‐element method

The scaled boundary finite‐element method, a semi‐analytical computational scheme primarily developed for dynamic stiffness of unbounded domains, is applied to the analysis of unsteady seepage flow problems. This method is based on the finite‐element technology and gains the advantages of the boundary element method as well. Only boundary of the domain is discretized, no fundamental solution is required and singularity problems can be modeled rigorously. Anisotropic and non‐homogeneous materials satisfying similarity are modeled with no additional efforts. In this study, firstly, formulation of the method for the transient seepage flow problems is derived followed by its solution procedures. The accuracy, simplicity and applicability of the method are demonstrated via four numerical examples of transient seepage flow – three of them are available in the literature. Homogenous, non‐homogenous, isotropic and anisotropic material properties are considered to show the versatility of the technique. Excellent agreement with the finite‐element method is observed. The method out‐performs the finite‐element method in modeling singularity points. Copyright © 2014 John Wiley & Sons, Ltd.     

一种采用基础矩阵描述的核线影像生成方法

设计了一种采用基础矩阵的立体像对核线影像制作方法,由基础矩阵来描述影像间的相对方位关系,避免了相对定向过程中复杂的迭代过程。通过稀疏匹配获取高精度的同名点,由基础矩阵确定每组同名点对应的同名核线,根据核线必相交于核点的原理,采用最小二乘法确定左右影像的核点坐标;然后根据核点坐标完成影像间核线的快速映射,沿核线方向采用双线性内插法进行核线重采样,完成核线影像制作。采用多组影像进行核线影像制作实验,对生成的核线影像进行同名特征点提取与匹配,结果表明采用该方法制作的核线影像上下视差较小,验证了方法的有效性。