福鼎山后尖玄武岩筒地质特征及其形成机制探讨

福鼎山后尖玄武岩位于福鼎一福清北东向断裂带北东段,呈岩筒状产于石帽山群下组下段火山沉积岩中,属钠质碱性玄武岩系列,由玄武质火山角砾岩、碧玄岩、橄榄辉长一玄武岩组合,经历火山爆发、喷溢、次火山侵入3个阶段而形成。     

Rate constants for the reactions of the NO3 radical with HCOOH/HCOO− and CH3COOH/CH3COO− in aqueous solution between 278 and 328 K

The kinetics of the aqueous phase reactions of NO₃ radicals with HCOOH/HCOO^– and CH₃COOH/CH₃COO^– have been investigated using a laser photolysis/long-path laser absorption technique. NO₃ was produced via excimer laser photolysis of peroxodisulfate anions (S₂O ₈ ^2– ) at 351 nm followed by the reactions of sulfate radicals (SO ₄ ^– ) with excess nitrate. The time-resolved detection of NO₃ was achieved by long-path laser absorption at 632.8 nm. For the reactions of NO₃ with formic acid (1) and formate (2) rate coefficients ofk ₁=(3.3±1.0)×10⁵ l mol^–1 s^–1 andk ₂=(5.0±0.4)×10⁷ l mol^–1 s^–1 were found atT=298 K andI=0.19 mol/l. The following Arrhenius expressions were derived:k ₁(T)=(3.4±0.3)×10¹⁰ exp[–(3400±600)/T] l mol^–1 s^–1 andk ₂(T)=(8.2±0.8)×10¹⁰ exp[–(2200±700)/T] l mol^–1 s^–1. The rate coefficients for the reactions of NO₃ with acetic acid (3) and acetate (4) atT=298 K andI=0.19 mol/l were determined as:k ₃=(1.3±0.3)×10⁴ l mol^–1 s^–1 andk ₄=(2.3±0.4)×10⁶ l mol^–1 s^–1. The temperature dependences for these reactions are described by:k ₃(T)=(4.9±0.5)×10⁹ exp[–(3800±700)/T] l mol^–1 s^–1 andk ₄(T)=(1.0±0.2)×10¹² exp[–(3800±1200)/T] l mol^–1 s^–1. The differences in reactivity of the anions HCOO^– and CH₃COO^– compared to their corresponding acids HCOOH and CH₃COOH are explained by the higher reactivity of NO₃ in charge transfer processes compared to H atom abstraction. From a comparison of NO₃ reactions with various droplets constituents it is concluded that the reaction of NO₃ with HCOO^– may present a dominant loss reaction of NO₃ in atmospheric droplets.     

重视和加强岩矿物性的测量研究

本文从物探科学技术的进步,勘查任务的发展变化、物探方法应用范畴的扩大和物性勘探等几个方面,论述了岩石和矿物物理性质测量、研究的重要性,指出：物性工作不可能毕其功于一役,并提出了五点建议：１．深入研究各类矿藏及其围岩（直至地面）物性的空间变化规律,为选择、研究合适的物探方法,提高物探效果,进一步探讨“直接”找矿问题,提供依据;２．这项工作可专门进行,但最好尽可能利用为其他目的而设计的钻井进行;３．物     

Quartz deformation mechanisms during Barrovian metamorphism: Implications from crystallographic orientation of different generations of quartz in pelites

The behaviour of quartz during metamorphism is studied based on two case studies from the Barrovian terrains of Sulitjelma in arctic Scandinavia and Loch Tay in the Central Highlands Dalradian of Scotland. Both terrains preserve evidence for metamorphism in pelites involving nucleation and growth of garnet at different times in the deformation history. Data are presented on the size, shape and crystallographic orientation of quartz preserved as inclusions in garnet and as grains in the surrounding matrix. While quartz-grains remain small and dispersed between mica grains, deformation appears to be dominated by grain-boundary sliding accommodated by dissolution–precipitation. At amphibolite facies, textural coarsening occurs by dissolution of small quartz grains and growth of larger quartz grains, coupled with segregation of quartz from mica. As a result, quartz deforms by dislocation creep, developing crystallographic preferred orientations (CPO) consistent with both coaxial and non-coaxial strain. Quartz CPOs with <0001> axes lying parallel to foliation and stretching direction are commonly developed, and best explained by mechanical rotation of inequant (detrital?) quartz grains. There is no evidence for selective entrapment of quartz inclusions in garnet on the basis of quartz crystallographic orientation.     

