底部边界层颗粒态物质迁移特征的放射性核素分析方法

利用颗粒态放射性核素携带的颗粒物历经过程信息,我们提出用泥沙扩散方程和颗粒态放射性核素扩散方程联解底部边界层颗粒态物质迁移参数的方法。分析实例的样品取自荷兰Waden Sea南部Balgzand潮滩(砂坪)和Mok湾潮滩(泥坪)的两个站位(BG1和Mok2)。示踪核素为~(234)Th,~(210)Pb和~(137)Cs,其放射性比度由r能谱测出。     

汞气测量在东安线江冲锑矿普查中的应用

Hg常与Cu,Pb,Zn,Sb等元素共生，因此在锑矿体周围多形成气晕。汞的气体晕穿透力极强，是覆盖区隐伏矿的重要找矿标志。线江冲锑矿区圈出4个汞气异常带：I号异常带长10000m，宽100－200m 异常值一般500－10000ng/m^3，最高＞499969ng/m^3，连续性好；Ⅱ号异常带长1000m ，宽100－200m，异常值与Ⅰ号异常带相同，较好地反映了②、③号矿脉的空间展布；Ⅲ号异常带长800m，宽100－280m，其展布与断 裂的展布吻合；Ⅳ号异常带是F1断裂的反映。分析类比表明，1号异常带是含矿断裂的反映，经工程验证，新发现了⑤号矿脉。     

Sources of pollution and distribution of Pb,Cd and Hg in Wrocław soils: Insight from chemical and Pb isotope composition

Human activities in cities affect properties of urban soils. In particular, urban soils often contain high contents of harmful metals even in deeper horizons added to them from diverse sources over centuries of the city development. This is reflected in complex distribution of metals in bulk soils with depth and the complex metal fractionation, but the exact sources of the metals are difficult to identify. This is also the situation in soils from Wroclaw, one of the largest cities in Poland. Potentially harmful elements Pb, Cd and Hg were examined in six profiles located along the major communication route and compared to two non-urban soils profiles located close to the same route. In all of the urban profiles, Pb and Cd exceeded the element contents observed in non-urban profiles and showed an erratic distribution compared to the more predictable one in non-urban soils. The differences between urban and non-urban profiles were explained as the result of contamination coming from more pollution sources in the case of urban soils, the conclusion supported by Pb isotope analyses. In fact, Pb isotopes showed that the contamination sources in urban soils included leaded petrol, coal combustion, smelting and possibly old pre-industrial ore processing, whereas leaded petrol and pre-industrial lead were the only possible anthropogenic sources in non-urban soils. The comparison of Wrocöaw soils with those from cities of comparable size Kraków and Poznań show similar ranges of metal contents with implication that urban pollution oversteps diverse geogenic chemical background. On the other hand, the comparison with other European cities show large variability in metal contents and suggest that urban soils contamination is time integrated and reflects long-term industrial evolution of each country.     

Phase Composition of Flood Sediments of the German-Polish Odra River Immediately after the Flood Event in 1997

Immediately after the flood event in summer 1997 at the Odra river, samples of flood sediments were taken for a complex phase analysis. The realized investigations show that the sampled flood sediments are very inhomogeneous. The main reasons for this substantial condition are surely different states of flow during the flood event. It is possible to characterize the investigated material as middle to fine sands with variable phase compositions. The mineral content of the fraction <2 μm shows a complex composition of amorphous matter, quartz, feldspars, and a different composed clay mineral matter. A high distribution of several mixed layers in the clay mineral phase is detectable. Within the scope of the taken analyses the following minerals were detected: kaolinite (disordered), kaolinite/smectite-mixed layer, chlorite/smectite-mixed layer, montmorillonite, illite/smectite-mixed layer, celadonite. The investigation of the heavy fraction shows heavy minerals and heavy particles of different geneses. Mainly these are geogenic, transparent heavy minerals like zircon, amphibole, garnet, pyroxene, apatite, rutile, and epidote. Furthermore there were analysed geogenic, opaque heavy minerals (magnetite and ilmenite), anthropogenic, opaque heavy particles (fly ashes and slags), and biogenic components (pyrite framboids). The substantial character of the investigated flood sediments (e.g. content of organic matter, content of clay minerals) shows that this material is able to act as a fixation medium of contaminants.     

Air Pollution Transport in an Alpine Valley: Results From Airborne and Ground-Based Observations

An observational dataset from a wintertime field campaign in the Inn Valley, Austria, is analysed in order to study mechanisms of air pollution transport in an Alpine valley. The results illustrate three types of mechanisms: transport by a density current, back-and-forth transport by valley winds, and transport by slope winds. The first type is associated with an air mass difference along the valley. Cooler air located in the lower part of the valley behaves like a density current and produces the advection of pollutants by upvalley winds. In the second type, strong horizontal gradients in pollution concentrations exist close to ground. Multiple wind reversals result in a back-and-forth transport of pollutants by weak valley winds. In the third type, upslope winds during daytime decrease low-level pollution concentrations and cause the formation of elevated pollution layers.     

