Phase Chemistry Study of the Zabuye Salt Lake Brine: Isothermal Evaporation at 15°C and 25°C

Zabuye Salt Lake in Tibet, China is a carbonate-type salt lake, which has some unique characteristics that make it different from other types of salt lakes. The lake is at the latter period in its evolution and contains liquid and solid resources. Its brine is rich in Li, B, K and other useful minor elements that are of great economic value. We studied the concentration behavior of these elements and the crystallization paths of salts during isothermal evaporation of brine at 15°C and 25°C. The crystallization sequence of the primary salts from the brine at 25°C is halite (NaCl) → aphthitalite (3K2SO4·Na2SO4) → zabuyelite (Li2CO3)→ trona (Na2CO3·NaHCO3·2H2O) → thermonatrite (Na2CO3·H2O) → sylvite (KCl), while the sequence is halite (NaCl) → sylvite (KCl) → trona (Na2CO3·NaHCO3·2H2O) → zabuyelite (Li2CO3) → thermonatrite (Na2CO3·H2O) → aphthitalite (3K2SO4·Na2SO4) at 15°C. They are in accordance with the metastable phase diagram of the Na+, K+-Cl?, CO32?, SO42?-H2O quinary system at 25°C, except for Na2CO3·7H2O which is replaced by trona and thermonatrite. In the 25°C experiment, zabuyelite (Li2CO3) was precipitated in the early stage because Li2CO3 is supersaturated in the brine at 25°C, in contrast with that at 15°C, it precipitated in the later stage. Potash was precipitated in the middle and late stages in both experiments, while boron was concentrated in the early and middle stages and precipitated in the late stage.     

强烈气洗作用导致原油成分变化的定量计算:以库车坳陷天然气藏为例

库车坳陷以产天然气为主,同时产出少量原油和凝析油,油气充注不同步,普遍具有"油早气晚"的特点,晚期大量天然气的侵入,必然对早期聚集的油藏发生改造作用。对气藏中原油成分变化的定量计算和讨论,可为天然气的注入强度定量评价提供直接证据。未遭受气洗的原油,正构烷烃摩尔浓度的对数与相应的碳数呈线性关系,而气洗作用可使轻组分的正构烷烃最先溶解于干气中,并随着天然气继续向前运移,原始油藏中的轻组分正构烷烃大大减少。以此为理论基础,建立了正构烷烃损失的定量计算模型。结果表明克拉2构造原油正构烷烃损失程度最高,平均可达70%左右,大北构造带原油正构烷烃损失程度差异较大,与该地区断块发育有关。气洗作用导致原油正构烷烃减少,而金刚烷、多环芳烃等在天然气中溶解度较低的化合物得以浓缩富集,相对含量大大增加。轻芳烃含量也会随之而增加,原油芳香度增加,石蜡度降低。在模拟实验基础上对气洗程度进行了定量评价,初步估算表明,克拉2构造原油遭受的气洗作用最强,是其他构造带的2～5倍。     

毛乌素沙地南缘固沙灌丛下地表凝结水特征

尽管凝结水在干旱生态系统中所发挥的重要作用已被广泛关注,但对其在固沙灌丛下时空变化特征的研究仍然比较薄弱。为探明固沙灌丛对地表凝结水的影响,在毛乌素沙地南缘沙区选择3种典型固沙灌丛（沙柳Salix psammophila、柠条Caragana korshinskii和油蒿Artemisia ordosica）,以无固沙灌丛影响的裸沙作为对照,用微型蒸渗仪测定了固沙灌丛下不同位置（根部、1/2冠幅和外缘）和不同方向（东、南、西、北）上地表凝结水的形成和蒸发特征。结果表明：（1）与对照相比,固沙灌丛的存在显著降低了地表凝结水量,沙柳、油蒿和柠条灌丛下凝结水量分别降低了29%、32%和33%;(2)不同类型固沙灌丛下地表凝结水量由里向外均呈显著增加的趋势,但不同方向上地表凝结水量差异不显著;（3）固沙灌丛的存在减缓了凝结水的形成和蒸发过程,即凝结水自19:00开始形成,到次日08:00基本结束,至13:00—15:00蒸发殆尽,其形成过程整体上表现出增加—平缓—增加的趋势,柠条和油蒿灌丛下地表凝结水在03:00—05:00甚至有少量蒸发,而蒸发过程呈稳定下降趋势;（4）凝结水的形成过程与空气...     

环境因子对敦煌莫高窟洞窟水分蒸发的影响

环境因子对洞窟水分蒸发有重要影响.在敦煌莫高窟72窟蒸发水分的收集过程中,通过对窟内温度和湿度的控制,分析窟内温湿度对水分蒸发的影响及作用机理,并根据围岩水分蒸发机理,探讨影响水分蒸发的外部环境因子.结果表明,洞窟2.0℃的温度变化即可对水分蒸发产生显著影响,短期内蒸发量可增大1倍以上.温度高、蒸发量大,可导致窟内相对湿度增加,因此目前全球性的气温升高对洞窟文物将产生不利影响.敦煌地区降雨量的增加增大了空气潮湿过程激活壁画盐分的可能.莫高窟所处的地理位置、地热、地形结构、围岩孔隙度和洞窟结构本身对围岩水分蒸发有重要影响.本文从环境因素揭示了莫高窟壁画能够保存至今的关键原因,为今后洞窟文物的更好保护提供了新思路.     