Flotation and depression control of arsenopyrite through pH and pulp redox potential using xanthate as the collector

The role of pH and pulp redox potential (E_H) to control the flotation and depression of arsenopyrite has been investigated through studies on microflotation of arsenopyrite crystals and batch flotation of an arsenopyritic ore using isopropyl xanthate as collector. The transition between flotation and depression of arsenopyrite is established by the reversible potential of the xanthate/dixanthogen couple. Adsorption of arsenate ions on ferric hydroxide has been studied through electrokinetics to delineate mechanisms involved in the depression of arsenopyrite using oxidants. Chemical binding between arsenate species and ferric hydroxide sites on arsenopyrite is suggested as the mechanism responsible for depression of arsenopyrite. E_H conditions are given for the flotation and depression of arsenopyite at various pH values for the arsenopyritic ore.     

Flow and form in rehabilitation of large-river ecosystems: An example from the Lower Missouri River

On large, intensively engineered rivers like the Lower Missouri, the template of the physical habitat is determined by the nearly independent interaction of channel form and flow regime. We evaluated the interaction between flow and form by modeling four combinations of modern and historical channel form and modern and historical flow regimes. The analysis used shallow, slow water (shallow-water habitat, SWH, defined as depths between 0 and 1.5 m, and current velocities between 0 and 0.75 m/s) as an indicator of habitat that has been lost on many intensively engineered rivers and one that is thought to be especially important in rearing of young fishes. Two-dimensional hydrodynamic models for modern and historical channels of the Lower Missouri River at Hermann, Missouri, indicate substantial differences between the two channels in total availability and spatial characteristics of SWH. In the modern channel, SWH is maximized at extremely low flows and in overbank flows, whereas the historical channel had substantially more SWH at all discharges and SWH increased with increasing discharge. The historical channel form produced 3–7 times the SWH area of the modern channel regardless of flow regime. The effect of flow regime is evident in increased within-year SWH variability with the natural flow regime, including significant seasonal peaks of SWH associated with spring flooding. Comparison with other reaches along the Lower Missouri River indicates that a) channel form is the dominant control of the availability of habitat even in reaches where the hydrograph is more intensively altered, and b) rehabilitation projects that move toward the historical condition can be successful in increasing topographic diversity and thereby decreasing sensitivity of the availability of habitat to flow regime. The relative efficacy of managing flow and form in creating SWH is useful information toward achieving socially acceptable rehabilitation of the ecosystem in large river systems.     

1999年杭嘉湖平原一次连续暴雨过程诊断分析

用新的曲面拟合法(NMOCSF)对江淮和杭嘉湖平原一次连续暴雨过程作物理诊断，结合天气形势讨论了准静止华北高压的形成及其对江淮和杭嘉湖平原连续暴雨的贡献。指出，当江淮和杭嘉湖平原处在梅雨期时，应特别注意华北高压的强度和位置，一旦构成阻塞形势，就极可能发生大范围、持续性的强降水过程。     

The geological and geodynamic evolution of the eastern Black Sea basin: insights from 2-D and 3-D tectonic modelling

Subsidence mechanisms that may have controlled the evolution of the eastern Black Sea have been studied and simulated using a numerical model that integrates structural, thermal, isostatic and surface processes in both two- (2-D) and three-dimensions (3-D). The model enables the forward modelling of extensional basin evolution followed by deformation due to subsequent extensional and compressional events. Seismic data show that the eastern Black Sea has evolved via a sequence of interrelated tectonic events that began with early Tertiary rifting followed by several phases of compression, mainly confined to the edges of the basin. A large magnitude (approximately 12 km) of regional subsidence also occurred in the central basin throughout the Tertiary. Models that simulate the magnitude of observed fault controlled extension (β=1.13) do not reproduce the total depth of the basin. Similarly, the modelling of compressional deformation around the edges of the basin does little to enhance subsidence in the central basin. A modelling approach that quantifies lithosphere extension according to the amount of observed crustal thinning and thickening across the basin provides the closest match to overall subsidence. The modelling also shows that deep crustal and mantle–lithosphere processes can significantly influence the rate and magnitude of syn- to post-rift subsidence and shows that such mechanisms may have played an important role in forming the anomalously thin syn-rift and thick Miocene–Quaternary sequences observed in the basin. It is also suggested that extension of a 40–45 km thick pre-rift crust is required to generate the observed magnitude of total subsidence when considering a realistic bathymetry.     

Ground deformation of the southern sector of the Aeolian islands volcanic arc from geodetic data

The deformation pattern and the dynamics of the southern sector of the Aeolian archipelago are investigated. A study on the ground deformation, measured over the last 20 years in the trilateration geodetic network between the islands of Vulcano and Lipari, has been conducted. Analysis of the relative displacements and the uniform strain tensor parameters, as well as the comparison between areal dilatation and the vertical variations deduced by precise levelling, allow distinguishing different phases associated both with the regional dynamics and the local volcanic context of the area. These phases, however, appear to be closely interrelated. The analysis of the deformation pattern allows to constrain the predominance of a roughly E–W trending extension and a N–S contraction at a regional scale. This regime is consistent with right-lateral movements along a NW–SE striking fault system.