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61.
《Marine pollution bulletin》2014,80(1-2):188-195
A new salt resistant alkaline phosphatase from eggs of the sea urchin Strongylocentrotus intermedius (StAP) has been shown to have a unique property to hydrolyze substrate in seawater without loss of enzymatic activity. The enzyme has pH optimum at 8.0–8.5. Model experiments showed various concentrations of copper, zinc, cadmium and lead added to seawater or a standard buffer mixture to inhibit completely the enzyme activity at the concentrations of 15–150 μg/l. StAP sensitivity to the presence in seawater of metals, pesticides, detergents and oil products appears to be considerably less. Samples of seawater taken from aquatic areas of the Troitsy Bay of the Peter the Great Bay, Japan Sea have been shown to inhibit the enzyme activity; the same was shown for the samples of fresh waters. The phosphatase inhibition assay developed proved to be highly sensitive, technically easy-to use allowing to test a great number of samples. 相似文献
62.
Josi R. Taylor Andrew P. DeVogelaere Erica J. Burton Oren Frey Lonny Lundsten Linda A. Kuhnz P.J. Whaling Christopher Lovera Kurt R. Buck James P. Barry 《Marine pollution bulletin》2014
Carrying assorted cargo and covered with paints of varying toxicity, lost intermodal containers may take centuries to degrade on the deep seafloor. In June 2004, scientists from Monterey Bay Aquarium Research Institute (MBARI) discovered a recently lost container during a Remotely Operated Vehicle (ROV) dive on a sediment-covered seabed at 1281 m depth in Monterey Bay National Marine Sanctuary (MBNMS). The site was revisited by ROV in March 2011. Analyses of sediment samples and high-definition video indicate that faunal assemblages on the container’s exterior and the seabed within 10 m of the container differed significantly from those up to 500 m. The container surface provides hard substratum for colonization by taxa typically found in rocky habitats. However, some key taxa that dominate rocky areas were absent or rare on the container, perhaps related to its potential toxicity or limited time for colonization and growth. Ecological effects appear to be restricted to the container surface and the benthos within ∼10 m. 相似文献
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Saed Khayat Peter Möller Stefan Geyer Amer Marei Christian Siebert Fayez Abu Hilo 《Environmental Geology》2009,57(8):1739-1751
The spatial and temporal changes of the composition of the groundwater from the springs along the Wadi Qilt stream running
from the Jerusalem–Ramallah Mountains towards the Jericho Plain is studied during the hydrological year 2006/2007. The residence
time and the intensity of recharge play an important role in controlling the chemical composition of spring water which mainly
depends on distance from the main recharge area. A very important factor is the oxidation of organics derived from sewage
and garbage resulting in variable dissolved CO2 and associated HCO3
− concentration. High CO2 yields lower pH values and thus under-saturation with respect to calcite and dolomite. Low CO2 concentrations result in over-saturation. Only at the beginning and at the end of the rainy season calcite saturation is
achieved. The degradation of dissolved organic matter is a major source for increasing water hardness. Besides dissolution
of carbonates dissolved species such as nitrate, chloride, and sulfate are leached from soil and aquifer rocks together with
only small amounts of Mg. Mg not only originates from carbonates but also from Mg–Cl waters are leached from aquifer rocks.
Leaching of Mg–Cl brines is particularly high at the beginning of the winter season and lowest at its end. Two zones of recharge
are distinguishable. Zone 1 represented by Ein Fara and Ein Qilt is fed directly through the infiltration of meteoric water
and surface runoff from the mountains along the eastern mountain slopes with little groundwater residence time and high flow
rate. The second zone is near the western border of Jericho at the foothills, which is mainly fed by the under-groundwater
flow from the eastern slopes with low surface infiltration rate. This zone shows higher groundwater residence time and slower
flow rate than zone 1. Groundwater residence time and the flow rate within the aquifer systems are controlled by the geological
structure of the aquifer, the amount of active recharge to the aquifer, and the recharge mechanism. The results of this study
may be useful in increasing the efficiency of freshwater exploitation in the region. Some precautions, however, should be
taken in future plans of artificial recharge of the aquifers or surface-water harvesting in the Wadi. Because of evaporation
and associated groundwater deterioration, the runoff water should be artificially infiltrated in zones of Wadis with high
storage capacity of aquifers. Natural infiltration along the Wadis lead to evaporation losses and less quality of groundwater. 相似文献
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Magnetic susceptibility is a non‐conventional way that can be used for evaluating proxy soil heavy metals pollution. The paper monitors available heavy metals (Cu, Fe, Zn, and Mn) present in cultivated soils around iron–steel plant by soil magnetic susceptibility. Our study was located in an area with high pollution with small grid density of 250 m in China. Results showed that low field magnetic susceptibility was significantly correlated with available Cu, Zn, and Mn. No clear association exists between magnetic susceptibility and available Fe, soil organic matter, pH. Frequency dependent susceptibility >5% suggests the possible presence of super‐paramagnetic particles, fly ashes produced during coal combustion. 相似文献
69.
Dan Hammarlund Anson W. Mackay David M. J. Fallon Gemma Pateman Luisa C. Tavio Melanie J. Leng Neil L. Rose 《Journal of Paleolimnology》2008,39(4):463-475
Detailed stratigraphic analyses of sediments deposited in Lake Botjärnen, a small boreal forest lake in the shield terrain of central Sweden, clearly reflect progressively increasing human impact on terrestrial and aquatic ecosystems following settlement and establishment of an iron industry in the 17th century. Rising frequencies of pollen and spores from light-demanding plants provide evidence of extensive forest clearance for charcoal and timber production, which peaked in the early 20th century. An associated increase in catchment erosion is reflected by changing carbon and nitrogen elemental content and carbon–isotope composition of sediment organic matter and by increased magnetic susceptibility of the sediments. Records of air-borne pollutants (lead, zinc and sulphur) can be correlated to the development of local and regional mining and metal industry as inferred from historical accounts. Rapid recession of the iron industry led to re-forestation and recovery of the aquatic nutrient status to pre-industrial conditions over the past 100 years. The chronology of the sediment succession, which is based on 210Pb and 137Cs radionuclide data in combination with radiocarbon dating, is confirmed by historical lead pollution trends established for the region. 相似文献
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