Cenozoic high-K alkaline magmatism and associated Cu–Mo–Au mineralization in the Jinping–Fan Si Pan region,southeastern Ailao Shan–Red River shear zone,southwestern China–northwestern Vietnam

The Jinping–Fan Si Pan (JFP) Cenozoic magmatic and Cu–Mo–Au metallogenic belt in the southeastern part of the Ailao Shan shear zone host the Tongchang, Chang′an, Habo, and Chinh Sang Cu–Mo–Au deposits. These deposits form an integrated epithermal-porphyry regional mineralization system associated with 40–32 Ma high-K alkaline magmatism. The magmatic rocks in the belt have relatively low TiO₂ (<0.73 wt%), P₂O₅ (<0.29 wt%), and FeO^* (<4.99 wt%), and high Na₂O (2.86–4.75 wt%) and K₂O (4.01–7.98 wt%). They also have high contents of incompatible trace elements, and are enriched in LILE (Rb, Ba, K, Sr) and LREE. They have marked Nb, Ta, Ti and P depletion in primitive mantle-normalized spidergrams, and plot close to the EMII mantle field in the Sr–Nd isotopic diagram. These characteristics are similar to those of the Eocene high-K alkaline rocks along the northern Ailao Shan belt, eastern Tibet plateau. The sulfur and lead isotope analyses of sulfide minerals from both the ores and related magmatic rocks confirm the involvement of a magmatic ore fluid. The Cenozoic alkaline intrusions and Cu–Mo–Au mineralization in the JFP were formed prior to the initiation of left-lateral shearing along the Ailao Shan shear zone. The magmas appear to have been derived from enriched mantle, possibly with mixing of materials from the buried Tethyan oceanic lithosphere, and/or crust.     

The Influence of Pan Evaporation Conditions on Na Cl crystallization

正1 Introduction Crystallization is one of important unit operations in the chemical production process,which requires not only the crystal product with high purity and yield,but also the available particle size of the crystal products to ensure product quality.Crystallization process is affected by     

The Metastable Phase Equilibria of the MeX-MgCl_2-H_2O Systems

正1 Introduction The Pingluoba brine,which characterized as high concentration with sodium,potassium,boron,lithium,and rubidium,possess great development value.The main composition of the brine can be summarized to the     

Study on the Isothermal Evaporation Process at 5℃ with the Brine of Laguocuo Salt Lake

正1 Introduction Tibet has nurmerous salt lakes.Laguocuo is one of the salt lakes,which is located to the sorthern of Ali Plateau,31°59′02″N-32°04′08″N,84°02′03″E-84°12′03″E.Its lake water is rich in potassium,magnesium,lithium,boron,rubidium,cesium and other resources.The study of     

新疆塔额盆地各气象要素对水面蒸发影响的敏感性分析

水面蒸发敏感因素的判断,对于干旱区水资源的规划与利用具有重要指导意义。文章以新疆塔额盆地内的塔城市气象站1981—2010年资料为例,采用敏感系数法对研究区多年月均水面蒸发影响因素进行敏感性分析,并与关联分析法分析的结果对比。结果表明：在塔额盆地内,温度与水汽压二因素对水面蒸发影响最为敏感;基于敏感系数法的敏感因素研究结果与关联分析的结果基本一致,尤其在主要影响因子的判定上。     

1980—2020年中国九大流域蒸散发及其组分时空评估

蒸散发是地表陆气水分交换的纽带,准确量化蒸散发的时空演变格局对于水资源规划与管理至关重要。本文基于GLEAM模型的蒸散发及其组分数据集,借助7个通量观测站数据、120个流域的流域水量平衡及PML_V2蒸散发产品,在中国九大流域系统评估了GLEAM-ET产品,分析了植被恢复背景下,蒸散发（ET）及其组分（植被蒸腾Ec,截留蒸发Ei,土壤蒸发Es）在1980—2020年的时空演变格局。本文主要得到以下结论：① GLEAM-ET产品在中国九大流域具有较好的适用性,其性能与气候类型有关,干旱区效果优于湿润区。此外,GLEAM与PML_V2模型在九大流域相关性较好（R>0.7）,分布格局与变化趋势整体保持一致。② 全国尺度上,ET均值为416.88 mm,增长速率为1.21 mm/a。Ec与ET均呈自东南向西北递减的分布格局,而Es与其相反。Ec、ET在九大流域均呈显著增加趋势（p<0.001）。Ei、Es在季风区流域分别呈显著增加和显著减小趋势;在内陆区流域呈不显著减小（p>0.05）和显著增加趋势。③在植被恢复背景下,ET组分比例发生了变化。Ec占比变化存在南北差异,南方流域Ec占比均减小,北方流域均增加。Ei占比在各流域均增加,Es占比均减小。黄河流域ET组分对植被恢复的响应最为明显,Ec占比增加了5.21%,Es占比减小了5.56%。