Mercury partition in the interface between a contaminated lagoon and the ocean: The role of particulate load and composition

After having estimated the patterns of flow to the ocean and found some seasonal and tidal differences, mainly with regard to the relative importance of dissolved and particulate fractions, mercury partitioning at the interface between a contaminated lagoon and the Atlantic Ocean was investigated during four tidal cycles in contrasting season and tidal regimes. Mercury was found to be located predominantely in the particulate fraction throughout the year, contributing to its retention within the system. Seasonal conditions, variations in marine and fluvial signals and processes affecting bed sediment resuspension influenced the character and concentration of suspended particulate matter in the water column. Variation in the nature, levels and partitioning of organic carbon in the particulate fraction affected levels of particulate mercury as well as mercury partitioning. These results highlight the dominant role of suspended particulate matter in the distribution of anthropogenic mercury and reinforce the importance of competitive behavior related to organic carbon in mercury scavenging.     

乌梁素海水体汞的分布特征及污染风险评估

于2011年1月采集乌梁素海表层水样,对湖水中重金属Hg含量进行分析.结合Hg的空间分布特征,利用单因子指数综合污染评价指数与健康风险评价模型对Hg污染程度与风险进行评估.结果表明,乌梁素海表层水体中Hg的平均浓度为1.04μg/L,所有监测点Hg的含量都超出地表水Ⅲ类标准和国家渔业用水标准,50%的监测点超出了地表水Ⅳ类标准.水体中Hg的分布模式与流域排污口位置、入湖口及水动力条件有一定关系,高值区域分布在入湖口相对集中的西北与东北部,湖泊南部与出口处的含量相对较低,处于中等水平.乌梁素海湖水中Hg的非致癌性污染物所致的健康危害风险度介于0.75×10-9~2.15×10-9a-1之间,Hg所致的健康危害风险度的贡献率在71.43%~92.44%之间,表明Hg污染水平与健康风险都较高,应该给予特别关注.     

从234Th的固/液分配看海洋胶体的作用

1994—1995年期间,利用β计数法实测了南沙群岛海域、南海东北部海域、厦门湾塔角附近海域和九龙江河口区共计116份海水样品中溶解态与颗粒态234Th的放射性比活度。结果表明,颗粒态234Th占总34Th的份额大小顺序为：九龙江河口区＞厦门海塔角附近海域＞南沙海域。南海东北部海域。234Th的条件分配系数Kd介于1．1×104—20×106dm3／kg之间,平均为2．2×105dm3／kdKd与总悬浮颗粒物含量（7SAN呈负相关关系：lg（Kd）＝－0．59·lg（TSM）＋5．67,这一“颗粒物浓度效应”可归因于海洋胶体物质的存在。由上述关系获得4个研究海区胶体浓度与悬浮颗粒物浓度的函数关系：Cc＝f（TSM0．59）。     

天然锰钾矿吸附水溶液中Hg^2＋的实验研究

利用粉碎分级的天然锰钾矿去除水溶液中Hg^2 的实验研究表明：反应平衡时间约为20小时；pH值对其吸附率影响很大，在中性（氯化物在偏碱性）条件下吸附率较高；溶液中阳离子的存在会产生竞争吸附而降低对Hg^2 的吸附量，2价金属离子较1价金属离子对Hg^2 竞争干扰明显；溶液中Cl^-的存在能明显降低对Hg^2 的吸附量。对等温吸附曲线的回归分析得出在浓度为5～350mg/L段能很好地符合Langmuir单吸附位吸附曲线，并计算出在该实验条件下其最大理论吸附量为27.6mg/g。解吸实验结果表明，在无其他电解质参与的条件下解吸量较少，受多种电解质干扰时其解吸率不超过20%。     

云南地下水中Rn和Hg震兆特征对比分析

以大量的实际观测资料及多次震例 ,深入研究了地下水中Rn和Hg的震兆特征。结果表明 :Hg对地壳岩石应力应变的反应程度比Rn更灵敏 ,更有利于地震预报。通过研究得出以下几点认识 :(1)大震前 ,Hg有 1年左右的中期趋势异常且都出现在距震中较近的有利部位 ,Rn有 1— 2年的趋势异常出现在距震中 5 0 0km范围内 ;(2 )大震前 ,大多数观测台站能观测到Hg突出的短临异常 ,而Rn出现短临异常的台站数只有Hg的1/ 2 ,且异常幅度小 ;(3)中强地震前 ,在距震中较近的观测台站 ,能观测到Hg异常 ,相同条件下的Rn异常则不明显。地下水中Rn和Hg的这些异常特征对未来地震三要素的预报有一定帮助。